RESUMEN
Feroxyhite (δ-FeOOH) nanomaterials were successfully synthesized through the atmospheric AC microplasma method at room temperature from ferrous sulfate aqueous solutions. Various syntheses conditions, including electric voltage, electric field strength, ferrous concentration, hydrogen peroxide concentration, and reaction duration, were systematically investigated. The synthesized products were characterized through x-ray diffraction, UV-vis absorption spectroscopy, photoluminescence spectroscopy, infra-red spectroscopy, and electron microscopy. The bandgap of the produced materials were strongly dependent of the ferrous concentration while the product ratio was dependent on all experimental conditions. The synthesis mechanism was thoroughly discussed. The synthesized nanomaterials were amorphous nanospheres, showing superparamagnetic properties at room temperature. The synthesized oxyhydroxide is a potential photovoltaic material besides its reported applications in photocatalysts and supercapacitors. The application of this synthesis technique could be extended to synthesize other oxy-hydroxide nanomaterials for renewable energy applications facilely, scalablely, cost-effectively, and environmentally.
RESUMEN
Recent experiments have shown that ions in weakly collisional plasmas containing two ion species of comparable densities nearly reach a common velocity at the sheath edge. A new theory suggests that collisional friction between the two ion species enhanced by two stream instability reduces the drift velocity of each ion species relative to each other near the sheath edge and finds that the difference in velocities at the sheath edge depends on the relative concentrations of the species. It is small when the concentrations are comparable and is large, with each species reaching its own Bohm velocity, when the relative concentration differences are large. To test these findings, ion drift velocities were measured with laser-induced fluorescence in argon-xenon plasmas. We show that the predictions are in excellent agreement with the first experimental tests of the new model.
RESUMEN
Laser-induced fluorescence (LIF) measurements have been performed for the first time in a low temperature (Te approximately 0.6 eV) Xe plasma using a tunable diode laser in the visible range of wavelengths. The transition in Xe II involved the (3P1)5d[3]7/2 metastable state and the excitation wavelength was found to be 680.570+/-0.001 nm (air). LIF measurements of I 2 in a room temperature iodine gas cell were used to monitor the wavelength of the laser during the measurements.