RESUMEN
Average concentration of Pb in atmospheric air particulates in different suburbs of Mumbai was studied for almost a decade and its spatial and temporal profiles are discussed in relation to emission sources. In general the concentration of Pb in all the residential suburban atmosphere is well below the Central Pollution Control Board (CPCB, 1994) prescribed limit of 1.5 microg m(-3) barring a few exceptions for some residential/industrial sites, such as those of Thane and Kurla scrap yards. The correlation between blood lead of children and air lead reveals that the blood Pb level in children could increase by 3.6 microg dl(-1) for an incremental rise of 1.0 microg Pb m(-3) of air. The temporal profile of air Pb values indicates a decreasing trend in residential suburbs (Khar: 1984, 0.39 microg m(-3); 1996, 0.17 microg m(-3)) as well as in suburban residential areas with low traffic (Goregaon: 1984, 0.53 microg m(-3); 1996, 0.30 microg m(-3)).
Asunto(s)
Contaminantes Atmosféricos/sangre , Exposición a Riesgos Ambientales/análisis , Plomo/sangre , Emisiones de Vehículos/análisis , Niño , Monitoreo del Ambiente , Humanos , IndiaRESUMEN
The trace element contents of five varieties of instant coffee powder available in the Indian market have been analysed. Ca, Cr, Fe, K, Mg, Mn, Ni, Sr, Zn and Pb, Cd, Cu have been determined using atomic absorption spectrophotometry and differential pulse anodic stripping voltammetry, respectively. The metal levels in the coffee powders observed in this study are comparable with those reported for green coffe beans (Arabica and Robusta variety) reported worldwide with the exception of Sr and Zn, which were on the lower side of the reported values. Concentrations of these metals have been converted into intake figures based on coffee consumption. The daily intakes of the above metals through ingestion of coffee are 1.4 mg, 1.58 microg, 124 microg, 41.5 mg, 4.9 mg, 17.9 microg, 2.9 microg, 3.8 microg, 12.5 microg, 0.2 microg, 0.03 microg and 15.5 microg, respectively. The values, which were compared with the total dietary, intake of metals through ingestion by the Mumbai population, indicate that the contribution from coffee is less than or around 1% for most of the elements except for Cr and Ni which are around 3%.
Asunto(s)
Café/química , Oligoelementos/administración & dosificación , Dieta , Electroquímica , Humanos , India , Garantía de la Calidad de Atención de Salud , Espectrofotometría Atómica , Oligoelementos/análisisRESUMEN
The daily intake of manganese (Mn) estimated through air, water and duplicate dietary analysis is found to range from 0.67 to 4.99 mg with a mean value of 2.21 mg. Ingestion through food contributed to the predominant fraction of the intake. The turnover rate of Mn through blood is approximately 2 h, based on the mean concentration of Mn in blood of 1.54 microg l(-1). The average concentrations of Mn in water and air were approximately 1.42 microg l(-1) and 37 ng m(-3), respectively. The daily intake of Mn by the adult population of Mumbai is closer to the lower bound of the recommended limit of 2-5 mg. Electro Thermal Atomic Absorption Spectrophotometry (ET-AAS), has been used for the determination of Mn in a variety of environmental and human biological fluids. The detection limit of Mn for a volume injection of 20 microl is 2 pg absolute. The precision of the method is established by analyzing a synthetic mixture containing various elements in different quantities (0.5-10 ppm) and is found to be within +/- 8%. The reliability of estimation is further assessed through the analysis of Standard Reference Materials (SRMs) of soil, hay, milk powder and fish tissue obtained from IAEA.
Asunto(s)
Contaminación de Alimentos , Manganeso/análisis , Adulto , Exposición a Riesgos Ambientales , Monitoreo del Ambiente/métodos , Femenino , Humanos , India , Masculino , Reproducibilidad de los Resultados , Abastecimiento de AguaRESUMEN
Heavy metal concentrations have been determined in maternal and cord blood samples collected from mothers in the age group 20-25 years with full-term neonates (37-40 weeks). The concentrations of Pb, Cd, Cu and Zn were found to be low in cord blood as compared to mother's blood and the ratio between cord blood and maternal blood for the respective elements was found to be approximately 0.80, 0.86, 0.47 and 0.40. On the other hand, the concentrations of Fe and Mg in the mother's blood were found to be lower than those in the cord blood. Prenatal exposure to lead in Mumbai, though low (5.1 microg/dl), is approximately 2-3 times higher than that observed in Canada or Italy. A strong correlation (r = 0.79) between the maternal and cord blood lead levels has been observed during the present study.
Asunto(s)
Contaminantes Ambientales/análisis , Sangre Fetal , Intercambio Materno-Fetal , Metales Pesados/análisis , Adulto , Canadá , Estudios Epidemiológicos , Femenino , Humanos , India , Recién Nacido , Italia , Masculino , EmbarazoRESUMEN
Concentrations of the essential elements Zn and Cu and potentially toxic elements Pb and Cd in different milk samples and baby food materials were measured, primarily to assess whether the intakes comply with recommended desired levels for essential and permissible levels for toxic elements. The geometric mean concentrations of Pb, Cd, Cu and Zn in different types of milk were found to vary from 1.70 to 3.35, 0.07 to 0.10, 43.2 to 195 and 1772 to 4230 micrograms/l, while the same in different baby foods had values from 39.5 to 77.7, 0.45 to 17.7, 1106.3 to 3157.3 and 9367 to 34,592 micrograms/kg, respectively. The concentration of Cd was found to be very low (0.1 microgram/l) and fairly constant in all types of milk. The lead content in cow milk was observed to be lowest even in comparison with breast milk. Concentrations of all these metals are approximately one order of magnitude higher in baby food products than those observed in different types of milk owing to higher fat content. The infant baby food Amul Spray contains low concentrations of toxic (Pb and Cd) and high concentrations of essential (Cu and Zn) elements. The daily intakes of Pb, Cd, Cu and Zn by infants through milk and baby foods marketed in Mumbai city have also been estimated. The daily intakes of Pb (1.1 micrograms/kg) and Cd (0.01 microgram/kg) for infants through baby foods are well below the recommended tolerable levels of 3.57 micrograms/kg and 0.8-1.0 microgram/kg, respectively. Similarly the daily intake levels of essential elements are also significantly lower than the recommended desirable levels of 3-5 mg and 0.5-1.0 mg for Zn and Cu, respectively. Milk from an Indian mother also does not provide adequate levels of essential elements to the infants and children.