1.
Angew Chem Int Ed Engl
; 52(40): 10533-6, 2013 Sep 27.
Artículo
en Inglés
| MEDLINE
| ID: mdl-23946186
RESUMEN
The thermodynamics of strong coupling between molecules and the vacuum field is analyzed and the Gibbs free energy, the enthalpy, and entropy of the coupling process are determined for the first time. The thermodynamic parameters are a function of the Rabi splitting and the microscopic solvation. The results provide a new framework for understanding light-molecule strong coupling.