RESUMEN
Tritium in urine was analysed from 227 randomly selected Finnish adults. The people were 18 to 65 of age. Urine samples were collected over night. The mean activity concentration of tritiated water in urine was 2.5 Bq l(-1) and the maximum activity concentration 18.3 Bq l(-1). The minimum detectable activity varied from 1.5 to 2.3 Bq l(-1). Because organically bound tritium is approximately 10% of the total tritium, its concentration was below the detection limit and could be ignored. The mean effective dose for Finnish people from tritium was 2.4 x 10(-3) microSv y(-1).
Asunto(s)
Tritio/orina , Adolescente , Adulto , Anciano , Femenino , Finlandia , Humanos , Masculino , Persona de Mediana Edad , Conteo por CintilaciónRESUMEN
Urine monitoring is the preferred method to determine exposure to soluble compounds of uranium in workplaces. The interpretation of uranium contents in workers bioassay samples requires knowledge on uranium excretion and its dependence on intake by diet. Exceptionally high concentrations of natural uranium in private drinking water sources have been measured in the granite areas of Southern Finland. Consequently, high concentrations of natural uranium have been observed in the urine and hair samples of people using water from their own drilled wells. Natural uranium content in urine and hair samples of family members, who use uranium-rich household water, have been analyzed by using ICP-MS. The uranium concentrations both in urine and hair samples of the study subjects were significantly higher than the world-wide average values. In addition, gammaspectrometric methods have been tested for determining uranium in hair samples. This method can be used only for samples with highly elevated uranium concentrations.
Asunto(s)
Bioensayo/métodos , Modelos Biológicos , Exposición Profesional/análisis , Monitoreo de Radiación/métodos , Protección Radiológica/métodos , Uranio/análisis , Uranio/farmacocinética , Algoritmos , Radiación de Fondo , Simulación por Computador , Finlandia , Humanos , Internacionalidad , Dosis de Radiación , Reproducibilidad de los Resultados , Sensibilidad y EspecificidadRESUMEN
Effects of industrial pollution on the behaviour of radionuclides in spruce forest ecosystems were studied along a gradient from of a copper-nickel smelter in Monchegorsk, NW Russia. A reference site was situated in Lapland, Finland, 152 km west of Monchegorsk. Most of the total 137Cs activity in soil was in mineral (E and B) horizons, except at the reference site where the major part was still in the organic surface layer. Most of the total 90Sr activity still remaining in the soil profile was found in the surface layer, but the relative amount decreased with increasing level of industrial pollution. Pollutants from the smelter clearly affected the chemical speciation of radionuclides. Smaller amounts of exchangeable radionuclides were present in the organic surface layer at the most polluted sites. The decline of 137Cs with decreasing distance from the smelter correlated strongly with a similar depletion in exchangeable K and Mg. Total concentrations of 137Cs and 90Sr showed high correlations with exchangeable cations, particularly in the E and upper B horizon. A sudden change in behaviour of 137Cs in the lower B horizon may be associated with changes in clay mineralogy along the soil profile caused by weathering.
Asunto(s)
Metales Pesados/análisis , Contaminantes Radiactivos del Suelo/análisis , Regiones Árticas , Cesio/análisis , Monitoreo del Ambiente , Estroncio/análisisRESUMEN
The aim of this study was to estimate the current concentrations of 90Sr and 137Cs in the urine of Finnish people and to estimate the doses. Two to three daily urine samples were collected from 18 adult Finnish volunteers in connection with studies of 137Cs body burdens in 1999-2001. The 90Sr activities in urine varied between 1.4 and 11 mBq l(-1). The 137Cs activity in urine varied between 0.36 and 56 Bq l(-1). The daily urinary excretion was found to be 4.8-17 mBq for 90Sr and 0.81-68 Bq for 137Cs. Assuming that the daily 90Sr intake was constant and that 18% of the ingested activity was excreted in urine, the mean intake in the investigated group would vary between 27 and 96 mBq d(-1). Based on these estimated intake values, the respective annual effective internal doses from 90Sr and 90Y varied from 0.3 to 1.0 microSv and from 137Cs from 4 to 350 microSv during the sampling period.
