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Inorg Chem ; 43(21): 6546-8, 2004 Oct 18.
Artículo en Inglés | MEDLINE | ID: mdl-15476350

RESUMEN

Persistent phosphinyl radicals featuring the 2,6-bis(trifluoromethyl)phenyl group were prepared and characterized. Their electronic structure was theoretically investigated, and their low-temperature dimerization into the corresponding diphosphines was found to be strongly inhibited when the sterically very demanding (tert-butyl)(trimethylsilyl)amino substituent was used.

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