Your browser doesn't support javascript.
loading
Mostrar: 20 | 50 | 100
Resultados 1 - 20 de 27
Filtrar
Más filtros











Base de datos
Intervalo de año de publicación
1.
Environ Sci Pollut Res Int ; 31(14): 21765-21780, 2024 Mar.
Artículo en Inglés | MEDLINE | ID: mdl-38393575

RESUMEN

In recent years, heavy metal contamination of soils has become a major concern in China due to the potential risks involved. To assess environmental pollution and human health risks in a typical heavy metal polluted site in Jiangxi Province, a thorough evaluation of the distribution, pollution levels, and sources of heavy metals in soils of the Yangmeijiang River watershed was conducted in this study. Positive matrix factorization and Monte Carlo simulation were used to evaluate the ecological and human health risks of heavy metals. The research findings indicate that heavy metal pollution was the most severe at the depth of 20-40 cm in soils, with local heavy metal pollution resulting from mining and sewage irrigation. The high-risk area accounted for 91.11% of the total area. However, the pollution level decreased with time due to sampling effects, rainfall, and control measures. Leaf-vegetables and rice were primarily polluted by Cd and Pb. The main four sources of heavy metals in soils were traffic emission, metal smelting, agricultural activities and natural sources, mining extraction, and electroplating industries. Heavy metals with the highest ecological risk and health risk are Cd and As, respectively. The non-carcinogenic and carcinogenic risks of children were 7.0 and 1.7 times higher than those of adults, respectively. Therefore, children are more likely to be influenced by heavy metals compared to adults. The results obtained by the risk assessments may contribute to the identification of specific sources of heavy metals (e.g., traffic emissions, metal smelting, mining excavation, and electroplating industries). Additionally, the environmental impacts and biotoxicity associated with various heavy metals (e.g., Cd and As) can also be reflected. These outcomes may serve as a scientific basis for the pollution monitoring and remediation in the mining-affected areas.


Asunto(s)
Cadmio , Metales Pesados , Adulto , Niño , Humanos , Método de Montecarlo , China , Medición de Riesgo , Suelo
2.
J Contam Hydrol ; 259: 104259, 2023 Nov.
Artículo en Inglés | MEDLINE | ID: mdl-37922726

RESUMEN

This paper presents an analytical study of organic contaminants transport in a cut-off wall and aquifer dual-domain system, considering the effects of the inlet boundary conditions and cut-off structural arrangements. The comprehensive sensitivity analysis of parameters focusing on the breakthrough time, attenuation time and cumulative concentration are presented using the Monte Carlo simulation and Sobol global method. The simplified constant inlet boundary condition can lead to an excessively conservative prediction of the contaminant breakthrough compared to the 'finite mass' and 'decaying source' boundary conditions. The cut-off wall hydraulic performance can be enhanced by reducing the contaminant's head loss, shape factor, half-life and cut-off wall hydraulic conductivity while increasing the retardation factor. The contaminant's half-life can largely influence the maximum contaminant concentration, attenuation time and breakthrough time. For example, the maximum contaminant concentrations for T1/2 = 1.4 years and T1/2 = 100 years are 13 and 123 times greater than that for T1/2 = 0.1 year, respectively. The influence of the variation of shape factor on the breakthrough curve should be taken into consideration. Altering the structural arrangement of the cut-off wall to accommodate a smaller shape factor increases the contaminant breakthrough time. The proposed solution allows the analysis of a cut-off wall and aquifer system with different inlet boundary conditions and structural arrangements of the cut-off wall.


Asunto(s)
Agua Subterránea , Modelos Teóricos , Movimientos del Agua , Simulación por Computador , Método de Montecarlo
3.
J Environ Manage ; 348: 119350, 2023 Dec 15.
Artículo en Inglés | MEDLINE | ID: mdl-37866188

