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The present work reports the study of the thermally coupled energy levels of the trivalent europium ion in the barium hafnate matrix, in the temperature range of 289.7-323.8 K, through the application of ultraviolet radiation. Barium hafnate doped with 1, 3, and 5 atomic % trivalent europium ion was synthesized by the hydrothermal route, using chlorides as precursor elements. X-ray diffraction analysis indicates that the material crystallized in the perovskite cubic phase of barium hafnate, according to diffraction card file number #24-0102. Using high-resolution transmission electron microscopy, it was observed that the obtained crystals have an average size of 10 nm. From the photoluminescent analysis at room temperature, it was found that the sample doped with 3.0% atomic of trivalent europium displayed with the highest luminescent emission, while the photoluminescent analysis as a function of temperature showed that the bands associated with the 5D0 → 7FJ (J = 1,2,3,4) transitions have a strong dependence on temperature in the physical range.

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The increasing use of thermoluminescence (TL) materials as radiation detectors with application in different areas of ionizing radiation has motivated research on new materials with adequate luminescent characteristics. In this work, experimental results gadolinium aluminate (GdAlO3) analyzed by thermoluminescent phenomenon under beta irradiation effect are studied. To prepare GdAlO3 powders the coprecipitation method was used. TL glow curve and other luminescent characteristics were analyzed using an automatic Lexsig Smart TL/OSL luminescent reader. TL glow curve showed four peaks with three prominent and well-defined peaks centered at 140, 230, and 270 °C. TL response as a function of beta radiation dose was linearity in the range from 1.1 up to 44 Gy. Kinetic parameters such as activation energy (E), frequency factor (s), and order of kinetics after the deconvolution of the TL glow curve were also determined using Chen's peak shape method. Experimental results show GdAlO3 as a potential luminescent host material for TL studies.

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AIM: To evaluate if a radiochromic film (RF) Gafchromic EBT3 is suitable for surface dose measurements of radiotherapy treatments performed with a 6 MV linear accelerator. Two aspects of RF were analyzed, beam energy dependence and surface dose determination. BACKGROUND: The measurements done at the surface or near the radiation source are done without charged electronic equilibrium and also have contribution of electron contamination. The detectors used for these measurements should not alter the dose to the target. To counteract these dosimetric problems it is proposed to do the measurements with radiochromic films which are thin detectors and have tissue equivalent properties. MATERIALS AND METHODS: The measurements were done using a Novalis linear accelerator (LINAC) with nominal energy of 6 MV. To determine the surface dose, the total scatter factors (TSF) of three different field sizes were measured in a water phantom at 5 cm depth. Energy dependence of EBT3 was studied at three different depths, using a solid water phantom. The surface measurements were done with the RF for the same field sizes of the TSF measurements. The value of the percentage depth dose was calculated normalizing the doses measured in the RF with the LINAC output, at 5 cm depth, and the TSF. RESULTS: The radiochromic films showed almost energy independence, the differences between the curves are 1.7% and 1.8% for the 1.5 cm and 10 cm depth, respectively. The percentage depth doses values at the surface measured for the 10 cm × 10 cm, 5 cm × 5 cm and 1 cm × 1 cm were 26.1 ± 1.3%, 21.3 ± 2.4% and 20.2 ± 2.6%, respectively. CONCLUSIONS: The RF-EBT3 seems to be a detector suitable for measurements of the dose at the surface. This suggests that RF-EBT3 films might be good candidates as detectors for in vivo dosimetry.

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In this paper, luminescent properties of Europium trivalent ion in the matrix with unbalanced charge of barium hafnate under UV radiation, with special emphasis on the 5D0 → 7F0 transition are reported. The synthesis was conducted by the hydrothermal route at 200 °C with a reaction time of 90 min using chlorides as raw materials. In order to determinate the luminescent quenching concentration, the samples were doped with different amounts of Europium trivalent ions being the sample doped with 1 and 3% at of Eu3+ which shows the highest luminescent emission. X-ray diffraction analysis showed that the material crystallize in the cubic perovskite structure with space group Pm-3m. The Energy Dispersive Spectroscopy (EDS) shows there are not elements other those that Ba, Hf, O and Eu in the synthesized material. Photoluminescent emission spectra show peaks of emission associated with the 5D0 → 7FJ (J = 0,1,2,3,4) transitions, characteristics of europium ion. The 5D0 → 7F0 transition centered at 580 nm showed an unusual great intensity when it was excited with the wavelength associated with the charge transfer band (272 nm). Finally the decay time was measured in the 5D0 → 7FJ (J = 0,1,2,3,4) transitions using the sample doped with Eu3+ (3% at).

