RESUMEN

Energy storage in electrochemical hybrid capacitors involves fast faradaic reactions such as an intercalation, or redox process occurring at a solid electrode surface at an appropriate potential. Hybrid sodium-ion electrochemical capacitors bring the advantages of both the high specific power of capacitors and the high specific energy of batteries, where activated carbon serves as a critical electrode material. Herein, we have demonstrated that a porous honeycomb structure activated carbon derived from Australian hemp hurd (Cannabis sativa L.) in aqueous Na2SO4 electrolyte showed a specific capacitance of 240 F/g at 1 A/g. The hybrid sodium-ion device employing hemp-derived activated carbon (HAC) coupled with electrolytic manganese dioxide (EMD) in an aqueous Na2SO4 electrolyte showed a specific capacitance of 95 F/g at 1 A/g having a capacitance retention of 90%. The hybrid device (HAC||EMD) can possess excellent electrochemical performance metrics, having a high energy density of 38 Wh/kg at a power density of 761 W/kg. Overall, this study provides insights into the influence of the activation temperature and the KOH impregnation ratio on morphology, porosity distribution, and the activated carbon's electrochemical properties with faster kinetics. The high cell voltage for the device is devoted to the EMD electrode.

RESUMEN

The introduction of phosphorous (P), and oxygen (O) heteroatoms in the natural honeydew chemical structure is one of the most effective, and practical approaches to synthesizing activated carbon for possible high-performance energy storage applications. The performance metrics of supercapacitors depend on surface functional groups and high-surface-area electrodes that can play a dominant role in areas that require high-power applications. Here, we report a phosphorous and oxygen co-doped honeydew peel-derived activated carbon (HDP-AC) electrode with low surface area for supercapacitor via H3PO4 activation. This activator forms phosphorylation with cellulose fibers in the HDP. The formation of heteroatoms stabilizes the cellulose structure by preventing the formation of levoglucosan (C6H10O5), a cellulose combustion product, which would otherwise offer a pathway for a substantial degradation of cellulose into volatile products. Therefore, heteroatom doping has proved effective, in improving the electrochemical properties of AC-based electrodes for supercapacitors. The specific capacitance of HDP-AC exhibits greatly improved performance with increasing carbon-to-H3PO4 ratio, especially in energy density and power density. The improved performance is attributed to the high phosphorous doping with a hierarchical porous structure, which enables the transportation of ions at higher current rates. The high specific capacitance of 486, and 478 F/g at 0.6, and 1.3 A/g in 1 M H2SO4 electrolyte with a prominent retention of 98.5 % is observed for 2 M H3PO4 having an impregnation ratio of 1 : 4. The higher yield of HDP-AC could only be obtained at an activation temperature of 500 °C with an optimized amount of H3PO4 ratio. The findings suggest that the concentration of heteroatoms as surface functional groups in the synthesized HDP-AC depends on the chosen biomass precursor and the processing conditions. This work opens new avenues for utilizing biomass-derived materials in energy storage, emphasizing the importance of sustainable practices in addressing environmental challenges and advancing toward a greener future.

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Off-grid hybrid power systems with renewable energy as the primary resource remain the best option to electrify rural/remote areas in developing countries to help attain universal electricity access by 2030. However, deploying these systems in West Africa faces several challenges and regularly fail to transition from pilot, donor-sponsored projects to sustainable large-scale implementations. The study examined the drivers and challenges by conducting a review of previous studies done in the region and a short survey in Ghana. Using Political, Economic, Social, Technical, Legal and Environmental dimensions, the review and survey showed that economic challenges have the worst impacts on the sustainable development of off-grid renewable energy-based power systems in WA. Further, the analysis revealed patterns and linkages among the challenges that make it detrimental to focus solely on the most pressing challenges.

RESUMEN

Renewable energy generation and increased electrification are pivotal to reducing greenhouse gas emissions and mitigating climate change. Consequently, global deployment of wind turbines has soared, and the trend is expected to continue. Installed turbines have only recently started reaching the end of their design lives, and waste volumes are projected to escalate rapidly. Approximately 94% of a wind turbine (by mass) is recyclable, but the waste polymer composite blades are most commonly landfilled. This mini-review aims to review current end-of-life (EoL) management practices in the large-scale wind industry for countries with established EoL standards as well as those with less mature regulations. Data on current EoL management practices, initiatives and regulations in industry was sourced primarily from literature reviews and publicly available internet information. Additional insights and perspectives were gained from WindEurope's EoL Issues and Strategies 2020 seminar and through communication with select individuals from various sectors such as wind energy development and operations, government, industry associations, academia and research organizations. The results show that the decision on EoL options is dictated by the remaining useful life (RUL) of the wind turbines, prevailing policies and electricity prices. The contribution of this article is, firstly, identifying a number of key technical, economic and regulatory questions that must be asked before deciding on the most appropriate EoL option. Secondly, the article identifies factors that impede current EoL management efforts to close the circular economy gap and those that can support sustainable technology deployment. Finally, the article considers the way that countries with a young fleet of wind farms may learn from more experienced nations. There are few proven business cases, and barriers to the profitability and effectiveness of EoL strategies include uncertainty about the assets' RUL, collection logistics, the size of wind farm operation margins, low waste feedstock and limited markets for recycled products. Designing for circularity, stakeholder collaboration, circular business models and technology-specific regulations can improve EoL sustainability. The research found that wind turbine EoL management is dynamic and complex and needs to consider multiple, often conflicting factors. However, it is necessary and has immense environmental, technical and economic potential as the industry matures and business cases are proven.

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RESUMEN

Nickel-based bimetallic oxides (BMOs) have shown significant potential in battery-type electrodes for pseudo-capacitors given their ability to facilitate redox reactions. In this work, two bimetallic oxides, NiMoO4 and NiWO4, were synthesized using a wet chemical route. The structure and electrochemical properties of the pseudo-capacitor cathode materials were characterized. NiMoO4 showed superior charge storage performance in comparison to NiWO4, exhibiting a discharge capacitance of 124 and 77 F.g-1, respectively. NiMoO4, moreover, demonstrates better capacity retention after 1000 cycles with 87.14% compared to 82.22% for NiWO4. The lower electrochemical performance of the latter was identified to result from the redox behavior during cycling. NiWO4 reacts in the alkaline solution and forms a passivation layer composed of WO3 on the electrode, while in contrast, the redox behavior of NiMoO4 is fully reversible.