RESUMEN

The remediation of contaminated soils is a great challenge for global environmental sciences and engineering. The landfill was a kind of infrastructure to deal with waste from different sources while it would also cause the threat to groundwater. Cut-off walls and pumping wells were usually applied in the landfill to prevent the spread of pollutants to wider areas. However, the combination of using both of methods was rarely analyzed, especially using field data for calibrating and fitting groundwater flow and pollutant transport. 7 monitoring wells were arranged in the study area to survey the subsurface seepage. The pollution monitoring was carried out for a period of 50 days, covering 31 types of inorganic and organic pollutants. The concentration of 2,4,6-trichlorophenol (TCP) was 556.7 times greater than the standard concentration. A coupled numerical model of groundwater flow and pollutant transport was developed to assess the effectiveness of various control methods. Three options were tested, including the implementation of a single cut-off wall as well as a combination of a cut-off wall and a pumping well, for preventing the discharge of pollutants from landfills. The combination of a cut-off wall and a pumping well is the best strategy for removal of TCP. The combination approaches lead to a reduction of pollution plumes by a factor of 11 compared to the case without pollution control measures. The research findings may provide a basis and reference for the application of cutoff walls and pumping well in landfill sites or contaminated groundwater.


Asunto(s)
Contaminantes Ambientales , Agua Subterránea , Eliminación de Residuos , Contaminantes Químicos del Agua , Monitoreo del Ambiente/métodos , Contaminación Ambiental , Instalaciones de Eliminación de Residuos , Contaminantes Químicos del Agua/análisis
4.
Environ Pollut ; 336: 122391, 2023 Nov 01.
Artículo en Inglés | MEDLINE | ID: mdl-37633438

RESUMEN

Volatile organic compounds (VOCs) emission flux and their concentration profiles were measured at a final municipal solid waste (MSW) landfill cover in Hangzhou, China. The influencing parameters, especially ground surface air temperature and pressure were monitored concomitantly. Furthermore, a numerical model incorporating coupled thermo-hydro-chemical interaction to assess VOCs emission from this final landfill cover (LFC) system was developed and validated with the field test results. The tested total VOC emission flux from the final cover is 0.0124 µg/m2/s, which indicates that the total amount of VOCs emitted into the atmosphere is 391 mg/m2 annually. Among these, dichloromethane (DCM) dominated VOCs emission flux during May, comprising 51.8% of the total emission flux. The numerical simulation results indicated that the diffusive emission flux of VOCs varied consistently with the fluctuation of atmospheric temperature. Whereas, the advective flux varied inversely with the fluctuation of barometric pressure. The highest difference in diffusive emission flux induced by temperature variation is 183 µg/m2/day and occurred in spring. Moreover, the results demonstrated that the impact of atmospheric temperature and pressure fluctuation on the emission of VOC from final covers is non-negligible when reasonably assessing the risks of landfill and landfill gas emission budget.


Asunto(s)
Contaminantes Atmosféricos , Eliminación de Residuos , Compuestos Orgánicos Volátiles , Temperatura , Compuestos Orgánicos Volátiles/análisis , Eliminación de Residuos/métodos , Contaminantes Atmosféricos/análisis , Instalaciones de Eliminación de Residuos
5.
Waste Manag ; 169: 11-22, 2023 Sep 01.
Artículo en Inglés | MEDLINE | ID: mdl-37384970

RESUMEN

This paper presents the study on the variation, influencing factors and diffusion regularity of hydrogen sulfide (H2S) concentration and surface flux on the working face and intermediate geomembrane cover of a landfill. Field investigations were conducted using static chambers at a large-scale municipal solid waste landfill in Hangzhou, China, from January 2019 to June 2021. The analytical models of H2S transport in the working face and intermediate cover were developed to investigate the surface flux under various conditions. The CALPUFF model was used to demonstrate the diffusion path. The H2S surface flux on the working face ranged from 7.1 × 10-3 to 1.7 mg/m2/h, whereas the range was found to be 1.5 × 10-4 to 0.9 mg/m2/h on the intermediate geomembrane cover. This observation indicated that the geomembrane can reduce H2S emissions. In addition, the H2S surface fluxes at the HDPE GMB seams and near the gas collecting wells were generally 1-2 orders of magnitude larger than that in the intact GMB. The analytical model estimates that the intact GMB exhibits a diffusion coefficient of H2S ranging from 2.7 × 10-11 to 2.2 × 10-10 m2/s. However, the diffusion coefficient increases significantly to a range of 3.3 × 10-11-9.8 × 10-7 m2/s on the GMB seams. According to CALPUFF results, only the H2S diffusion from the working face had areas exceeding the standard concentration.


