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The study reports the development of a liquid smoke solution of rice husk ash (RHA) as a green corrosion inhibitor in NH4Cl solution in approaching corrosion protection for refinery facilities. The recent utilization of RHA has a partial solution to address the possible chemical to form a filming layer to disconnect bare metal and their environment. This work prepared the RHA solution by condensing the RHA vapor before adding it to various concentrations. The corrosion test of potentiodynamic and electrochemicals intends to discover the inhibitor's corrosion resistance before examining the electronic transition corresponding to the contribution of several functional groups using Ultraviolet Visible (UV-Vis) and Fourier-Transform Infrared Spectroscopy (FTIR). Surface evaluation intends to unveil the nature of the corrosion by utilizing the Scanning Electronic and Atomic Force Microscope. The corrosion test result shows the depression of corrosion rate to 0.120 mmpy with high efficiency beyond 96 % in the addition of 7.5 ppm RHA inhibitor. The greater Nyquist semicircle diameter at high concentrations increases the adsorption of the RHA on the surface of C1018. The electronic transition of n-π* and π -π* shows an extensive contribution of C[bond, double bond]C, C[bond, double bond]O, and -OH based on the UV-Vis and FTIR test. The formation of a complex compound of Fe-(NH4Cl-RHA)n blocks the corrosion active sites to reduce the corrosion. This study paves the way for using RHA as an organic compound under NH4Cl conditions, such as in a refinery process facility.

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The research proposes a new model for evaluating offshore pipelines due to corrosion. The existing inspection method has an inherent limitation in reusing the primary root cause analysis data to forecast the potential loss and corrosion mitigation, particularly in the scope of data utilization. The study implements Artificial Intelligence to transfer the knowledge of failure analysis as a consideration for conducting the inspection and lowering the risk of failure. This work combines experimental and modelling methodologies to assert the actual and feasible inspection method. The elemental composition, hardness, and tensile tests are utilized to unveil the types of corrosion products and metallic properties. Scanning Electronic Microscope and Energy Dispersive X-Ray (SEM-EDX) and X-Ray Diffractometer (XRD) was utilized to assess the corrosion product and their corresponding morphology to reveal the corrosion mechanism. The Gaussian Mixture Model (GMM), aided by the Pearson Multicollinear Matrix, shows the typical risk and predicts the damage mechanism of the spool to suggest the types of mitigation scenarios for the pipeline's longevity. According to the laboratory result, the wide and shallow pit corrosion and channelling are evident. The result of the tensile and hardness test confirms the types of the API 5 L X42 PSL 1 standard material. The SEM-EDX and XRD provide a piece of clear evidence into the corrosion product are primarily due to CO2 corrosion. The silhouette score agrees well with the results of the Bayesian information criterion of GMM to show three different risk levels low, medium, and high-risk profiles. The combination of injection of chemicals such as parasol, biocide and cleaning pigging are a few solutions to address CO2 corrosion. This work can be used as a guideline for assessing and clustering the risk based on the risk-based inspection.

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This paper aims to develop phantoms for measurement of computed tomography dose index (CTDI) based on a polyester resin mixed with methyl ethyl ketone peroxide (MEKP) as catalyst. CT number and CTDI values of the polyester resin phantoms were compared with a standard polymethyl methacrylate (PMMA) phantom as reference. The percentage of MEKP was varied from 0.3 to 0.6 wt%. The polyester resin phantoms had diameter of 160 mm, length of 150 mm and five cylindrical holes with diameter of 13.5 mm. One hole was positioned at the centre of the phantom and the other four near its periphery, 10 mm from the edge. The results show that the CT number of the polyester resin phantom was about 1%-9% higher than that of the standard PMMA phantom. Among the polyester resin phantoms, the one with 0.3 wt% MEKP is closest to the standard PMMA phantom in terms of CT number. In addition, the difference in weighted CTDI value between the 0.3 wt% polyester resin phantom and the PMMA is less than 5%. Thus, the 0.3 wt% polyester resin is potentially used as an alternative to the standard PMMA, with the advantage of a lower cost.

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RESUMEN

This study was to evaluate dose reduction and resulting image quality of a new synthetic thyroid shield based on silicon rubber (SR)-lead (Pb) composites and compare to tungsten paper (WP) and a Radibabarrier thyroid shields in CT examination of the neck. The synthetic SR-Pb thyroid shield had a Pb percentage from 0 to 5 wt% and a thickness of 0.6 cm. Scanning on the neck of an anthropomorphic phantom was performed with and without the SR-Pb, WP, and Radibarrier thyroid shields. The thyroid shields were placed directly on the neck surface. The thyroid dose was measured using radiophoto-luminescence (RPL) detectors. Image quality was characterized by consistency of the Hounsfield unit (HU) on the areas of anterior, posterior and lateral of the neck phantom. Detailed evaluation of the image quality was employed by image subtraction. It was found that the thyroid dose at the surface decreased with an increase of Pb percentage in the SR-Pb shield. The thyroid dose reduction was 34% for a Pb percentage of 5 wt%. The reduction of the dose using WP and Radibarrier were 36% and 67%, respectively. The dose reduction when using the WP and Radibarrier was higher than when using the SR-Pb 5 wt% thyroid shield. However the existence of artifact in the WP and the Radibarrier reduced the image quality, indicated by a significant change of HU, i.e. the increases of HU in the posterior area were 77% for the WP and 553% for the Radibarrier. The SR-Pb shield produced only a very small artifact, resulting in an increase of HU in the posterior area of only 9%. The SR-Pb shield is suitable in the daily clinical setting for thyroid dose reduction in CT examinations while maintaining image quality.

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