RESUMEN
Pultrusion is a highly efficient continuous process to manufacture advanced fiber-reinforced composites. The injection pultrusion variant permits a higher control of the resin flow, enabling the manufacturing of a high reinforcement volume fraction. Moreover, it reduces the emission of volatile compounds that are dangerous for the operators and for the working environment. The present study proposes an experimental analysis of injection pultrusion in three different operative conditions. In particular, the activity focused on the effects of the temperature setup on the thermochemical and rheological behaviors of the resin system and on the interaction between the processed materials and the pultrusion die wall. The setup of the parameters was selected to evidence the behavior of the viscous interaction during the thermoset transition to the solid state, which is particularly challenging due to the localization of high adhesive forces related to the sharp increase in resin viscosity. Microscope observations of the cross-sections were performed to discuss the effects of the process parameters.
RESUMEN
The present work focuses on the pultrusion of pre-impregnated glass-reinforced polypropylene tapes. An appositely designed laboratory-scale pultrusion line, consisting of a heating/forming die and a cooling die, was used. The temperature of the advancing materials and the pulling force resistance were measured by using thermocouples embedded in the pre-preg tapes and a load cell. From the analysis of the experimental outcomes, we gained insight into the nature of the material-machinery interaction and the transitions of the polypropylene matrix. The cross-section of the pultruded part was analyzed by microscope observation to evaluate the distribution of the reinforcement inside the profile and the presence of internal defects. Three-point bending and tensile testing were conducted to assess the mechanical properties of the thermoplastic composite. The pultruded product showed good quality, with an average fiber volume fraction of 23% and a limited presence of internal defects. A non-homogenous distribution of fibers in the cross-section of the profile was observed, probably due to the low number of tapes used in the present experimentation and their limited compaction. A tensile modulus and a flexural modulus of 21.5 GPa and 15.0 GPa, respectively, were measured.
RESUMEN
Cure-induced deformations are inevitable in pultruded composite profiles due to the peculiarities of the pultrusion process and usually require the use of costly shimming operations at the assembly stage for their compensation. Residual stresses formed at the production and assembly stages impair the mechanical performance of pultruded elements. A numerical technique that would allow the prediction and reduction of cure-induced deformations is essential for the optimization of the pultrusion process. This study is aimed at the development of a numerical model that is able to predict spring-in in pultruded L-shaped profiles. The model was developed in the ABAQUS software suite with user subroutines UMAT, FILM, USDFLD, HETVAL, and UEXPAN. The authors used the 2D approach to describe the thermochemical and mechanical behavior via the modified Cure Hardening Instantaneous Linear Elastic (CHILE) model. The developed model was validated in two experiments conducted with a 6-month interval using glass fiber/vinyl ester resin L-shaped profiles manufactured at pulling speeds of 200, 400, and 600 mm/min. Spring-in predictions obtained with the proposed numerical model fall within the experimental data range. The validated model has allowed authors to establish that the increase in spring-in values observed at higher pulling speeds can be attributed to a higher fraction of uncured material in the composite exiting the die block and the subsequent increase in chemical shrinkage that occurs under unconstrained conditions. This study is the first one to isolate and evaluate the contributions of thermal and chemical shrinkage into spring-in evolution in pultruded profiles. Based on this model, the authors demonstrate the possibility of achieving the same level of spring-in at increased pulling speeds from 200 to 900 mm/min, either by using a post-die cooling tool or by reducing the chemical shrinkage of the resin. The study provides insight into the factors significantly affecting the spring-in, and it analyzes the methods of spring-in reduction that can be used by scholars to minimize the spring-in in the pultrusion process.