Asunto(s)
Contaminantes Atmosféricos , Sulfuro de Hidrógeno , Eliminación de Residuos , Sulfuro de Hidrógeno/análisis , Instalaciones de Eliminación de Residuos , Residuos Sólidos , China , Eliminación de Residuos/métodos , Contaminantes Atmosféricos/análisis
6.
Environ Sci Pollut Res Int ; 30(32): 78811-78824, 2023 Jul.
Artículo en Inglés | MEDLINE | ID: mdl-37273058

RESUMEN

The current study focuses on developing alternative formulations (mobile-immobile model) of transient analytical modelling for organic contaminant transport in a composite of geosynthetic clay (GCL) and attenuation layer (AL) system. The Laplace transform method is adopted to derive the solution. The proposed analytical frameworks are validated by two set of benchmarks. The varied examples of organic contaminant transport in the composite liner are evaluated by the proposed solution to discuss the effects of soil properties, flow conditions, adsorption, and mass transfer in mobile and immobile zones on the overall transport of contaminants. Finally, an example case is presented to show the application prospect of the proposed model. The result demonstrated that mass transfer between mobile and immobile may increase the breakthrough time by a factor of 2. This indicates that heterogeneities of clay are a non-negligible part for the performance assessment of the liner system. Péclet number in GCL ([Formula: see text]) is used to investigate the relative importance of advection and diffusion mechanisms. Increasing [Formula: see text] from 0.1 to 1 can lead to an increase of the breakthrough time by a factor of 15. The analytical solutions presented here may also serve as the basic benchmark test tool for alternative numerical studies of contaminants transport in heterogeneous media.


Asunto(s)
Modelos Teóricos , Suelo , Arcilla , Difusión , Adsorción
7.
J Environ Manage ; 336: 117604, 2023 Jun 15.
Artículo en Inglés | MEDLINE | ID: mdl-36871453

RESUMEN

Bisphenol A (BPA) is a toxic endocrine disruptor often found in landfill leachate. Adsorption behaviors and mechanisms of BPA onto organo-bentonites amended loess, e.g., Hexadecyltrimethylammonium chloride-bentonite (HTMAC-B) and Carboxymethylcellulose-bentonite (CMC-B) were experimentally investigated. The adsorption capacity of loess amended by HTMAC-B (LHB) and CMC-B (LCB) is 4.2 and 4 times greater than that of loess (L), respectively. It is attributed to the increase of hydrogen bonds and hydrophobic lateral interactions between the adsorbent and the adsorbate. The binary (Pb2+-BPA) systems may enhance BPA adsorption onto the samples by the formation of coordination bonds between the hydroxyl group of BPA and Pb2+ ions. A cycled column test was used for investigating the transport behavior of BPA in LHB and LCB samples. The hydraulic conductivity of loess amended by the organo-bentonite (e.g., HTMAC-B, CMC-B) is generally lower than 1 × 10-9 m/s. Especially for CMC-B amended loess, the hydraulic conductivity can be reduced to 1 × 10-12 m/s. This guarantees the hydraulic performance of the liner system. Transport behavior of BPA in cycled column test is explained by the mobile-immobile model (MIM). Modelling results showed that loess amended by organo-bentonites can increase the breakthrough time of BPA. In comparison to loess-based liner, the breakthrough time of BPA for LHB and LCB can be increased by a factor of 10.4 and 7.5, respectively. These results indicate that organo-bentonites can serve as a potentially effective amendment for improving the adsorption of loess-based liners.


Asunto(s)
Plomo , Contaminantes Químicos del Agua , Adsorción , Contaminantes Químicos del Agua/química , Tensoactivos
8.
Sci Total Environ ; 879: 162962, 2023 Jun 25.
Artículo en Inglés | MEDLINE | ID: mdl-36958554

