RESUMEN
In the title compound, C15H16N2S3 {systematic name: [({[(4-methyl-phen-yl)meth-yl]sulfan-yl}methane-thio-yl)amino][1-(thio-phen-2-yl)ethyl-idene]amine}, the central CN2S2 residue is almost planar (r.m.s. deviation = 0.0061â Å) and forms dihedral angles of 7.39â (10) and 64.91â (5)° with the thienyl and p-tolyl rings, respectively; the dihedral angle between these rings is 57.52â (6)°. The non-thione S atoms are syn, and with respect to the thione S atom, the benzyl group is anti. In the crystal, centrosymmetrically related mol-ecules self-associate via eight-membered {â¯HNCS}2 synthons. The dimeric aggregates stack along the a axis and are are consolidated into a three-dimensional architecture via methyl-C-Hâ¯π(benzene) and benzene-C-Hâ¯π(thien-yl) inter-actions.