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Biochar enriched with metals has an increased potential for sorption of organic and inorganic pollutants. The aim of the research was to identify the possibility of using biochar composites produced on the basis of waste plant biomass and waste FFH (ferryferrohydrosol) containing iron atoms, after CO2 capture. The composites were produced in a one-stage or two-stage pyrolysis process. Their selected properties were determined as follows: pH, ash content, C, H, N, O, specific surface area, microstructure and the presence of surface functional groups. The produced biochar and composites had different properties resulting from the production method and the additive used. The results of experiments on the removal of methylene blue (MB) from solutions allowed us to rank the adsorbents used according to the maximum dye removal value achieved as follows: BC1 (94.99%), B (84.61%), BC2 (84.09%), BC3 (83.23%) and BC4 (83.23%). In terms of maximum amoxicillin removal efficiency, the ranking is as follows: BC1 (55.49%), BC3 (23.51%), BC2 (18.13%), B (13.50%) and BC4 (5.98%). The maximum efficiency of diclofenac removal was demonstrated by adsorbents BC1 (98.71), BC3 (87.08%), BC4 (74.20%), B (36.70%) and BC2 (30.40%). The most effective removal of metals Zn, Pb and Cd from the solution was demonstrated by BC1 and BC3 composites. The final concentration of the tested metals after sorption using these composites was less than 1% of the initial concentration. The highest increase in biomass on prepared substrates was recorded for the BC5 composite. It was higher by 90% and 54% (for doses of 30 g and 15 g, respectively) in relation to the biomass growth in the soil without additives. The BC1 composite can be used in pollutant sorption processes. However, BC5 has great potential as a soil additive in crop yield and plant growth.
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With a growing need to reduce greenhouse gas emissions, innovative carbon dioxide sorbents are being sought. One of the sorbents being tested is nanoparticle ferric hydrosol (FFH). In parallel with sorbent testing, it is also necessary to test the used sorbent after carbon dioxide capture (FFHCO2) and to develop an optimal method for its processing and management. The research described in this article evaluated the potential use of FFHCO2 in dewatering, coagulation and bioleaching processes. The research results indicate that the basic strategy for dealing with waste FFHCO2 sorbent should be to minimize the amount of waste by volume reduction-dewatering. Recycling of FFHCO2 as an iron waste coagulant or its processing products by bioleaching had no technological justification. It is only proposed to recover the material-iron compounds-if it is environmentally and economically justified.
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Peat is considered a contentious input in horticulture. Therefore, there is a search for suitable alternatives with similar properties that can be used for partial or complete peat substitution in growing media. Poultry-manure-derived biochar (PMB) is considered such an alternative. This study aimed at determining the properties of PMBs obtained through pyrolysis at selected temperatures and assessing their potentials to substitute peat in growing media based on the selected properties. The scope included the laboratory-scale pyrolysis of poultry manure at the temperatures of 425-725 °C; the determination of selected physico-chemical and physical properties of the obtained biochars, including the contaminants; and the assessment of the potentials of produced biochars to be used as peat substitutes. PMBs contained less than 36% of total organic carbon (TOC). The contents of P and K were about 2.03-3.91% and 2.74-5.13%, respectively. PMBs did not retain N. They can be safely used as the concentrations of heavy metals, polycyclic aromatic hydrocarbons (PAHs), polychlorinatd biphenyls (PCBs), dioxins, and furans are within the permissible values (except for Cr). Due to high pH (9.24-12.35), they can have a liming effect. High water holding capacity (WHC) in the range of 158-232% w/w could allow for the maintenance of moisture in the growing media. PMBs obtained at 525 °C, 625 °C, and 725 °C showed required stability (H/Corg < 0.7).
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Promising methods for managing poultry manure (PM) include converting poultry manure through pyrolysis to biochar, which can be used for soil applications. The overall goal of this study was to determine the effects of poultry manure-derived biochar and compost on the soil and growth of cherry tomatoes. The biochar obtained at 475 °C was characterized by a relatively high organic matter content of 39.47% and nitrogen content of 3.73%, while it had the lowest C/N ratio of 8.18. According to the recommendations of the EBC, the biochar obtained at 475 °C demonstrated the most beneficial effects in terms of fertilizing potential. The composting of poultry manure with the straw was successful, and the limit of 60 °C was exceeded, which allowed for the hygienization of the compost. The produced compost and biochar are sanitary safe and do not exceed the limits of heavy metal content. The lowest plant biomass was obtained from growing medium A with 3.6 g wet weight (0.24 g dry weight). The measurements of the height of cherry tomatoes showed that growing media D, E, and F allowed the plants to obtain from 602 to 654 mm in height.
