RESUMEN
Photocatalysis is found to be one of the best suited processes that respond to the purification of water systems and the semiconductor nanomaterials are learned to be incredible materials which carry out the photocatalytic process as they readily decompose the pollutants effectively. In this present work, CdSe nanoparticles belonging to II-VI group semiconductor compounds were synthesized using a facile hydrothermal process with different precursor concentrations and were analysed for various characterization studies such as X-ray diffraction (XRD), Transmission electron microscopy (TEM), UV-vis absorption spectroscopy, Fourier transform infrared spectroscopy (FTIR) and Photoluminescence (PL) studies. The XRD study of the synthesized CdSe nanostructures revealed that the average crystallite size was ranging from 18.5 nm to 24 nm pointing out the increase in size with increase in molar concentrations. The morphological structure of synthesized CdSe samples exhibited urchin-like structure for a lower concentration with several rod-like projections appearing in diverse directions. These CdSe nano-urchins synthesized with lower concentrations are found suitable to carry out the process of photocatalytic activity. The process was carried out under visible light radiation for 180 min with aqueous solution of methylene blue (MB) as the ideal toxin to be degraded. The attained degradation efficiency was nearly 80% clearly displaying that the synthesized samples are good photocatalysts. By tuning the bandgap, through the optimization of the precursor concentrations, greater efficiency can be achieved in future.
Asunto(s)
Compuestos de Cadmio , Compuestos de Selenio , Catálisis , Luz , Azul de MetilenoRESUMEN
Semiconductor nanoparticles and nanocrystals have a great impact due to its contribution in the diverse fields including electronics, solar energy, biological imaging, and photonics. Among these semiconductor nanoparticles, cadmium selenide of II-VI group binary semiconductor nanoparticles were synthesized using solvothermal process for the different reaction temperatures. The XRD pattern of the synthesized samples confirms the crystalline nature of the samples and showed increase in its crystallite size with rise in temperature. The morphology of the samples was analysed with TEM images and found that the nanoparticles synthesized at different temperatures were varied in size and shape indicating the increase in the size of the particles with the raise in temperature. The optical properties of the samples pointed out that they exhibit a blue shift owing to quantum confinement. Photocatalytic activity was carried out for the synthesized samples under visible light radiation using methylene blue (MB) as a model pollutant and it proved to be a good photocatalyst achieving the efficiency of 75% which is promising for future application with good optimization. The efficiency could be increased when these semiconductor CdSe nanoparticles are doped with metal particles due to an increase in the absorption edge wavelength and a decrease in bandgap energy were reported in detail.