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Fabrication of dense aluminum (Al-1100) parts (>99.3% of relative density) by our recently developed laser-foil-printing (LFP) additive manufacturing method was investigated as described in this paper. This was achieved by using a laser energy density of 7.0 MW/cm2 to stabilize the melt pool formation and create sufficient penetration depth with 300 µm thickness foil. The highest yield strength (YS) and ultimate tensile strength (UTS) in the LFP-fabricated samples reached 111 ± 8 MPa and 128 ± 3 MPa, respectively, along the laser scanning direction. These samples exhibited greater tensile strength but less ductility compared to annealed Al-1100 samples. Fractographic analysis showed elongated gas pores in the tensile test samples. Strong crystallographic texturing along the solidification direction and dense subgrain boundaries in the LFP-fabricated samples were observed by using the electron backscattered diffraction (EBSD) technique.

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A method employing an integrated femtosecond (fs) and nanosecond (ns) dual-laser system was developed to generate plasma with desired radical species from gas mixtures via a fs laser pulse and then to excite selected radical species to higher electronic states using a wavelength-tunable ns laser pulse. An optical spectrometer was used to measure the emission spectra and identify the transition from the excited electronic state to the ground state. The proposed technique has been demonstrated for an N2-CO2 mixture with various time delays between the two fs and ns pulses. The results have indicated that the population of selected radical species at the excited electronic state can be increased using the subsequent ns laser pulse, which also enhances the intensity of emission spectra allowing better identifications of the radical species. This technique holds a promise of detection and identification of signature plasma species, particularly for trace elements and long-distance standoff detections.

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A real-time and real-space time-dependent density functional is applied to simulate the nonlinear electron-photon interactions during shaped femtosecond laser pulse train ablation of diamond. Effects of the key pulse train parameters such as the pulse separation, spatial/temporal pulse energy distribution and pulse number per train on the electron excitation and energy absorption are discussed. The calculations show that photon-electron interactions and transient localized electron dynamics can be controlled including photon absorption, electron excitation, electron density, and free electron distribution by the ultrafast laser pulse train.

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A fiber inline Mach-Zehnder interferometer (MZI) consisting of ultra-abrupt fiber tapers was fabricated through a new fusion-splicing method. By fusion-splicing, the taper diameter-length ratio is around 1:1, which is much greater than those (1:10) made by stretching. The proposed fabrication method is very low cost, 1/20-1/50 of those of LPFG pair MZI sensors. The fabricated MZIs are applied to measure refractive index, temperature and rotation angle changes. The temperature sensitivity of the MZI at a length of 30 mm is 0.061 nm/°C from 30-350 °C. The proposed MZI is also used to measure rotation angles ranging from 0° to 0.55°; the sensitivity is 54.98 nm/°. The refractive index sensitivity is improved by 3-5 fold by fabricating an inline micro-trench on the fiber cladding using a femtosecond laser. Acetone vapor of 50 ppm in N(2) is tested by the MZI sensor coated with MFI-type zeolite thin film. The proposed MZI sensors are capable of in situ detection in many areas of interest such as environmental management, industrial process control, and public health.

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A non-equilibrium molecular dynamics model is developed to investigate how a thin film confined between two dissimilar solids affects the thermal transport across the material interface. For two highly dissimilar (phonon frequency mismatched) solids, it is found that the insertion of a thin film between them can greatly enhance thermal transport across the material interface by a factor of 2.3 if the thin film has one of the following characteristics: (1) a multi-atom-thick thin film of which the phonon density of states (DOS) bridges the two different phonon DOSs for the solid on each side of the thin film; (2) a single-atom-thick film which is weakly bonded to the solid on both sides of the thin film. The enhanced thermal transport in the single-atom-thick film case is found mainly due to the increased inelastic scattering of phonons by the atoms in the film. However, for solid-solid interfaces with a relatively small difference in the phonon DOS, it is found that the insertion of a thin film may decrease the thermal transport.

