RESUMEN

The complex was prepared with preyssler polyoxoanion and transition metal (Mo), a cationic surfactant as a connector. It has tuneable physical and chemical potential which has been exploited to study novel properties. A new technique of shock wave impulses is also used on the Mo-PHP complex. Extensive use of cationic surfactants could impact accumulation in the environment set off the surfacing of bacterial resistance. Due to the electrostatic binding to bacterial surface, the hydrophobic parts of cationic surfactants tend to penetrate bacterial cell walls and may cause membrane lysis and bacteria death. The surfactant-supported and direct release of metal ions from P5W29Mo against bacterial resistance has been explained schematically. The dielectric study helps to understand the dissociation of cations that generate polarons and the hopping mechanism with neighbouring vacant atomic sites. Structural analysis confirms the formation of cationic surfactant incorporated polyoxoanion (Mo-PHP). A hexagonal shape-like structure for the PHP complex has been observed. The Mo-incorporated PHP complex was characterized using UV-visible (UV), Fourier Transform-infrared (IR), Raman spectra, scanning electron microscope (SEM), energy dispersive spectroscopy (EDS), and X-ray diffraction (XRD) techniques.

RESUMEN

A novel keggin-type tetra-metalates substituted polyoxometalate was functionalized by 3-(aminopropyl)-imidazole (3-API) supporting a ligand substitution method. In this paper, polyoxometalate (POMs) (NH4)3 [PMo12O40] and transition metal substituted of (NH4)3 [{PMIVMo11O40}.(H2O)] (M = Mn, V) are used as one of the adsorbents. The 3-API/POMs hybrid have been synthesized and used as adsorbent for the photo-catalysis of azo-dye molecule degradation after visible-light illumination as a simulated organic contaminant in water. The transition metal (M = MIV, VIV) substituted keggin-type anions (MPOMs) were synthesized, which reveals the degradation of methyl orange (MO) of about 94.0 % and 88.6 %. Immobilizing high redox ability POMs as an efficient acceptor of photo generated electron, on metal 3-API. In the presence of visible light irradiation result reveals that 3-API/POMs (89.9 %) have incredibly achieved after certain irradiation time and at specific conditions (3)-API/POMs; photo-catalysts dose = 5mg/100 ml, pH = 3 and MO dye concentration = 5 ppm). As the surface of POM catalyst has strong absorption of azo-dye MO molecule engaged as a molecular exploration through photo catalytic reactant. From the SEM images it is clear that the synthesized POMs based materials and POMs conjugated MO have varieties of morphological changes observed such as flakes, rods and spherical like structures. Anti-bacterial study reveals that the process of targeted microorganism occur higher activity against pathogenic bacterium for 180 min of visible-light irradiation is measured in terms of zone of the inhibition. Furthermore, the photo catalytic degradation mechanism of MO using POM, metaled POMs and 3-API/POMs also has been discussed.

Asunto(s)

Colorantes , Luz , Colorantes/química , Aniones , Imidazoles/farmacología

RESUMEN

In order to overcome the challenges of low permeate flux (Jp) and the accompanying reverse solute flux (JS) during the forward osmosis (FO) membrane separation process, we synthesized four hybrid materials of polyacid-based organic compounds and incorporated them into the selective polyamide (PA) layer to make novel thin-film nanocomposite (TFN) FO membranes. The Jp and JS of each membrane were evaluated and used along with membrane selectivity (Jp/JS) as indicators of membrane separation performance. The fabricated and modified membranes were also characterized for ridge and valley surface morphologies with increasing hydrophilicity and finger-shaped parallel channels in the PSf substrate. Moreover, two highly hydrophilic nanoparticles of graphene oxide (GO) and titanium oxide (TiO2) were introduced with the hybrid materials for PA modification, which can further enhance the Jp of the TFN membranes. The highest Jp of the TFN membranes achieved 12.1 L/m2-h using 0.1% curcumin-acetoguanamine @ cerium polyacid (CATCP) and 0.0175% GO. The characteristic peaks of the hybrid materials were detected on the membrane surface using attenuated total reflectance Fourier transform infrared (ATR-FTIR) spectroscopy, evidencing successful incorporation of the hybrid materials during membrane modification. Here, we present the novel TFN membranes using hybrid materials for separation applications. The reactions for synthesizing the hybrid materials and for incorporating them with PA layer are proposed.