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J Photochem Photobiol B ; 193: 118-130, 2019 Apr.
Artículo en Inglés | MEDLINE | ID: mdl-30849710

RESUMEN

TiO2-ZnO heterogeneous catalytic system provides a good replacement of a homogeneous catalytic reaction due to its easier recovery. In this study, biodiesel was produced from Ulva lactuca seaweeds using TiO2-ZnO nanocomposite catalysts with particle size of ~12 nm. The size controlled TiO2-ZnO nanocomposite was characterized by powder XRD analysis and TEM. The result of that TiO2-ZnO catalyst is a promising catalyst for the production of biodiesel under mild reaction conditions and high yield of hydroxydecanoic acid conversion of 82.8%. The various conditions optimized for the higher conversion to FAME (15.8 ml of FAME) were 4 wt% catalysts at 4 h under 60 °C and further there is no increase of conversion to FAME above 60 °C-80 °C. The total product yield was calculated as 82.8% of conversion to FAME. The evaluated biodiesel was found to be up to the mark of ASTM standards. The silver nanoparticles (AgNPs) were synthesized by using leftover biomass of algae obtaining after lipid extraction of U.lactuca. AgNPs particle size was achieved as ~12 nm and was confirmed by UV-Visible spectroscopy, XRD and TEM analysis. Antibacterial activities of the synthesized AgNPs were analyzed and compared. The antibacterial activity was excellent against bacterial pathogens and treatment against P. vulgaris shows the maximum zone of inhibition (13.8 mm). The present work identified that the unutilized bioresource such as U.lactuca can be effectively utilized for biodiesel production so as to replace fossil fuel usage.


Asunto(s)
Antiinfecciosos/química , Biocombustibles , Nanopartículas del Metal/química , Nanocompuestos/química , Plata/química , Ulva/metabolismo , Óxido de Zinc/química , Antiinfecciosos/farmacología , Bacillus subtilis/efectos de los fármacos , Biocombustibles/análisis , Catálisis , Farmacorresistencia Bacteriana Múltiple/efectos de los fármacos , Cromatografía de Gases y Espectrometría de Masas , Klebsiella pneumoniae/efectos de los fármacos , Lípidos/análisis , Nanopartículas del Metal/toxicidad , Tamaño de la Partícula , Titanio/química , Ulva/química
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