RESUMEN

P25/PBP (TiO2, anthocyanins) prepared by combining PBP (blueberry peels) with P25, and N-doped porous carbon-supported Ni nanoparticles (Ni@NPC-X) prepared using blueberry-derived carbon were used for the application as photoanode and the counter electrode, respectively, in dye-sensitized solar cells (DSSCs) to create a new perspective for blueberry-based photo-powered energy systems. PBP was introduced into the P25 photoanode and carbonized to form a C-like structure after annealing that improved its adsorption capacity for N719 dye, contributing a 17.3% higher power conversion efficiency (PCE) of P25/PBP-Pt (5.82%) than that of P25-Pt (4.96%). The structure of the porous carbon changes from a flat surface to a petal-like structure due to the N doping by melamine, and the specific surface area increases. N-doped three-dimensional porous carbon supported the loading and reduced the agglomeration of Ni nanoparticles, reducing the charge transfer resistance, and providing a fast electron transfer path. The doping of Ni and N on the porous carbon worked synergistically to enhance the electrocatalytic activity of the Ni@NPC-X electrode. The PCE of the DSSCs assembled by Ni@NPC-1.5 and P25/PBP was 4.86%. Also, the Ni@NPC-1.5 electrode exhibited 116.12 F g-1 and a capacitance retention rate of 98.2% (10 000 cycles), further confirming good electrocatalysis and cycle stability.

RESUMEN

The biomass-based inter-transmission network architecture is expected to act on all-solid-state supercapacitors (ASSSCs) by building excellent conductive paths and achieving high ionic conductivity to promote their development as future electronic devices. Here, biomass-derived hybrid organogel electrodes constructed by incorporating polyaniline (PANI) into cellulose/dealkaline lignin (C/DL) film architectures exhibit an impressive specific capacitance (582 F g-1 at 1 A g-1) due to the effective dispersion and doping of PANI. Moreover, the specific capacitance of the best C/DL-PANI electrode is nearly 19 times higher than that of a cellulose-PANI electrode, which is attributed to the contribution of DL to the pseudocapacitance. ASSSCs assembled using the C/DL-PANI electrodes and the DL gel electrolyte exhibit excellent specific capacitance (344 F g-1 at 1 A g-1), Coulombic efficiency (∼100% for 5000 cycles), cycle stability (85.7% for 5000 cycles at 1 A g-1), and energy density (58.1 W h kg-1 at 0.5 kW kg-1). The ASSSCs showed a comparable or even higher electrochemical performance than the reported PANI-based or biomass-based ASSSCs, which can be due to the conductive network of the biomass-derived electrodes, the migration of ions between the electrodes through the gel electrolyte ion pathway, and the interfacial synergy. This innovative work paves the way for the development of ASSSC applications based on biomass materials.

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RESUMEN

The development of high-performance shape-stable phase change material composites (SPCMs) with high phase change enthalpy and high conversion efficiency, especially with good photochromic properties, is essential for thermal energy storage. Here, we report that one type of SPCMs with both photochromic and phase change energy storage is obtained by incorporating organic binary composite PCMs (hexadecanol/coconut oil, H/C) and photochromic phosphotungstic acid (PA) into Ochroma pyramidale wood-based cellulose microframe (DOW) through simple vacuum impregnation. When the ratio of hexadecanol to coconut oil is 3:7 and the ratio of phosphotungstic acid to N,N-dimethylacetamide is 4:13.6, the SPCM composite material (DOW-H3C7-4PA) represents a high phase transition enthalpy of 163.7 J/g and an appropriate phase transition temperature of 42.55 °C that can be applied to the environmental temperature adjustment of high-temperature areas (>40 °C) mentioned in this paper, in addition to the excellent thermal stability and photochromic stability; for example, even after 100 thermal cycles and UV radiation cycles, its phase transition enthalpy remains almost unchanged. The DOW-H3C7-4PA composite material also shows good shape stability and leakage resistance. In addition, the high photothermal conversion efficiency (65.71%) of DOW-H3C7-4PA is considered to be a promising candidate for photothermal energy storage applications. Therefore, the manufactured SPCMs (DOW-H3C7-4PA) have high latent heat, good melting/freezing cycle reliability, high photochromic stability, and remarkable light-to-heat energy conversion ability, making them show broad application prospects in energy conversion and storage devices.

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