1.
Angew Chem Int Ed Engl
; 55(4): 1523-6, 2016 Jan 22.
Artículo
en Inglés
| MEDLINE
| ID: mdl-26636435
RESUMEN
Two new catalytic systems for hydrogen-atom transfer (HAT) catalysis involving the N-H bonds of titanocene(III) complexes with pendant amide ligands are reported. In a monometallic system, a bifunctional catalyst for radical generation and reduction through HAT catalysis depending on the coordination of the amide ligand is employed. The pendant amide ligand is used to activate Crabtree's catalyst to yield an efficient bimetallic system for radical generation and HAT catalysis.