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Sorption properties of various biochars have been extensively investigated by many researchers. One of the parameters that have a significant impact on sorption properties is pyrolysis temperature. This paper presents a study on the effect of pyrolysis temperature (425, 575, 725 °C) on the sorption properties of poultry-manure-derived biochar (BPM). The produced biochars, i.e., BPM425, BPM575 and BPM725, demonstrated specific properties at 425, 525 and 752 °C such as high pH (10.40, 10.65 and 12.45), high ash contents (52.07, 61.74 and 78.38%) and relatively low BET (Brunauer, Emmett and Teller) surface area (11, 17 and 19 m2·g-1). The analysis of the mineral phases of the BPMs confirmed the buffering capacity. The investigated biochars were tested for sorption of Zn, Cd and Pb in mono-, double- and triple-metal batch sorption tests. According to the obtained results, biochar produced at a temperature of 575 °C (BPM575) can function as a sufficient sorbent for the removal of Zn, Cd and Pb from a water solution. The presented results do not confirm the effect of competing metal ions on the sorption efficiency of the selected metals by the investigated biochars. Based on that, the studied biochar sorbents can be used in environments contaminated with many metals.
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Biochars produced during biodegradable waste pyrolysis are products with a wide range of environmental applications. The effect of impact biochars depends on their properties which determine the course of specific processes. The main aim of the study was to investigate the effect of pyrolysis temperature on selected properties of biochar produced from various plant wastes (beech wood chips, walnut shells, wheat-rye straw), the valorization of which is of key importance for the implementation of the circular economy. Biochars were produced at temperatures of: 400 °C, 500 °C, 600 °C and 700 °C in a nitrogen atmosphere. An increase in the pyrolysis temperature caused a drop in the biochar production yield. As the temperature increased, higher carbon content and lower hydrogen content could be seen in the products obtained. An increase in the pH and total organic carbon (TOC) values also found. The influence of temperature on ash content, observed in the case of BWS (biochar from walnut shell) and BWRS (biochar from wheat and rye straw), did not occur in the case of BWC (biochar from beech wood chips). Another parameter that demonstrated a growing tendency with increasing temperature was the BET specific surface area (except for biochars from wheat and rye straw). An increase in pyrolysis temperature caused a decrease in the diversity and density of the surface functional groups of biochars. The influence of the type of precursor used in the production of biochar on the presence of surface functional groups was demonstrated. The presence of intense stretching vibrations of C-O bonds, having a potential impact on the sorption capacity of biochars, was determined in the FTIR spectra of BWC600 and BWC700 biochars, this feature, combined with the large BET surface area, may affect the sorption potential of these biochars. The presence of this type of high-intensity vibrations was also observed in the spectra of biochar BWRS600 and BWRS700. This can compensate for the low BET surface value and play an important role when using these biochars in sorption processes for organic and inorganic compounds.
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This review aimed to analyse the current state of management practices for poultry manure in Poland and present future perspectives in terms of technologies allowing closing the loops for circular economy, and thus recovery of nutrients and energy. The scope of the review focused primarily on: (1) the analysis of poultry production and generation of poultry manure with special references to quantities, properties (e.g. fertilizing properties), seasonality, etc.; (2) the overview of current practices and methods for managing poultry manure including advantages and limitations; (3) the analysis of potential and realistic threats and risk related to managing poultry manure, and also (4) the analysis of promising technologies for converting poultry manure into added value products and energy. The review addressed the following technologies: composting of poultry manure to obtain fertilizers and soil improvers, anaerobic digestion of poultry manure for energy recovery, and also pyrolysis of poultry manure into different types of biochar that can be applied in agriculture, horticulture and industry. Poultry manure is rich in macro- and micronutrients but also can contain various contaminants such as antibiotics or pesticides, and thus posing a realistic threat to soil and living organisms when applied to soil directly or after biological treatment. The main challenge in poultry manure processing is to assure sufficient closing of carbon, nitrogen and phosphorous loops and safe application to soil.
Asunto(s)
Compostaje , Estiércol , Animales , Fertilizantes , Nitrógeno , Polonia , Aves de Corral , SueloRESUMEN
This study evaluated the content of bioavailable forms of selected heavy metals present in the waste from Zn and Pb processing that can potentially have an effect on the observed difficulties in reclamation of landfills with this waste. The particular focus of the study was on iron because its potential excess or deficiency may be one of the causes of the failure in biological reclamation. The study confirmed that despite high content of total iron in waste (mean value of 200.975gkg-1), this metal is present in the forms not available to plants (mean: 0.00009gkg-1). The study attempted to increase its potential bioavailability through preparation of the mixtures of this waste with additions in the form of sewage sludge and coal sludge in different proportions. Combination of waste with 10% of coal sludge and sewage sludge using the contents of 10%, 20% and 30% increased the amounts of bioavailable iron forms to the level defined as sufficient for adequate plant growth. The Lepidum sativum test was used to evaluate phytotoxicity of waste and the mixtures prepared based on this waste. The results did not show unambiguously that the presence of heavy metals in the waste had a negative effect on the growth of test plant roots.