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The aim of this study was to determine the in vitro antioxidant potential of four extruded and domestically prepared composite flour formulations developed by composting selected locally available grain varieties in Sri Lanka. The potential of the flour extracts to scavenge free radicals were evaluated by performing DPPH, ABTS, and FRAP assays. Furthermore, the antimicrobial activities of the flour formulations against selected Gram-positive and Gram-negative pathogenic microorganisms were comparatively evaluated using agar well diffusion and disk diffusion assays. Ethanol and water extracts of the samples were evaluated for their antimicrobial potential. The results showed that extruded samples possessed high antioxidant properties than samples prepared using the conventional cooking. Furthermore, the antioxidant potential of the formulations evaluated using different assays was strongly correlated. Moreover, the formulations reported positive antimicrobial potential against tested Gram-negative and Gram-positive bacteria. The ethanol extracts of flour formulations exhibited higher susceptibility to tested microbes than that of water extracts while agar well diffusion resulted significantly high inhibition against pathogenic bacteria than that of agar disk diffusion method (p < 0.05). In overall, the highest inhibition zone of 17.64 mm was depicted by F4 against Salmonella, while the lowest diameter of 6.09 mm was depicted by F1 against Listeria. In conclusion, the developed flour formulations contained natural antimicrobial agents which can combat common food spoilage and pathogenic bacteria and can be promoted as value-added products with health benefits beyond nutrition.
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CONTEXT: Plastic waste pyrolysis offers a potential solution to reduce plastic accumulation, but prioritizing monomer recovery from the process is crucial to effectively address the environmental consequences of plastic accumulation. This study focuses on enhancing the yield of styrene during the pyrolysis of polystyrene by investigating thermal and kinetic data. A comprehensive investigation into the thermal degradation pathways of polystyrene is imperative to overcome the challenges associated with its waste management. The calculated bond dissociation energies reveal that the cleavage of non-terminal carbon-carbon bonds is energetically favorable, resulting in the formation of high molecular weight benzylic radicals. Based on these findings, four pyrolysis pathways are proposed, and the associated thermodynamic and kinetic parameters are determined using the DFT method. The major products identified in this study include styrene, α-methylstyrene, isopropylbenzene, methylbenzene, ethylbenzene, and methane. Furthermore, optimizing the temperature profile of the reactor is shown to enhance the recovery of styrene, thereby contributing to the reduction of plastic waste. This study provides valuable insights into the effective resource recovery from polystyrene waste pyrolysis, emphasizing the significance of managing pyrolysis conditions to achieve maximum yield. By controlling the temperature profile during the pyrolysis process, it is possible to obtain a high yield of styrene, facilitating the efficient recovery of the monomer from waste polystyrene and addressing the environmental concerns associated with plastic accumulation. METHODS: In this study, all calculations were performed using the B3LYP/6-31G(d) level of theory with the Gaussian 16 program package. The proposed model underwent geometry optimization and frequency calculations. Transition states were optimized using the TS Berny method, and energy profiles along reaction pathways were refined using the QST3 method. The IRC method validated proposed mechanisms and investigated energy profiles. Structural models were visualized using GaussView 6.0.
RESUMEN
Lauha Bhasma (LB) is a prominent Ayurveda medicine and is used as an ingredient to prepare other indigenous medicines in Ayurveda. The outcomes of this study on chemical and physical changes during the preparation process of LB become significant to explore ancient knowledge of east within the modern context. The preparation process of LB was carried out under laboratory conditions; starting from the elemental form of the Iron sample to identify the chemical and physical changes. The metallic composition of the starting material and intermediate products formed during the LB preparation process was determined using the AAS technique. The variation of the amount of Fe2+ and Fe3+ throughout the process and formation of nanoparticles was identified using quantitative analysis. Even though the amount of heavy metals (Cr, Cd, Cu, Pb, Zn, and Mn) present in the starting material is low, the trace level of heavy metals in the iron sample significantly reduces during the LB preparation process. Irregular-shaped, agglomerated, blackish red (Pakvajambuphala varna) fine LB powder formed at the end of the Putapaka step. The value of ancient knowledge can be revealed using the chemical and physical changes identified throughout the study on the LB preparation process.
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Rubber seed oil (RSO) and its sodium soap were pyrolysed in a batch reactor to obtain low molar mass organic substances. The pyrolitic oil of RSO was redistilled and the distillates were characterized by GC-MS and FTIR. Density, acid value, saponification value and ester values were also measured according to the ASTM standard methods. A similar analysis was done for samples taken out at different time intervals from the reaction mixture. Industrially important low molar mass alkanes, alkenes, aromatics, cyclic compounds and carboxylic acids were identified in the pyrolysis process of rubber seed oil. However, pyrolysis of the sodium soap of rubber seed oil gave a mixture of hydrocarbons in the range of C14-C17 and hence it has more applications as a fuel.
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The current study evaluates the migration of benzene, toluene, ethylbenzene, xylene (BTEX) and phthalates into artificial saliva from natural rubber latex (NRL) balloons available for sale in Sri Lanka. It was discovered that at least one BTEX compound migrated from almost all the brands. The migration of four phthalates; diethyl phthalate, dibutyl phthalate, di-isobutyl phthalate and butyl benzyl phthalate were also observed. Migratory levels of BTEX and phthalates in most of the balloon brands were above the permissible levels set by the European Union. Assessment of factors affecting the migratory levels indicated migration under active mouthing conditions and migration from the neck region of the balloons were significantly higher. The migratory levels were observed to decrease with storage time, and in certain brands the BTEX levels decreased below the permissible level. One-way ANOVA indicated no significant differences (p ≥ 0.05) in migratory levels of each individual compound within the same brand for both BTEX and phthalates. When compared among different brands, BTEX levels indicated significant differences (p ≤ 0.05), while phthalate levels were observed to not be significantly different (p ≥ 0.05). A significant difference was also observed (p ≤ 0.05) among the migratory levels of compounds under each test condition evaluated as factors affecting the migratory level. Furthermore, the solvent based colorants added to color the latex were found to be the source of BTEX and phthalates in the NRL balloons.