RESUMEN

Phthalic acid ester (PAE) is a toxic pollutant commonly found in high concentrations in municipal solid waste landfills. Soil-bentonite is widely used as a barrier material to control groundwater contaminants from landfill leachates. Traditional soil-bentonite materials always have a limited capacity for organic pollutant adsorption. To address this issue, the adsorption and transport behavior of dimethyl phthalate (DMP) on loess amended with two kinds of modified bentonite (HTMAC-B, modified with hexadecyltrimethylammonium chloride; CMC-B, modified with hydrophobic cationic surfactant, and carboxymethyl cellulose) were investigated. The kinetics of DMP adsorption indicates that film diffusion contributes significantly to the kinetic adsorption of DMP on HTMAC-B. The adsorption isotherm results showed that partitioning dominated DMP adsorption on loess with both modified bentonites. Owing to the in-ionic sites in HTMAC-B, which attracted hydrophobic compounds such as DMP, the adsorption capacity of 5 % HTMAC-B-amended loess (LH) was increased by a factor of 3.2. However, because CMC-B provided mostly ionic sites, 5 % CMC-B-amended loess (LC) had a little effect on DMP adsorption. The hydraulic conductivity values of LH and LC were 5.95 × 10-10 and 1.65 × 10-11 m/s, respectively. The X-CT result showed that there is a significant porosity change for both LH and LC. Dual-porosity model reveals that the leaching process primarily affects micro-pores, rather than larger pores in the soil matrix. The predicted retardation factors for LH and LC were 38.89 and 9.67, respectively. When using loess-bentonite as barrier material, the amendment of HTMAC-B and CMC-B can help to increase the retardation ability and reduce the permeability, respectively.

9.
J Environ Manage ; 321: 116020, 2022 Nov 01.
Artículo en Inglés | MEDLINE | ID: mdl-36104890

RESUMEN

Landfill gas (LFG) emission is gaining more attention from the scientific fraternity and policymakers recently due to its threat to the atmosphere and human health of the populace living in surrounding premises. Though landfill cover (LFC) (viz., daily, intermittent and final cover) is widely used by landfill operators to mitigate or reduce these emissions, their overall performance is still under question. A critical analysis of available literature, primarily pertaining to (i) the composition of the landfill gases and their migration in the LFC system, (ii) experimental and mathematical investigations of the transport mechanism of gas and (iii) the impact of additives to cover soils on transport and fate of gas, has been conducted and presented in this manuscript. Investigation of the efficiency of modified soil was mainly focused on laboratory test. More field tests and application of amended cover soils should be conducted and promoted further. Studies on nitrous oxide and emerging pollutants, including poly-fluoroalkyl substances transport in landfill cover system are limited and need further research. The transport mechanisms of these unconventional contaminants should be considered regarding the selection of LFC materials including geomembrane and geosynthetic clay liners. The existing analytical and numerical models can provide a basic understanding of LFG transport mechanisms and are able to predict the migration behaviour of LFG; however, there are still knowledge gaps concerning the interaction between different species of the gas molecule when modeling multi-component gas transport. Gas transport through fractured cover should also be considered when evaluating LFG emission in the future. Simplified design method for landfill cover system regarding LFG emission based on analytical models should be proposed. Overall, mathematical models combined with experiments can facilitate more visualized and intensive insights, which would be instrumental in devising climate adaptive landfill covers.


Asunto(s)
Eliminación de Residuos , Gases/análisis , Humanos , Eliminación de Residuos/métodos , Suelo , Instalaciones de Eliminación de Residuos
10.
Environ Sci Pollut Res Int ; 29(51): 76944-76960, 2022 Nov.
Artículo en Inglés | MEDLINE | ID: mdl-35668271

RESUMEN

A field gas extraction experiment is carried out at a high-kitchen food large-scale landfill site with high leachate level. The leachate level was decreased to improve the pumping efficiency. Considering the heterogeneity of the municipal solid waste (MSW), the pores in the unsaturated MSW are divided into matrix pores and fractures. A transient dual-porosity model was then developed to analyze the pumping test results. The first and second boundary conditions considering the effect of cover layers of landfills was involved. The results show that the gas flow rate can be increased by 14-37% due to the drawdown of the leachate level. Compared with the single pore model, the dual-porosity model can better predict the field results, indicating that the preferential flow in the landfill caused by the heterogeneity of MSWs is very important. As the pumping pressure increases by a factor of 5, the ratio of fractures to pores wf can be decreased by a factor of 4.4. This may be due to the fact that the fractures will be compressed when the effective stress was increased as the negative pumping pressure was applied. The pumping pressure and the anisotropy value of the MSWs have the greater influence on the well radius of influence. The proposed model can be used for effective design of the field gas pumping experiments. The obtained gas generation rate, gas permeability of the dual porosity MSWs can be useful for gas transport analysis and gas pumping well design for the high-kitchen food content landfills.