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We report a simple and repeatable method for fabricating a large-area substrate for surface-enhanced Raman scattering. The substrate was processed by three steps: (i) femtosecond (fs) laser micromachining and roughening, (ii) thin-film coating, and (iii) nanosecond laser heating and melting. Numerous gold nanoparticles of various sizes were created on the surface of the silicon substrate. The 3D micro-/nanostructures generated by the fs laser provide greater surface areas with more nanoparticles leading to 2 orders of magnitude higher of the enhancement factor than in the case of a flat substrate. Using an He-Ne laser with a 632.8 nm excitation wavelength, the surface-enhanced Raman scattering enhancement factor for Rhodamine 6G was measured up to 2×10(7).

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The Brownian motion and aggregation of particles in nanofluids often lead to the formation of solid-film-solid structures. The molecular thin film confined between nanoparticles may have non-negligible effects on thermal conduction among nanoparticles. Using nonequilibrium molecular dynamics simulations, we study thermal conduction across the Ag particle-Ar thin-film interface. If the film contains only one molecular layer, we find that the solid-film interfacial thermal resistance R(SF) is about 1 order of magnitude smaller than the solid-liquid (bulk) interfacial thermal resistance R(SL). If there are two or more molecular layers in the film, it is shown that R(SF) increases rapidly toward R(SL) as film thickness increases. By comparing the vibrational density of states of Ag atoms and Ar molecules in the film, we demonstrate that the low thermal resistance in the monolayer film case is caused by the resonant thermal transport between Ag particles and Ar thin films.

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This study performs a detailed theoretical analysis of refractive index (RI) sensors based on whispering gallery modes (WGMs) in liquid core optical ring resonators (LCORRs). Both TE- and TM-polarized WGMs of various orders are considered. The analysis shows that WGMs of higher orders need thicker walls to achieve a near-zero thermal drift, but WGMs of different orders exhibit a similar RI sensing performance at the thermostable wall thicknesses. The RI detection limit is very low at the thermostable thickness. The theoretical predications should provide a general guidance in the development of LCORR-based thermostable RI sensors.

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Thermal conductivity of interfacial layers is an essential parameter for determining how the ordered liquid layering around the particle-liquid interface contributes to the unusual high thermal conductivity of nanofluids. However, so far there is no experimental data regarding this parameter. Using nonequilibrium molecular dynamics simulations of an inhomogeneous Au-Ar system in which the solid-liquid interactions are assumed to be much stronger than the liquid-liquid interactions, we show explicitly that the thermal conductivity of a 1-nm-thick interfacial layer is 1.6 ∼ 2.5 times higher than that of the base fluid. The simulation results are incorporated into a three-level clustering model to calculate the effective thermal conductivity of nanofluids. The results show that the contribution of the interfacial layer to thermal conductivity enhancements should be considered if there are particle clusters in nanofluids.

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During new fiber sensor development experiments, an easy-to-fabricate simple sensing structure with a trench and partially ablated fiber core is fabricated by using an 800 nm 35 fs 1 kHz laser. It is demonstrated that the structure forms a Mach-Zehnder interferometer (MZI) with the interference between the laser light passing through the air in the trench cavity and that in the remained fiber core. The fringe visibilities are all more than 25 dB. The transmission spectra vary with the femtosecond (fs) laser ablation scanning cycle. The free spectral range (FSR) decreases as the trench length increases. The MZI structure is of very high fabrication and sensing repeatability. The sensing mechanism is theoretically discussed, which is in agreement with experiments. The test sensitivity for acetone vapor is about 10(4) nm/RIU, and the temperature sensitivity is 51.5 pm/°C at 200 ∼ 875 °C with a step of 25 °C.

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We report a surface-enhanced Raman scattering (SERS) microchip that is capable of measuring SERS signals of liquid samples with high sensitivity. The microdevice is an integration of a silicon-based SERS substrate, a multimode optical fiber (MMF), and a microchannel embedded in the photosensitive glass fabricated by the femtosecond laser followed by thermal treatment, wet etching, and annealing. The performance of the SERS microchip is evaluated by measuring rhodamine 6G using a 632.8 nm He-Ne laser at 4.3 mW excitation power, which reveals that the detection limit is lower than 10(-10) M at a 1 s short accumulation time.

