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In glucose biofuel cells (G-BFCs), glucose oxidation at the anode and oxygen reduction at the cathode yield electrons, which generate electric energy that can power a wide range of electronic devices. Research associated with the development of G-BFCs has increased in popularity among researchers because of the eco-friendly nature of G-BFCs (as related to their construction) and their evolution from inexpensive bio-based materials. In addition, their excellent specificity towards glucose as an energy source, and other properties, such as small size and weight, make them attractive within various demanding applied environments. For example, G-BFCs have received much attention as implanted devices, especially for uses related to cardiac activities. Envisioned pacemakers and defibrillators powered by G-BFCs would not be required to have conventional lithium batteries exchanged every 5-10 years. However, future research is needed to develop G-BFCs demonstrating more stable power consistency and improved lifespan, as well as solving the challenges in converting laboratory-made implantable G-BFCs into implanted devices in the human body. The categorization of G-BFCs as a subcategory of different biofuel cells and their performance is reviewed in this article.
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In the present work, a novel sensor developed for the quantification of quercetin (QRC) is being reported. Due to synergistic effects of Aloe vera and titanium oxide, voltammetric performance of the developed sensor (ALV-TiO2/glassy carbon electrode) was greatly enhanced. The fabricated sensor was characterized by scanning electron microscopy, X-ray diffraction, energy dispersive X-ray, and electrochemical impedance spectroscopy. The sensor was applied to study electrochemical behavior of QRC using square wave voltammetry. Under optimal condition, the developed sensor exhibited a linear response in the range of 3.3 × 10-7 to 2.31 × 10-6 µM with a detection limit of 0.8 nM. The analytical utility of the proposed sensor was justified by applying it for the analysis of QRC in real samples.
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The herbicide Triclopyr (TCP) is widely applied to minimize the growth of woody plants. Monitoring of TCP is of major environmental concern due to its adverse impact on aquatic organisms, soils and animals. Electrochemical behavior of TCP was investigated at C70 decorated PANI modified glassy carbon sensor (PANI/C70/GC). The experimental parameters, such as concentration, pH, amplitude, frequency, deposition potential were optimized. The modified sensor exhibited an excellent catalytic response towards the reduction of TCP with a well-defined reduction peak at 1.72 V. The developed sensor was characterized by scanning electron microscopy (SEM), fourier transform infrared spectroscopy (FTIR), X-Ray diffraction (XRD) and electrochemical impedance spectroscopy (EIS). The electrochemical measurements were carried out using square wave (SWV) and cyclic voltammetry (CV). The modified sensor exhibited linear calibration curve for TCP over a concentration range of 10 ngmL-1-100 ngmL-1 with detection limit of 1.9 ngmL-1. The developed sensor could detect TCP efficiently without any interference from the common metabolites. The voltammetric procedure was applied successfully to real sample analysis with high sensitivity and good selectivity.
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Introduction: Marginal seal integrity is important for a successful adhesive dental restoration. Alterations caused by laser irradiation in the enamel and dentin surface can affect the marginal integrity of adhesive restorations. The aim of this study was to evaluate the microleakage of a composite resin restoration in primary teeth following laser irradiation of enamel and dentin. Methods: Forty freshly extracted sound human primary maxillary and mandibular anterior teeth were used in this study. The teeth were randomly divided into two groups (I and II), with 20 teeth in each. In group I, proximal cavities (Class III) were prepared using an airotor hand -piece and diamond bur. The cavities were etched for 15 seconds with 35% phosphoric acid gel, rinsed with water for 15 seconds, air dried and a bonding agent was applied onto the cavity surfaces and light cured for 20 seconds. The cavities were restored with composite resin and light cured for 40 seconds. In group II, proximal (Class III) cavities were prepared using Erbium, Chromium: Yttrium Scandium Gallium Garnet (Er,Cr:YSGG) (Er,Cr:YSGG) (Biolaseiplus, wave length 2.78 µm). The cavity was then rinsed, air dried and without etching, a bonding agent was applied and light cured for 20 seconds. The cavities were restored in the same manner as that of group I. The treated teeth were mounted on acrylic resin blocks and were subjected to a thermocycling regimen. Following, the teeth were immersed in 2% methylene blue for 24 hours. The teeth were sectioned longitudinally in a bucco-lingual direction using a diamond disc at slow speed. The sections of all the groups were examined under a stereomicroscope for micro-leakage. Results: The mean scores for microleakage in group I was 1.95 ± 1.31 and in group II it was 1.4 ± 1.27. There was no significant difference between the two groups (P = 0.882). Conclusion: No significant difference in microleakage was noticed between the composite resin bonded to lased enamel and dentin and the teeth preparedwith conventional method.
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OBJECTIVE: THE AIM WAS TO EVALUATE THE EFFECT OF ER, CR: YSGG laser and casein phosphopeptide-amorphous calcium phosphate (CPP-ACP) on surface micro-hardness of primary tooth enamel. MATERIALS AND METHODS: A total of 30 freshly extracted caries free primary anterior teeth were cleaned and stored in 1% thymol. Teeth were embedded in acrylic resin such that only their buccal surfaces were exposed and were divided into four groups. Group I: Five intact teeth (negative control). The remaining 25 teeth were immersed for 30 min in 1% citric acid for demineralization. Group II: Five demineralized teeth (positive control), Group III: CPP-ACP (GC tooth mousse-GC International, Itabashi-Ku, Tokyo, Japan) application and Group IV: Etching using Er, Cr: YSGG laser + CPP-ACP application. Groups III and IV were subjected to pH cycling for 5 days. Surface micro-hardness of all the teeth was measured using Brinell hardness tester (Fuel Instruments and Engineers Pvt. Ltd.). Data were analyzed using ANOVA. RESULTS: Mean surface micro-hardness of Groups I and II were 177.43 kgf/mm(2) and 164.86 kgf/mm(2), respectively. Group IV showed a higher mean surface micro-hardness (230.68 kgf/mm(2)) compared with that of Group III (190.28 kgf/mm(2)). In comparison to all other groups, laser etching prior to CPP-ACP application increased surface micro-hardness significantly (P < 0.001). CONCLUSION: Laser irradiation of primary teeth followed by CPP-ACP application increased surface micro-hardness of enamel.