1.
Acta Crystallogr E Crystallogr Commun
; 75(Pt 6): 867-871, 2019 Jun 01.
Artículo
en Inglés
| MEDLINE
| ID: mdl-31391984
RESUMEN
The title compound, [Ni(C10H8N2)3](C9H5N4O)2·2H2O, crystallizes as a racemic mixture in the monoclinic space group C2/c. In the crystal, the 1,1,3,3-tetracyano-2-ethoxypropenide anions and the water molecules are linked by O-Hâ¯N hydrogen bonds, forming chains running along the [010] direction. The bpy ligands of the cation are linked to the chain via C-Hâ¯π(cation) inter-actions involving the CH3 group. The inter-molecular inter-actions were investigated by Hirshfeld surface analysis and two-dimensional fingerprint plots.