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The modern world requires a chemical industry that can run at low production costs while producing high-quality products with minimal environmental impact. The development of environmentally friendly, cost-effective, and efficient wastewater treatment materials remains a major problem for the sustainable approach. We prepared nanoscale cadmium sulfide (CdS)-enwrapped polypyrrole (PPy) polymer composites for degradation of organic pollutants. The prepared CdS@PPy nanocomposites were characterized by powder X-ray diffraction, scanning electron microscope (SEM), field emission scanning electron microscope (FESEM), Fourier transform infrared spectroscopy (FTIR), and ultraviolet-visible (UV) absorption spectroscopy, indicating proper intercalation between CdS and PPy. Consequently, the catalytic efficiency of the synthesized hybrid nanocomposites was analyzed through the degradation of methylene blue (MB) and rhodamine B (Rh B) under visible light irradiation. The measured degradation efficiency of the dye solutions under the photolysis process is about 18% and 23% for MB and Rh B dye, respectively. Furthermore, the recycle test result concludes that the CdS@PPy composite exhibits 91% and 89% of MB and Rh B dye degradation efficiency even at the 4th cycle, respectively. The positive synergistic impact of CdS and PPy may be the result of effective photocatalytic degradation of MB and RhB.

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Agriculture is having a major role in solving issues associated with food shortages across the globe. Carbendazim (CZM) is one of the fungicides which is commonly used in agriculture to grow crops in large quantities and fast. Monitoring CZM content is in high demand for environmental remediation. The present work deals with the synthesis of gadolinium sesquisulfide anchored Nitrogen-doped reduced graphene oxide (Gd2S3/NRGO) through a simple microwave-assisted method. X-ray diffraction and morphological studies confirm the formation of the nanocomposite. Gd2S3/NRGO showed enhanced activity both in electrochemical detection and light-driven degradation of CZM compared to Gd2S3 and NRGO. Gd2S3/NRGO modified glassy carbon electrode (GCE) exhibit a wide linear range of 0.01-450 µM CZM with 0.009 µM LOD using differential pulse voltammetry (DPV). Gd2S3/NRGO@GCE showed good selectivity, stability, and recovery (98.13-99.10%) in the river water sample. In addition, Gd2S3/NRGO has been explored towards the visible-light-induced degradation of CZM. The reactions conditions were optimized to achieve maximum efficiency. 94% of CZM was degraded within 90 min in presence of Gd2S3/NRGO. Mechanism of electrochemical redox reaction and degradation of CZM in presence of Gd2S3/NRGO has been explored to the maximum extent possible. Degradation intermediates were identified using LC-MS.

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In the current work, we present the facile one-pot synthesis of 0.0, 0.5, 1.0, 2.0 and 3.0 wt% of Ni doped ZnO nanoparticles (Ni:ZnO NPs) through combustion route at 550 °C. Structural and vibrational studies approve the synthesis of monophasic hexagonal Ni:ZnO NPs. The crystallite size was calculated to be in the range of 36-60 nm for pure and doped samples. The composition of all elements in the final product along with their homogeneity, was approved through EDX/FESEM e-mapping analysis. The morphology and phase confirmation of the prepared samples was investigated through FESEM and TEM/HRTEM analyses. TEM/HRTEM study shows that the size of grains is within the range of 100 nm and grown along the c-axis as the lattice spacing is found ∼2.6005 Å. Diffused reflectance study was used to estimate the energy gap for all samples and found to reduce from 3.287 eV for pure to 3.258 eV for 3.0 wt% Ni doping. From an applications point of view, the photocatalytic performance of Ni:ZnO NPs was studied, and with 3.0 wt% of Ni doping in ZnO the degradation of methylene blue (MB) and tetracycline (TCN) pollutants were found to be remarkably improved.

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An effective heterojunction with robust charge separation and enormous degradation efficiency is the major task for photocatalyst preparation. In this study, we have prepared the FeCo2O4-loaded g-C3N4 nanosheet by the sol-gel-assisted calcination method for photo-Fenton-like degradation under visible-light irradiation by activating persulfate. The nanocomposite exhibits a higher charge separation efficiency than pure g-C3N4 and FeCo2O4 for the degradation reaction against naproxen drugs. An effective interaction between the nanoparticles increases the degradation efficiency up to 91% with a synergistic index of 73.62%. Moreover, the nanocomposite exhibits a 78% mineralization efficiency against the naproxen pollutant under visible-light irradiation. For practical implementation, the degradation reaction was tested with various pH values, different water sources (DI, lake, and tap water), and light sources (LED (visible)/direct sunlight (UV-visible)). Moreover, the possible degradation mechanism predicted by the elemental trapping experiment and the recycling experiment clearly revealed that the heterojunction composite has a high enough degradation stability.

