RESUMEN
The aim of this study is to examine the Darcy-Forchheimer flow = of H2O-based Al-Al2O3/Cu-Al2O3 hybrid nanofluid past a heated stretchable plate including heat consumption/ generation and non-linear radiation impacts. The governing flow equations are formulated using the Naiver-Stokes equation. These flow equations are re-framed by using the befitted transformations. The MATLAB bvp4c scheme is utilized to compute the converted flow equations numerically. The graphs, tables, and charts display the vicissitudes in the hybrid nanofluid velocity, hybrid nanofluid temperature, skin friction coefficient, and local Nusselt number via relevant flow factors. It can be seen that the hybrid nanofluid velocity decreased as the magnetic field parameter was increased. The hybrid nanofluid temperature tended to rise as the heat absorption/generation, nanoparticle volume friction, and nonlinear radiation parameters were increased. The surface drag force decreased when the quantity of the magnetic parameter increased. The larger size of the radiation parameter led to enrichment of the heat transmission gradient.
RESUMEN
An alternative biotechnological solid phase bio-extraction (SPE) method was developed. Bacillus subtilis loaded multiwalled carbon nanotube was designed and used as biosorbent for the preconcentrations of Pb(II), Ni(II), and Zn(II). The experimental parameters such as sample flow rate, pH of sample solution, amounts of Bacillus subtilis and multiwalled carbon nanotube, volume of sample solution and reusability of column which affects the analytical characteristics of the SPE method were investigated in details. Surface structures were examined by using FTIR, SEM. The best pH was determined as 5.0 and the percentages recoveries of Zn(II), Ni(II), and Pb(II) were determined as 99.1%, 98.7%, and 96.2%, respectively, at a flow rate of 3 mL/min. In this study, in which the profitable sample volume was determined as 400 mL and the amount of multiwalled carbon nanotube (MWCNT) as 50 mg. It was also observed that the column had a significant potential to preconcentrate Zn(II), Ni(II), and Pb(II) even after 25 reuses. The biosorption capacities for Zn(II), Ni(II) and Pb(II) were calculated as 39.67 mg/g, 45.98 mg/g and 51.34 mg/g respectively. The LOD values were calculated as 0.024 ng/mL for Pb(II), 0.029 ng/mL for Ni(II), and 0.019 ng/mL for Zn(II). The linear range was detected as 0.25-25 ng/mL. The concentrations of Pb(II), Ni(II), and Zn(II) in a variety of real food samples were determined by using developed method after application of certified reference sample.