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Thermoluminescent (TL) response of trivalent praseodymium ion doped lanthanum aluminate (LaAlO3:Pr3+) obtained by Pechini method and Spray Dryer was studied. TL response of LaAlO3:Pr3+ powders submitted at 1600°C exhibited one peak centered at 157°C. Sensitivity of LaAlO3:Pr3+ was improved in around 90 times compared with undoped LaAlO3. TL response as a function of wavelength showed a maximum in 230nm. Dosimetric characteristics of LaAlO3:Pr3+ under UVR radiation effects were analyzed. Evaluation of activation energy was obtained by Glow Fit v.1.3 software. Experimental results about thermoluminescent characteristics of LaAlO3:Pr3+ suggest as good candidate to be employed as a complementary thermoluminescent device with other TL phosphors as aluminum oxide.

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Radiochromic films are dosimeters with more favorable characteristics than other two-dimensional (2D) radiation detectors. Transmission film scanners using a linear charge-coupled device (CCD) array have a drawback of variation in response along the detector array, which may result in a nonuniform transmission of signal over the scanned image. This study uses 2D gamma index analysis to compare two methods for correcting the nonuniform response of EBT2: the first method was based on the new red:blue method proposed by the manufacturer (to compensate for small nonuniformities in the film coating) and the second method, proposed by Menegotti et al. (2008), was based on dose-dependent matrix correction factors. The gamma index analysis shows that both the methods are comparably accurate for all the criteria values used for evaluation (1 mm/1%, 2 mm/2%, 3 mm/3%). Centers around the world use both the methods to correct EBT2 local heterogeneities, but it is important to note that the former method has several advantages such as less time consumption and easy implementation.

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The aim of this paper was to develop a thermoluminescent dosimetry method for the absorbed dose determination of 6 MeV high-energy electron beams by thermoluminescent dosimetry. Total body irradiation (TBI) was performed using four dual fields angled at 252° and 285° in high-dose rate (HDR) mode. TBI measurements were investigated to estimate the absorbed dose in different anatomical parts of the patient. Experimental results were obtained using thermoluminescent detectors and solid water phantoms. The TL response of the dosimeters, as a function of the high-energy electron beam (HEEB) absorbed dose, was linear, from 0.1 to 500 cGy. The entrance skin dose (ESD) and isodose distribution on the surface of the treatment were investigated graphically.

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This paper presents results of equivalent dose organ determining to both primary beam and scattered radiation in a computed tomography (CT) procedures. All measurements were carried out to abdomen and critical organ (gonads) area. Selected dosimeters showed a standard deviation of 4.1% below to the reference values established by international guide lines. The equivalent dose in gonads was 14.27 mGy.

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This paper presents the results of Environmental and Personnel Dosimetry made in a radiology area of a veterinary hospital. Dosimetry was realized using thermoluminescent (TL) materials. Environmental Dosimetry results show that areas closer to the X-ray equipment are safe. Personnel Dosimetry shows important measurements of daily workday in some persons near to the limit established by ICRP. TL results of radiation measurement suggest TLDs are good candidates as a dosimeter to radiation dosimetry in veterinary radiology.

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Se ha medido la dosis en la superficie de entrada de ojos, tiroides y gónadas en pacientes sometidos a estudio de radiografía de tele de tórax mediante dosimetría termoluminiscente. Se usaron 5 dosímetros en cada una de las exploraciones; encontrándose los siguientes rangos de dosis: 20 mGy a 350 mGy. En el caso de los pacientes pediátricos se propone incluir la información de las dosis recibidas en su cartilla de vacunación con el fin de hacer un seguimiento de los posibles efectos nocivos en su salud.

Doses have been measured at the entrance surface of eyes, thyroid and gonads in patients undergoing chest x-ray studies, using thermo-luminiscent dosimetry. Five dosimeters were used in each investigation, and doses ranged from 20 mGy to 350 mGy. In the case of pediatric patients, it is proposed that dose information from diagnostic examinations is included in the vaccination chart in order to correlate with findings at follow-up.

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Thermoluminescent response of LiF:Mg,Cu,P+PTFE under clinical photon irradiation was obtained. Thermoluminescent dosimeters (TLDs) were irradiated for determining entrance surface dose (ESD) in a solid water phantom when using standard clinical adult treatment protocols. A Monte Carlo simulation of photon interaction with matter was performed and absorbed dose determined. ESD calculated by MCNPX code was greater than those determined by direct measurements in phantom. The results obtained open the possibility for using this material as a TLDs in medical accelerators.

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