1.
Acta Crystallogr C
; 67(Pt 2): m56-8, 2011 Feb.
Artículo
en Inglés
| MEDLINE
| ID: mdl-21285497
RESUMEN
The title complex, [Cd(2)(C(2)H(2)N(3))(OH)(SO(4))](n), is a three-dimensional metal-organic framework consisting of pseudo-cubane-like tetranuclear cadmium clusters, which are formed by four Cd(II) atoms, two sulfate groups and two hydroxide groups. The tetranuclear cadmium clusters are connected into a layered substructure by Cd-O bonds and adjacent layers are linked by triazolate ligands into a three-dimensional network. A photoluminescent study revealed that the complex exhibits a strong emission in the visible region which probably originates from a π-π* transition.