Asunto(s)
Radioisótopos de Cesio/orina , Radiometría/métodos , Radioisótopos de Estroncio/orina , Adulto , Finlandia , Humanos , Masculino , Persona de Mediana Edad , Dosis de Radiación , Protección Radiológica/métodos , Ceniza Radiactiva/análisis , Medición de Riesgo/métodos , Recuento Corporal Total/métodosRESUMEN
The aim of the present study was to determine the forms of 137Cs, 90Sr and 239,240Pu occurring in different soil horizons using sequential extraction of samples taken from four sites located along a pollution gradient from the copper-nickel smelter at Monchegorsk in the Kola Peninsula, Russia, and from a reference site in Finnish Lapland in 1997. A selective sequential-leaching procedure was employed using a modification of the method of Tessier, Cambell and Bisson ((1979). Analytical Chemistry, 51, 844-851). For 137Cs the organic (O) and uppermost mineral (E1) layer were studied, for 90Sr and 239,240Pu only the uppermost organic layer (Of). The fraction of 137Cs occurring in readily exchangeable form in the organic layer was about 50% at the reference site and decreased as a function of pollution, being 15% at the most polluted site in the Kola Peninsula. There was a clear positive correlation in the O layer between the distance from the smelter and the percentage of 137Cs extracted in the readily exchangeable fraction (Spearman correlation rsp = 0.7805, p = 0.0001), whereas in the E1 layer no correlation was evident. The distribution of 90Sr in the Of layer was similar at all sites, with the highest amounts occurring in exchangeable form and bound to organic matter, whereas stable Sr showed a somewhat different distribution with the highest amount in the oxide fraction. Most of the 239,240Pu was bound to organic matter. Chemical pollution affected the exchangeable fraction of 239,240Pu, which was about 1% at the most polluted site and 4-6% at the other sites.
Asunto(s)
Radioisótopos de Cesio/análisis , Plutonio/análisis , Contaminantes Radiactivos del Suelo/análisis , Radioisótopos de Estroncio/análisis , Regiones Árticas , Radioisótopos de Cesio/farmacocinética , Compuestos Orgánicos/metabolismo , Oxidación-Reducción , Plutonio/farmacocinética , Radioisótopos de Estroncio/farmacocinéticaRESUMEN
To study the impact of industrial pollution on the soil-to-plant uptake of fallout-radiocesium in a boreal forest ecosystem, four study sites were selected at distances of 7, 16, 21 and 28 km from the large copper-nickel smelter at Monchegorsk on the Kola Peninsula (Russia). At each site, soil and selected plant species were sampled from five plots and analysed separately for 137Cs and 40K. The data show that the root-uptake of 137Cs, as characterised by the median aggregated transfer-factor T(ag), decreased significantly (P < 0.05) with decreasing distance from the smelter for the plants Vaccinium myrtillus (from 0.023 to 0.007 m2 kg-1) and Empetrum nigrum (from 0.015 to 0.007 m2 kg-1), but increased for Deschampsia flexuosa (from 0.013 to 0.031 m2 kg-1). For Vaccinium vitis-idaea a significant trend for the T(ag) was not observed. The median 40K activity concentrations in these plants also decreased significantly (P < 0.001) with decreasing distance from the smelter for Vaccinium myrtillus (from approx. 140 to 20 Bq kg-1 dry wt.), Empetrum nigrum (from approx. 90 to 40 Bq kg-1 dry wt.), and also for Deschampsia flexuosa (from approx. 270 to 40 Bq kg-1 dry wt.). For Vaccinium vitis-idaea such a continuous significant trend was not observed. The results for the Cu-Ni polluted soils thus show: (1) that the soil-to-plant transfer of radiocesium can be significantly modified; (2) that these modifications are quite specific; and (3) that modifications of the uptake of potassium do not always correspond to those of radiocesium.