1.
Chem Commun (Camb)
; 60(13): 1770-1773, 2024 Feb 08.
Artículo
en Inglés
| MEDLINE
| ID: mdl-38252318
RESUMEN
Reported herein is an efficient and eco-friendly peri-selective monohydroxylation of naphthalene monoimides (NMIs) to access 4-hydroxy NMIs, which possess multidisciplinary applications. The key aspect of this method is the utilization of cobalt(II)-catalysis via a single electron transfer mechanism to achieve site-selective C(sp2)-hydroxylation. Transformation of the hydroxyl group into pseudohalides reveals its applications towards cross-coupling reactions.