Asunto(s)
Eliminación de Residuos , Contaminantes Químicos del Agua , Residuos Sólidos/análisis , Eliminación de Residuos/métodos , Modelos Teóricos , Instalaciones de Eliminación de Residuos , Reactores Biológicos , Contaminantes Químicos del Agua/análisis
11.
Environ Sci Pollut Res Int ; 29(49): 74225-74241, 2022 Oct.
Artículo en Inglés | MEDLINE | ID: mdl-35635673

RESUMEN

The quantitative assessment of landfill gas emissions is essential to assess the performance of the landfill cover and gas collection system. The relative error of the measured surface emission of landfill gas may be induced by the static flux chamber technique. This study aims to quantify effects of the size of the chamber, the insertion depth, pressure differential on the relative errors by using an integrated approach of in situ tests, and numerical modeling. A field experiment study of landfill gas emission is conducted by using a static chamber at one landfill site in Xi'an, Northwest China. Additionally, a two-dimensional axisymmetric numerical model for multi-component gas transport in the soil and the static chamber is developed based on the dusty-gas model (DGM). The proposed model is validated by the field data obtained in this study and a set of experimental data in the literature. The results show that DGM model has a better capacity to predict gas transport under a wider range of permeability compared to Blanc's method. This is due to the fact that DGM model can explain the interaction among gases (e.g., CH4, CO2, O2, and N2) and the Knudsen diffusion process while these mechanisms are not included in Blanc's model. Increasing the size and the insertion depth of static chambers can reduce the relative error for the flux of CH4 and CO2. For example, increasing the height of chambers from 0.55 to 1.1 m can decrease relative errors of CH4 and CO2 flux by 17% and 18%, respectively. Moreover, we find that gas emission fluxes for the case with positive pressure differential (∆Pin-out) are greater than that of the case without considering pressure fluctuations. The Monte Carlo method was adopted to carry out the statistical analysis for quantifying the range of relative errors. The agreement of the measured field data and predicted results demonstrated that the proposed model has the capacity to quantify the emission of landfill gas from the landfill cover systems.

12.
Environ Sci Pollut Res Int ; 29(27): 40768-40780, 2022 Jun.
Artículo en Inglés | MEDLINE | ID: mdl-35084682

RESUMEN

Compacted clay liners (CCLs) are extensively used as engineering barriers for groundwater and soil pollution. The existence of cracks/fractures in CCL caused by thermally induced shrinkage is reported to importantly damage the performance of the CCL. An analytical model is developed to study the effects of the cracks/fractures on the migration of organic contaminants through a composite liner system. Laplace transformation and Laplace inversion using the Stehfest method are adopted to derive the analytical solution, which is validated by the experimental data. The existence of crack shows a significant impact on the breakthrough curve and bottom flux of organic contaminants. Increasing the crack width from 1 to 25 mm results in an enhancement of contaminant bottom concentration by a factor of 280. Increasing the adsorption factor and degradation rate of contaminants can effectively improve the performance of the composite liner with cracks. The effects of degradation of contaminants on the breakthrough curve are found to be more significant for the case with a larger retardation factor. This may be due to the fact that increasing the retardation factor can significantly slow down the transport of contaminants, which may indirectly create a longer period for the degradation of contaminants.


Asunto(s)
Agua Subterránea , Eliminación de Residuos , Contaminantes Químicos del Agua , Silicatos de Aluminio , Arcilla , Eliminación de Residuos/métodos , Contaminantes Químicos del Agua/análisis
13.
Environ Sci Pollut Res Int ; 29(4): 6360-6374, 2022 Jan.
Artículo en Inglés | MEDLINE | ID: mdl-34449022

RESUMEN

The leakage of chemical compounds in landfill leachate led to serious environment pollution, especially, the compounds termed endocrine disruptors such as bisphenol A (BPA). It is very important to study the adsorption behavior of endocrine disruptors in modified soil for predicting and evaluating the potential harm of endocrine disruptors to the soil. Bentonite-amended Chinese loess mixtures, with various proportions of bentonite, were used for the removal of BPA from an aqueous solution. A batch test was used to investigate the adsorption properties of bisphenol A on bentonite and Chinese loess mixtures. The influences of bentonite proportion, temperature, reaction time, pH, and soil-water ratios on the adsorption process were considered. The Fourier transform infrared spectra (FTIR) was used to clarify the change of functional groups before and after the adsorption of BPA on soil. The adsorption mechanism of BPA on soil was discussed preliminary. The results show that the addition of bentonite to the loess can improve the adsorption rate of BPA. The adsorption of BPA was mainly a spontaneous, exothermic, entropy decreasing physical adsorption process. The interaction between bentonite content and reaction concentration had a beneficial effect on BPA adsorption. The linear relationship between bentonite content and adsorption capacity was obtained. The results indicate that bentonite amended loess can provide a good liner for BPA.


