1.
Dalton Trans
; 46(35): 11547-11551, 2017 Sep 12.
Artículo
en Inglés
| MEDLINE
| ID: mdl-28828427
RESUMEN
The synthesis and characterization of silica-grafted monopodal and bipodal aluminum hydrides has been achieved starting from 200 °C- and 700 °C-annealed silica and [AlH3(NMe2Et)]. The mechanism by which aluminum trishydride reacts with isolated and vicinal silanols, assisted by the amine, has been investigated computationally at the ωB97XD-DFT level.