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1.
Materials (Basel) ; 15(24)2022 Dec 13.
Artículo en Inglés | MEDLINE | ID: mdl-36556728

RESUMEN

In this study, we successfully synthesized rare-earth-doped crystalline SrWO4 at room temperature by co-precipitation. The results from the X-ray diffraction analysis showed a main diffraction peak related to the (112) plane. Phosphors doped with either Dy3+ or Sm3+ ions showed strong light absorption in the UV region and blue-yellow and red light emission. To synthesize a white light phosphor, Dy3+ and Sm3+ ions were co-doped to produce a SrWO4:[Sm3+]/[Dy3+] phosphor. When the Sm3+ ion concentration was increased and the Dy3+ concentration was maintained, the red light intensity increased while the blue-yellow light intensity decreased. The composites were combined with polydimethylsiloxane (PDMS), and a flexible composite material was fabricated. The composite exhibited various luminescence properties under UV and visible light, which suggested its potential for use as an LED color filter.

2.
Materials (Basel) ; 15(22)2022 Nov 09.
Artículo en Inglés | MEDLINE | ID: mdl-36431401

RESUMEN

A BaMoO4:[Er3+]/[Yb3+] up-conversion (UC) phosphor was synthesized by co-precipitation and calcination of the precursor at 800 °C. The main peak (112) for the synthesized phosphor was strongly detected in the XRD pattern and had a tetragonal structure. The doping of rare-earth ions affected the crystal lattice by shifting the main peak, decreasing the lattice constant, and shifting the position of the Raman signal. The synthesized upconverted phosphor exhibited strong green signals at 530 and 553 nm and weak red signals at 657 nm when excited at 980 nm. The green light emission intensity of the UC phosphor increased as the pump power of the laser increased due to the two-photon effect. The synthesized upconverted phosphor was prepared as a pellet and flexible composite. Thermal quenching led to a decrease in luminescence intensity as the temperature increased, which means that the phosphor can be applied to optical temperature sensing.

3.
Nanomaterials (Basel) ; 11(10)2021 Sep 27.
Artículo en Inglés | MEDLINE | ID: mdl-34684960

RESUMEN

In this study, we investigated the effects on the characteristic changes in OLED devices of using self-assembled monolayers with different functional groups as the hole injection layer, resulting in changes in their performance. Thus, we confirmed that it is possible to control the wetting properties, surface roughness, and work function of the indium tin oxide (ITO) surface by introducing self-assembled monolayers (SAMs). The contact angle measurements confirmed that the substrate surface contact angle tended to increase with SAM deposition. In addition, AFM measurements confirmed that the substrate surface roughness tended to decrease when SAM was deposited on the surface. Finally, it was confirmed through the work function measurement results that the work function increased when the ITO surface was modified by SAM. Furthermore, compared to OLEDs using only the ITO anode, the SAM-modified device showed a higher current density (359.68 A/cm2), improved brightness (76.8 cd/cm2), and a smaller turn-on voltage (7 V). This approach provides a simple route for fabricating organic light-emitting diode applications.

4.
Materials (Basel) ; 12(6)2019 Mar 22.
Artículo en Inglés | MEDLINE | ID: mdl-30909501

RESUMEN

We examined the electro-optical characteristics of organic light emitting diodes according to the N,N'-diphenyl-N,N'-di(m-tolyl)-benzidine (TPD) thicknesses. The thicknesses of TPD were varied from 5 nm to 50 nm. The current density of the device with a TPD thickness of 5 nm was 8.94 times higher than that with a thickness of 50 nm at a driving voltage of 10 V. According to the conduction⁻current characteristics of conductors, the current densities improved with a decreasing TPD thickness. Different from the current density⁻voltage characteristics, the current efficiency⁻current density characteristics showed an improved efficiency with a 50 nm TPD thickness. The current efficiencies of a device with a 5 nm TPD thickness at a driving voltage of 10 V was 0.148 and at a 50 nm TPD thickness 0.993 cd/A, which was 6.7 times higher than the 5 nm TPD thickness. These results indicated that hole transport in Organic Light-Emitting Diode (OLED) devices were more efficient with thin 5 nm TPD than with thick 50 nm TPD, while electron transport was more efficient with thick 50 nm TPD, which caused conflicting results in the current efficiency-current density and current density-voltage characteristics according to TPD thicknesses.

5.
Sci Adv ; 4(4): eaar7328, 2018 04.
Artículo en Inglés | MEDLINE | ID: mdl-29675471

RESUMEN

Predation is considered a major selective pressure in the evolution of fear, but the neurophysiology of predator-induced fear is unknown. We simultaneously recorded lateral amygdala (LA) and prelimbic (PL) area neuronal activities as rats exited a safe nest to search for food in an open space before, during, and after encountering a "predator" robot programmed to surge from afar. Distinct populations of LA neurons transiently increased spiking as rats either advanced or fled the robot, whereas PL neurons showed longer-lasting spike trains that preceded and persisted beyond LA activity. Moreover, discrete LA-PL cell pairs displayed correlated firings only when the animals either approached or fled the robot. These results suggest a general fear function of the LA-PL circuit where the PL participates in the initial detection of potential threats, the LA signals the occurrence of real threats, and the dynamic LA-PL interaction optimizes defensive readiness for action.