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We have conducted experimental investigations for the micromachining of dielectrics (fused silica) using an integrated femtosecond (fs) and nanosecond (ns) dual-beam laser system at different time delays between the fs and ns pulses. We found that the maximum ablation enhancement occurs when the fs pulse is shot near the peak of the ns pulse envelope. Enhancements up to 13.4 times in ablation depth and 50.7 times in the amount of material removal were obtained, as compared to fs laser ablation alone. The fs pulse increases the free electron density and changes the optical properties of fused silica to have metallic characteristics, which increases the absorption of the ns laser energy. This study provides an opportunity for efficient micromachining of dielectrics.

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A rapid and simple approach to fabricate a large area of nanostructured substrate for surface-enhanced Raman scattering (SERS) is reported. Gold nanoparticles ranging from 10 to 40 nm in diameter uniformly distributed on a silicon substrate were obtained by annealing the gold film precoated on the silicon substrate with UV nanosecond (ns) laser pulses. The gold nanoparticles were formed by surface tension of the melted gold layer heated by ns laser pulses. The enhancement factor of the SERS substrate for Rhodamine 6G at 632.8 nm excitation was measured to be higher than 10(5). The proposed technique provides the opportunity to equip a functional microchip with SERS capability of high sensitivity and chemical stability.

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This paper reports an efficient fabrication of nanostructures on silicon substrates for surface-enhanced Raman scattering (SERS). Silicon wafer substrates in the aqueous solution of silver nitrate were machined by the femtosecond laser direct writing to achieve simultaneously in one-step the generation of grating-like nanostructures on the surface of the substrate and the formation of silver nanoparticles on the surface of the nanostructures via the laser-induced photoreduction effect. Parametric studies were conducted for the different concentrations of aqueous silver nitrate solutions and scanning speeds. The enhancement factor of the SERS is found to be higher than 10(9). The patterning technique provides an opportunity to incorporate the SERS capability in a functional microchip.

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We report what we believe to be a new method to fabricate surface enhanced Raman scattering (SERS) fiber probe by direct femtosecond laser micromachining. Direct femtosecond laser ablations resulted in nanostructures on the cleaved endface of a multimode optical fiber with a 105/125 microm core/cladding diameter. The laser-ablated fiber endface was SERS activated by silver chemical plating. High-quality SERS signal was detected using Rhodamine 6G molecules (10(-8)-10(-6) M solutions) via back excitation with the fiber length of up to 1 m. The fiber SERS probe was compared with a planar fused silica substrate at a front excitation. The long lead-in fiber length and the backexcitation/collection setup make the SERS probe promising for remote sensing applications.

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We report a simple Fabry-Perot interferometer (FPI) embedded in a glass chip, which is capable of precisely measuring the refractive indices of liquid samples. The microdevice is the integration of a single-mode optical fiber and a microchannel in the photosensitive glass fabricated by femtosecond laser followed by thermal treatment, wet etching, and annealing. The function of the FPI is demonstrated by measuring the refractive indices of water and methanol. The interference visibility is more than 4.0 dB, which is sufficient for most sensing applications. This refractive index sensor with rigid structure could be further integrated to become a more complex 3D lab-on-a-chip for reliable biomedical applications.

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We report a miniaturized fiber inline Fabry-Perot interferometer (FPI), with an open micro-notch cavity fabricated by one-step fs laser micromachining, for highly sensitive refractive index measurement. The device was tested for measurement of the refractive indices of various liquids including isopropanol, acetone and methanol at room temperature, as well as the temperature-dependent refractive index of deionized water from 3 to 90 degrees C. The sensitivity for measurement of refractive index change of water was 1163 nm/RIU at the wavelength of 1550 nm. The temperature cross-sensitivity of the device was about 1.1x10(-6) RIU/degrees C. The small size, all-fiber structure, small temperature dependence, linear response and high sensitivity, make the device attractive for chemical and biological sensing.

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We report a miniaturized inline Fabry-Perot interferometer directly fabricated on a single-mode optical fiber with a femtosecond laser. The device had a loss of 16 dB and an interference visibility exceeding 14 dB. The device was tested and survived in high temperatures up to 1100 degrees C. With an accessible cavity and all-glass structure, the new device is attractive for sensing applications in high-temperature harsh environments.