RESUMEN
The United Nations General Assembly explicitly recognized the human right to water and sanitation and acknowledged that drinking water is essential to the realization of all human rights in a 2010 resolution. Supporting and strengthening the quality infrastructure in countries throughout the world guarantees more reliable water quality analyses, thus reducing the risks to consumers' health. The present paper describes a multilateral cooperation project developed in Nicaragua to improve the country's quality infrastructure and, in turn, the quality control of drinking water. The project was developed with the support of National Metrology Institutes (NMIs) from the Inter-American Metrology System (SIM), the Physikalisch Technische Bundesanstalt (PTB) and the participation of research institutes and laboratories in Nicaragua. Several mechanisms such as awareness seminars, workshops, metrological screenings, peer review of the laboratories' quality systems, and organizing proficiency testing (PT) were used to successfully achieve the cooperation goal. As a result, technical infrastructure for the organization of PT rounds in Nicaragua was implemented to evaluate the relevant physicochemical parameters such as pH, chloride (Cl-), and nitrate (NO3-) in drinking water. The results from the PT rounds which took place during the two-year cooperation project showed substantial improvement in the performances of the participating laboratories, and therefore, in their measurement methods. Finally, this article shows how multilateral cooperation projects can strengthen the quality infrastructure, improving and ensuring the quality control of drinking water.
RESUMEN
The quantification of Cr (VI) in the cement matrix is highly important, given the possibility of suffering illnesses including dermatitis, induced nasal carcinoma, and DNA damage produced by inhalation of and/or direct contact with this substance by construction workers. This study presents an analytical validation of the determination of water-soluble Cr (VI) using Ultraviolet-Visible Spectroscopy (UV-Vis) with 1.5-diphenylcarbazide. To do so, different performance characteristics were determined: working interval, analytical sensitivity, linearity, limits of detection (LOD) and quantification (LOQ), as well as measurement uncertainty, in order to provide better metrological information about the performance of this method. The study also focused on evaluating the impact of use of different types of standard sands (ASTM C-778 and CEN) for preparing mortar cement and extracting water soluble Cr (VI) present in the cement. For this purpose, two cements with different concentrations (2.01 ± 0.21 and 0.75 ± 0.09 mg-kg-1) of Cr (IV) were created to evaluate extraction using three types of treatments: oxidized with potassium peroxidisulfite, non-oxidized, and an alternative method using cement paste. It was observed that mortar cement using ASTM C-778 sand tends to underestimate Cr (IV) content when concentrations are below 0.8 mg kg-1, while at higher concentrations of ~2.0 mg kg-1 it does not generate different results compared to those obtained using mortar cement made with CEN-standard sand. An alternative method called "paste extraction" also showed statistically comparable results with respect to standard mortar for both concentration levels evaluated. Finally, samples of cement marketed in Costa Rica were analyzed using different types of water soluble Cr (IV) extraction methods. The results show concentrations between 0.70 ± 0.13 mg kg-1 and 1.30 ± 0.13 mg kg-1, demonstrating that they comply with the limits established by international standards and national regulations in Costa Rica.