RESUMEN
A three-component 1,4-alkylarylation of 1,3-enynes with organic halides through the combination of nickel and photoredox catalysis has been established, providing a novel and modular approach for the assembly of tetrasubstituted allenes. This reductive cascade cross-electrophile reaction obviates the need for air-sensitive organometallic reagents and stoichiometric metallic reductants. A diverse range of functional groups are very compatible under mild reaction conditions and give satisfactory yields. Moreover, a reasonable mechanism is presented according to a series of control experiments.
RESUMEN
A CuBr2-catalyzed annulation of 2-bromo-N-arylbenzimidamide with selenium/sulfur powder for the synthesis of benzo[d]isoselenazole and benzo[d]isothiazole in generally good yields was investigated. This synthetic strategy features good substrate scope and functional group tolerance. Furthermore, the corresponding products could be converted into N-aryl indoles via rhodiumIII-catalyzed ortho C-H activation of the N-phenyl ring, providing an efficient approach for axial aromatic molecules.
RESUMEN
The dewatering of waste activated sludge by integrated hydrodynamic cavitation (HC) and Fenton reaction was explored in this study. We first investigated the effects of initial pH, sludge concentration, flow rate, and H2O2 concentration on the sludge dewaterability represented by water content, capillary suction time and specific resistance to filtration. The results of dewatering tests showed that acidic pH and low sludge concentration were favorable to improve dewatering performance in the HC/Fenton system, whereas optimal flow rate and H2O2 concentration applied depended on the system operation. To reveal the synergism of HC/Fenton treatment, a suite of analysis were implemented: three-dimensional excitation emission matrix (3-DEEM) spectra of extracellular polymeric substances (EPS) such as proteins and polysaccharides, zeta potential and particle size of sludge flocs, and SEM/TEM imaging of sludge morphology. The characterization results indicate a three-step mechanism, namely HC fracture of different EPS in sludge flocs, Fenton oxidation of the released EPS, and Fe(III) re-flocculation, that is responsible for the synergistically enhanced sludge dewatering. Results of current study provide a basis to improve our understanding on the sludge dewatering performance by HC/Fenton treatment and possible scale-up of the technology for use in wastewater treatment plants.