Asunto(s)
Bentonita , Contaminantes Químicos del Agua , Adsorción , Compuestos de Bencidrilo , Concentración de Iones de Hidrógeno , Cinética , Fenoles , Contaminantes Químicos del Agua/análisis
14.
Waste Manag ; 120: 448-458, 2021 Feb 01.
Artículo en Inglés | MEDLINE | ID: mdl-33139192

RESUMEN

A new analytical model for organic contaminant transport through GMB/CCL (geomembrane and compacted clay liner) composite liner is developed, which can consider adsorption, diffusion and thermodiffusion processes and is applicable for typical bottom boundary conditions. The separation of variables method is adopted to derive the solution. The present model is first verified against experimental results and a numerical model. The influence of thermodiffusion on organic contaminant transport in composite liner is then investigated. Toluene is adopted as the representative organic contaminant. The results reveal that when the Soret coefficient ST is not less than 0.01 K-1, the effect of thermodiffusion should be taken into account on the contaminant transport in GMB/CCL composite liner in wet landfills. When the Soret coefficient ST is 0.03 K-1, the breakthrough time of a GMB + 0.75 m CCL composite liner and a 2 m CCL would be overestimated by 20% to 76% due to omitting of the effect of thermodiffusion. Namely, the barrier performance would be greatly overestimated if the effect of thermodiffusion is neglected in these cases. In other aspects, the thermal conductivity of GMB and CCL has little effect on the contaminants transport in GMB/CCL composite liners, so there is no need to modify the materials for this parameter. The present model is an applicable tool for evaluating the barrier performance of the GMB/CCL composite liner, and can provide valuable advices for improving the liner materials.


Asunto(s)
Eliminación de Residuos , Contaminantes Químicos del Agua , Adsorción , Difusión , Difusión Térmica , Contaminantes Químicos del Agua/análisis
15.
Environ Sci Pollut Res Int ; 28(4): 4488-4502, 2021 Jan.
Artículo en Inglés | MEDLINE | ID: mdl-32940835

RESUMEN

Lead (Pb) is one of the most toxic, hazardous pollutants available in landfill leachate. Loess-amended soil buffers are found suitable and effective in attenuating migration of Pb and the other trace metals. High concentration of ammonium (NH4+ > 1000 mg/l) is also reported in landfill leachate, and therefore, it is essential to investigate the transport of lead under such condition. In this study, the mechanisms and the capacity of loess to adsorb Pb under high NH4+ concentration were investigated. Adsorption isotherm test data were obtained for 25 °C, 35 °C and 45 °C. The maximum adsorption capacity is estimated to be 2101.97 mg/g at 25 °C and 4292.8 mg/g at 45 °C under 1000 mg/l NH4+. The binding sites of Pb on loess are positively related to each other at low temperatures (25-35 °C). The thermodynamic analysis indicates that adsorption process is endothermic and non-spontaneous and the system randomness increases with reaction time. The kinetic test data, fitted with a pseudo-second-order kinetic model and an intraparticle diffusion model, suggests that removal of Pb is driven by both membrane and intraparticle diffusions. The SEM, XRD and FTIR analyses indicate flocculation, precipitations as well as some ion exchange processes, which perhaps combinedly increases adsorption of both NH4+ and Pb in loess. The two kinds of precipitations are involved for the removal of Pb. The precipitations of PbCO3, Pb(OH)2 and PbCO3·2H2O are formed by the reactions between calcite and lead. The other precipitation of white basic salt (Pb2O(NO3)2) is formed by the reactions among Pb2+, NO3- and aqueous ammonia under alkaline environment of loess slurry.


