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ScientificWorldJournal ; 2012: 168148, 2012.
Artículo en Inglés | MEDLINE | ID: mdl-22619610

RESUMEN

In the present work, known concentration of sulfite aqueous solutions in the presence and absence of gallic acid was measured to corroborate the validity of modified Monier-Williams method. Free and bound-sulfite was estimated by differential pulse voltammetry. To our surprise, the modified Monier-Williams method (also known as aspiration method) showed to be very inaccurate for free-sulfite, although suitable for bound-sulfite determination. The differential pulse approach, using the standard addition method and a correction coefficient, proved to be swift, cheap, and very precise and accurate.


Asunto(s)
Técnicas Electroquímicas , Sulfitos/análisis , Agua/química , Soluciones
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