RESUMEN
The dissolved organic matter (DOM) in landfill pollutes not only the landfill and surroundings, but also the environment far away from the landfill by infiltrating into the soil and/or flowing on the ground surface. Developing an efficient photocatalyst to degrade DOM is an interesting topic. Herein, the catalysts composed of ZnO and reduced graphene oxide (ZnO-rGO) with different morphologies were fabricated with a two-step hydrothermal method. The phase composite and microstructure were analyzed, and the degradation efficiency of the DOM under ultraviolet light was investigated. Three kinds of ZnO-rGO composite catalysts with different morphologies were successfully synthesized, and rGO was coated on the ZnO surface to form heterostructural composite catalysts. The catalyst powders have similar Raman and FT-IR spectra, but have different specific surface areas and band gaps. The degradation efficiency of DOM by ZnO-rGO composites is higher than that of pure ZnO powder. Compared to pure ZnO, ZnO-rGO composite catalysts contain more oxygen vacancies and a narrower band gap, and the heterostructure is beneficial for accelerating electron separation, inhibiting electron recombination.