Asunto(s)
Compuestos de Amonio , Contaminantes Químicos del Agua , Purificación del Agua , Adsorción , Concentración de Iones de Hidrógeno , Cinética , Plomo , Termodinámica , Contaminantes Químicos del Agua/análisis
16.
Environ Sci Pollut Res Int ; 26(18): 18162-18180, 2019 Jun.
Artículo en Inglés | MEDLINE | ID: mdl-31037526

RESUMEN

Variation of volatile organic compound (VOC) concentration and composition in an active landfill were monitored by a developed static chamber for 2 years. The landfill gas from 82 sampling points including 70 points on working face, 8 points on geomembrane (GMB), and 4 points on final cover were analyzed for VOCs by GC-MS. Twenty-eight types of VOCs were detected, including terpenes, sulfur compounds, aromatics, hydrocarbon, oxygenated compounds, aldehyde compounds, and halogenated compounds. Terpenes were the dominant VOCs recorded in the spring, autumn, and winter seasons, whereas sulfur compounds dominated in the summer season. Limonene, ethyl alcohol, and acetone were identified as the main VOCs emitted from the waste working face of the landfill. Limonene dominated the terpenes with a maximum concentration of 43.29 µg m-3 in the autumn season. Limonene was also the dominant VOC escaping from the defects of geomembrane temporary cover reaching an average concentration 38 µg m-3. The defects of geomembranes can be a great emission source of VOCs. Emission rate of limonene was 2.24 times higher than that on the working face. VOC concentrations on the final cover can be 166 times less than those obtained on the working face. VOC emitted from the landfill did not represent a health threat for human health. However, concentrations of methyl mercaptan and ethanethiol on the working face were 3.4-22.8 times greater than their odor threshold, which were the main compounds responsible for odor nuisance. Results obtained from CALPUFF model indicated that methyl mercaptan and ethanethiol would not be a nuisance for the residents around the landfill. However, these compounds are harmful to the workers on the landfill.


Asunto(s)
Contaminantes Atmosféricos/análisis , Monitoreo del Ambiente , Compuestos Orgánicos Volátiles/análisis , Instalaciones de Eliminación de Residuos , China , Monitoreo del Ambiente/métodos , Cromatografía de Gases y Espectrometría de Masas , Estaciones del Año , Compuestos de Sulfhidrilo/análisis , Compuestos de Azufre/análisis
17.
J Environ Manage ; 225: 232-241, 2018 Nov 01.
Artículo en Inglés | MEDLINE | ID: mdl-30092550

RESUMEN

The variation characteristics and influence factors of methane emission at Jiangchungou landfill, one of the largest landfill in China, has been investigated by a one-year field monitoring campaign during 2015-2016. The methane concentration above the landfill surface varied widely from negligible to 33,975 ppm. At least 75% of the methane concentration values of the sampling points are lower than the allowed limit (500 ppm). More than 95% of the high concentration zones (>500 ppm) were located in the temporary cover area (TA). Several environmental factors were found to be related to the variation of the concentration values. A clear correlation was observed between barometric pressure and exceeding-standard areas with a correlation coefficient of -0.743 (p < 0.1). The concentration values in the final cover area (FA) were about one order of magnitude lower than those observed in the TA due to the fact that rapid methane production rate happened in the first 180 days after the high kitchen content wastes were landfilled. The percentages of the measured concentration values exceeding 500 ppm near the gas collection wells in TA zone were 71.5% in November, 2015 and 55.7% in January, 2016 due to the leakage from the sides of gas collection wells. The average methane concentration values on the HDPE geomembrane was higher than those observed on the loess cover due to the fact that the geomembrane was relatively thin (0.5 mm) and can be easily damaged by the operation vehicles. Thicker geomembranes (>1.5 mm) with a good construction quality control are expected to provide better performance at this site.