Asunto(s)
Amígdala del Cerebelo/metabolismo , Corteza Cerebral/metabolismo , Conducta Predatoria , Animales , Miedo , Neuronas/fisiología , Ratas
6.
J Nanosci Nanotechnol ; 18(9): 6010-6013, 2018 09 01.
Artículo en Inglés | MEDLINE | ID: mdl-29677734

RESUMEN

In this study, we investigated the photoelectric effect and optimization of an organic light-emitting diode (OLED) depending on the presence or absence of a fluorinated self-assembled monolayer (FLSAM) and by varying the thickness of N,N'-Di (1-naphthyl)-N,N'-diphenyl-(1,1'-biphenyl)-4,4'-diamine (α-NPD) from 0 nm to 50 nm. The large distinction in electronegativity between the carbon and the fluorine replacing hydrogen in the alkyl chain of FLSAM generates a strong dipole moment to elevate the vacuum level, resulting in a change of the work function. This eliminates the injection barrier between the work function of the ITO modified by FLSAM and the highest occupied molecular orbital (HOMO) level of the hole-transport layer, thus leading to excellent driving voltage characteristics. Devices without FLSAM had a driving voltage more than twice that of devices using with FLSAM. The introduction of α-NPD as the hole-transport layer enhanced the electrical conductivity by facilitating the transport of holes. However, due to the inherent insulating film properties of α-NPD, the increase in its thickness resulted in a decrease in current density.

7.
Micromachines (Basel) ; 9(11)2018 Oct 29.
Artículo en Inglés | MEDLINE | ID: mdl-30715054

RESUMEN

The form of the collection of bio-signals is becoming increasingly integrated and smart to meet the demands of the age of smart healthcare and the Fourth Industrial Revolution. In addition, the movement patterns of human muscles are also becoming more complex due to diversification of the human living environment. An analysis of the movement patterns of normal people's muscles contracting with age and that of patients who are being treated in a hospital, including the disabled, will help improve life patterns, medical treatment patterns, and quality of life. In this study, the researchers developed a smart electromyogram (EMG) sensor which can improve human life patterns through EMG range and pattern recognition, which is beyond the conventional simple EMG measurement level. The developed sensor has a high gain of 10,000 times or more, noise of 500 uVrms or less, and common mode rejection ratio (CMRR) of 100 dB or more for EMG level and pattern recognition. The pattern recognition time of the sensor is 30 s. All the circuits developed in this study have a phase margin of 75 degrees or more for stability. Standard 0.25 µm complementary metal oxide semiconductor (CMOS) technology was used for the integrated circuit design. The system error rate was confirmed to be 1% or less through a clinical trial conducted on five males in their 40s and three females in their 30s for the past two years. The muscle activities of all subjects of the clinical trial were improved by about 21% by changing their life patterns based on EMG pattern recognition.

8.
Curr Biol ; 25(10): 1362-7, 2015 May 18.
Artículo en Inglés | MEDLINE | ID: mdl-25891402

RESUMEN

Fear is an adaptive mechanism evolved to influence the primal decisions of foragers in "approach resource-avoid predator" conflicts. To survive and reproduce, animals must attain the basic needs (food, water, shelter, and mate) while avoiding the ultimate cost of predation. Consistent with this view, ecological studies have found that predatory threats cause animals to limit foraging to fewer places in their habitat and/or to restricted times. However, the neurophysiological basis through which animals alter their foraging boundaries when confronted with danger remains largely unknown. Here, we investigated place cells in the hippocampus, implicated in processing spatial information and memory, in male Long-Evans rats foraging for food under risky situations that would be common in nature. Specifically, place cells from dorsal cornu ammonis field 1 (CA1) were recorded while rats searched for food in a semi-naturalistic apparatus (consisting of a nest and a relatively large open area) before, during, and after encountering a "predatory" robot situated remotely from the nest. The looming robot induced remapping of place fields and increased the theta rhythm as the animals advanced toward the vicinity of threat, but not when they were around the safety of the nest. These neurophysiological effects on the hippocampus were prevented by lesioning of the amygdala. Based on these findings, we suggest that the amygdalar signaling of fear influences the stability of hippocampal place cells as a function of threat distance in rats foraging for food.


Asunto(s)
Conducta Animal/fisiología , Hipocampo/citología , Hipocampo/fisiología , Neurofisiología/métodos , Amígdala del Cerebelo/citología , Amígdala del Cerebelo/fisiología , Animales , Conducta Alimentaria , Hambre , Masculino , Neurofisiología/instrumentación , Conducta Predatoria , Ratas Long-Evans , Robótica , Memoria Espacial
9.
Luminescence ; 30(4): 416-9, 2015 Jun.
Artículo en Inglés | MEDLINE | ID: mdl-25131636

RESUMEN

The electrical conductivity behavior of a fluorinated self-assembled monolayer (FSAM) of a molybdenum oxide (MoOx)-doped α-naphthyl diamine derivative (α-NPD) in organic light-emitting diodes (OLEDs) was investigated. The current density of the MoOx-doped α-NPD/FSAM device was proportional to its voltage owing to smooth carrier injection through the FSAM and the high carrier density of its bulk. The temperature-dependent characteristics of this device were investigated. The current density-voltage characteristics at different temperatures were almost the same owing to its very low activation energy. The activation energy of the device was estimated to be 1.056 × 10(-2) [eV] and was very low due to the inelastic electron tunneling of FSAM molecules.


Asunto(s)
Iluminación/instrumentación , Molibdeno/química , Conductividad Eléctrica , Diseño de Equipo , Óxidos/química , Temperatura
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