RESUMEN
Abstract: This study outlines a variant of three-dimensional OH planar laser-induced fluorescence and its application in characterising a single bluff body stabilised flame inside a 12 burner annular combustor. In this variant of the method a relatively large volume was scanned slowly in order to calculate the full three-dimensional Flame Surface Density (FSD) distribution. The method used a combination of two scanning directions to overcome bias errors associated with laser sheet positions close to the flame edges. The source of this bias error was confirmed numerically through a complimentary synthetic PLIF study, which was also used to refine the experimental setup. The bias error resulted in a reduction of FSD magnitude, although the method was still capable of capturing the flame structure. This was demonstrated by comparing the reconstructions from the two independent scan directions. Combining the data from both directions overcame the bias, and allowed flame asymmetry due to the confinement to be assessed. The FSD was used to determine the heat release rate of the flame with varying local azimuthal angle for different downstream regions. This highlighted the highly asymmetric structure, produced by the asymmetric confinement.
RESUMEN
The noble gases are the most inert group of the periodic table, but their reactivity increases with pressure. Diamond-anvil-cell experiments and ab initio modelling have been used to investigate a possible direct reaction between xenon and oxygen at high pressures. We have now synthesized two oxides below 100â GPa (Xe2O5 under oxygen-rich conditions, and Xe3O2 under oxygen-poor conditions), which shows that xenon is more reactive under pressure than predicted previously. Xe2O5 was observed using X-ray diffraction methods, its structure identified through ab initio random structure searching and confirmed using X-ray absorption and Raman spectroscopies. The experiments confirm the recent prediction of Xe3O2 as a stable xenon oxide under high pressure. Xenon atoms adopt mixed oxidation states of 0 and +4 in Xe3O2 and +4 and +6 in Xe2O5. Xe3O2 and Xe2O5 form extended networks that incorporate oxygen-sharing XeO4 squares, and Xe2O5 additionally incorporates oxygen-sharing XeO5 pyramids. Other xenon oxides (XeO2, XeO3) are expected to form at higher pressures.