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A carbon dot (CD)-intercalated NiFe2O4 (NFO)/graphitic carbon nitride (g-C3N4, g-CN) ternary Z-scheme heterojunction was synthesized by the facile wet chemical method and used for photo-Fenton degradation. The structural, optical, electrical, vibrational, and morphological properties of the photocatalysts were investigated through various analytical methods. The CD-intercalated heterojunction formation was analyzed by high-resolution transmission electron microscopy (HRTEM). The intercalated CD acted as an electron donor/acceptor, which converted a type-II heterojunction to a Z-scheme heterojunction. The formation of Z-scheme heterojunction was confirmed by the enormous production of radicals (hydroxyl (OH•) and superoxide (O2 -)) and the elemental trapping experiment. In particular, the heterojunction photocatalyst NFO/5g-CN/7.5CD showed the highest photo-Fenton degradation efficiency of 99% for rhodamine B (Rh B) and 93% for tetracycline (TCN) in the presence of H2O2. The charge separation and electron transport behaviors of the photocatalyst were examined by photoluminescence (PL) and photocurrent measurements. In the Z-scheme photo-Fenton system, hydroxyl and superoxide radicals played a vital role in the visible-light-driven degradation process. Hence, the prepared Z-scheme ternary photocatalyst is well suitable for wastewater treatment in practical use.

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Herein, a strong redox ability photocatalyst of CdCuS solid solution composited with pyrochlore like Bi2Zr2O7 has been fabricated by the simple hydrothermal method. The robust CdCuS solid solution materials perform the supporting role to the Bi2Zr2O7 nano materials. The structural, optical, valence and vibrational states of the prepared heterostructure materials were analyzed using various characterization techniques. The photocatalytic activity of the as-synthesized Bi2Zr2O7/CdCuS heterostructure has been verified under direct solar light and ambient conditions. The synthesized Bi2Zr2O7/CdCuS nano combination exhibits a better photocatalytic activity for the removal of methylene blue and 4-nitrophenol organic probe molecules. The heterostructure formation between the samples is confirmed by HRTEM analysis. The improved rate of the photocatalytic reaction of the samples is attributed to the formation of heterostructures at the interface. The close interfacial contact between the two materials discloses the effective charge transfer, which leads to suppressed charge carrier recombination. The enhanced photo catalytic activity of redox-mediator-free-Bi2Zr2O7/CdCuS heterostructure, possibly will be credited to the robust redox ability and the several charge transfer channels in the tight contact. The chief radicals produced in the catalytic reduction reaction have been predicted by the scavenger trapping methods and the results are discussed in detail. The obtained information from this study on Bi2Zr2O7/CdCuS delivers some new visions for the design of active photocatalysts with multiple benefits.

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The design of UV-visible light active photocatalysts for organic pollutant removal is a challenging task. Herein, we have developed an LED light active ZnO-embedded S-doped g-C3N4 (SCN) heterojunction by a facile sol-gel assisted calcination method. The heterojunction between ZnO and SCN nanoparticles generates a Z-scheme photocatalyst, which helps to separate the photo-induced charge carriers in the opposite direction, and is beneficial for more visible light absorption for photocatalytic dye degradation. The composite heterojunction shows better photocatalytic redox in comparison with pristine nanomaterials. The enhanced degradation efficiency is attributed to the high production rate of ˙OH (hydroxyl) radicals during the photocatalysis process, which is analyzed by the TA test and elemental trapping experiment. Hence, we hope that this Z-scheme heterojunction provides a new way to develop UV-visible light active photocatalysts for environmental remediation applications.

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The BiFeO3/V2O5 has been successfully synthesized by simple annealing of BiFeO3 nanoplates and V2O5 nanoflower. The phase, structural, optical properties and chemical state of the BiFeO3, V2O5 and different composition of BiFeO3/V2O5 samples were comparatively characterized by various spectroscopic and microscopic techniques. The prepared catalyst exhibits unique photo catalytic and post-oxidation/reduction ability for removal of various (MB, Phenol, CV, RhB) water organic pollutants. Compared to pure BiFeO3 and V2O5, the different Wt % of BiFeO3/V2O5 composition exhibited higher photo catalytic activity. The fortunate BiFeO3/V2O5 interface hybrid photo catalyst makes a significant impact in the enhancement of photo catalytic reaction. This remarkable efficiency could be ascribed to the synergistic effect between the V2O5 petals and BiFeO3 plates. The exceptional morphology, increased surface area, uniformity, less-agglomerated spreading could increase the ability of visible light response, which lead the improved electron transport ability and the higher charge separation. The enhanced rate of photo generated charge carriers separations were evinced by the EIS and PL spectrum measurements. The allowed radical trapping experiment divulge that the hole (h+), and super oxide radical (O2-) are the minimized effect in degradation, on the other hand hydroxyl radical (OH) is plays the foremost role and act as the active radicals in the catalytic organism. In relations of above investigation, a probable photo degradation mechanism of the as-synthesized photo catalyst is carefully explicated. This effort delivers an effective approach to design and fabricate the efficient photo catalyst through integrating of materials, which has a potential for industrial waste water purification.

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