Asunto(s)
Metano , Eliminación de Residuos , Contaminantes Atmosféricos , China , Monitoreo del Ambiente , Instalaciones de Eliminación de Residuos
18.
Waste Manag Res ; 35(10): 1072-1083, 2017 Oct.
Artículo en Inglés | MEDLINE | ID: mdl-28825359

RESUMEN

Leachate recirculation in municipal solid waste (MSW) landfills operated as bioreactors offers significant economic and environmental benefits. Combined drainage blanket (DB)-horizontal trench (HT) systems can be an alternative to single conventional recirculation approaches and can have competitive advantages. The key objectives of this study are to investigate combined drainage blanket -horizontal trench systems, to analyze the effects of applying two recirculation systems on the leachate migration in landfills, and to estimate some key design parameters (e.g., the steady-state flow rate, the influence width, and the cumulative leachate volume). It was determined that an effective recirculation model should consist of a moderate horizontal trench injection pressure head and supplementary leachate recirculated through drainage blanket, with an objective of increasing the horizontal unsaturated hydraulic conductivity and thereby allowing more leachate to flow from the horizontal trench system in a horizontal direction. In addition, design charts for engineering application were established using a dimensionless variable formulation.


Asunto(s)
Reactores Biológicos , Eliminación de Residuos , Residuos Sólidos , Instalaciones de Eliminación de Residuos
19.
J Environ Manage ; 202(Pt 1): 46-54, 2017 Nov 01.
Artículo en Inglés | MEDLINE | ID: mdl-28715681

RESUMEN

NH4+-N is a crucial pollutant in landfill leachate and can be in high concentrations for a long period of time due to anaerobic condition of landfills. The adsorption properties of NH4+-N on the Chinese loess were investigated using Batch test. The influences of ammonium concentration, temperature, reaction time, slurry concentration, and pH on the adsorption process are evaluated. Adsorption kinetics and isotherm behaviors were studied by applying different models to the test data to determine the adsorption parameters. The equilibrating duration was shown to be less than 60 min. The data on adsorption kinetics can be well fitted by the pseudo-second-order kinetics model. According to the Langmuir isotherm model, the adsorption capacity of Chinese loess about NH4+-N was predicted to be 72.30 mg g-1. The uptake of NH4+-N by Chinese loess was considered to be the type of physical adsorption on the basis of D-R isotherm analysis. The optimal pH and slurry concentration are 4 and 2 g/50 ml, respectively. According to the calculated values of free energy, enthalpy and entropy change, the adsorption process is determined to be exothermic. The disorder of the system appeared lowest at temperature of 308.15 K. The predicted Gibb's free energies also indicate the adsorption process is endothermic and spontaneous. The FTIR spectrum and EDX analysis showed the adsorption process of NH4+ involves cation exchange and dissolution of calcite.


Asunto(s)
Contaminantes Químicos del Agua , Adsorción , Concentración de Iones de Hidrógeno , Cinética , Temperatura , Termodinámica
20.
Waste Manag ; 66: 103-113, 2017 Aug.
Artículo en Inglés | MEDLINE | ID: mdl-28495226

RESUMEN

This paper developed a two-dimensional axisymmetric analytical model for layered landfills with vertical wells. The model uses a horizontal layered structure to describe the waste non-homogeneity with depth in gas generation, permeability and temperature. The governing equations in the cylindrical coordinate system were transformed to dimensionless forms and solved using a method of eigenfunction expansion. After verification, the effects of different well boundary conditions and gas extraction systems on recovery efficiency were investigated. A dimensionless double-layer system, consisting of a cover and a waste layer, was also explored. The results show that a constant vacuum pressure boundary condition can be enough to describe a perforated pipe surrounded by drainage gravel with a reasonable value of well radius, such as half the radius of gravel fill. Also, the 7 independent variables (one marked with an asterisk is dimensionless) of a double-layer system can be integrated into 3 dimensionless ones: Cover permeability Kv1∗/(Vertical gas permeability of waste Kv2∗×Cover thickness h1∗),-Vacuum pressure pw×PatmKv2∗/(µRgT2×Gas generation rate of waste s2) and ln(Well radius rw∗)/(Anisotropy degree of waste k2∗). The integration is based on the inherent mechanism of this flow system with certain simplification. The effects of these variables are then quantitatively characterized for a better understanding of gas recovery efficiency. Same recovery efficiency can be achieved with different variable combinations. For example, increasing h1∗ (such as doubling it) has the same effect with decreasing Kv1∗ (such as halving it). Along with the reduction of variables by half, the integration can facilitate the preliminary design, and is a small but important advance in the consideration of MSW non-homogeneity.


Asunto(s)
Eliminación de Residuos , Instalaciones de Eliminación de Residuos , Modelos Teóricos
SELECCIÓN DE REFERENCIAS
DETALLE DE LA BÚSQUEDA