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1.
Mol Inform ; 30(2-3): 276-85, 2011 Mar 14.
Artículo en Inglés | MEDLINE | ID: mdl-27466781

RESUMEN

The growth response of 25 Trichoderma strains to 26 alkanols and 7 other organic solvents was examined in vitro. The sensitivity of strains considerably varied depending on their taxonomic position, thus the strains of Longibrachiatum section proved to be more tolerant than those of Pachybasium and Trichoderma sections. Significant relationship was revealed between structure of C1 -C24 alkanols and their growth inhibitory effect to Trichodermas, both efficacy and selectivity of C1 -C3 and C14 -C24 alkanols failed off the C9 -C11 alkanols. The non-alkanol solvents tested were non-toxic. The C8 -C11 alkanols used in agricultural practices exhibited noticeable toxicity to all Trichoderma strains, therefore pesticidal preparations containing these alkanols cannot be used simultaneously with Trichoderma based biopreparations.

2.
J Sep Sci ; 31(6-7): 1057-9, 2008 Apr.
Artículo en Inglés | MEDLINE | ID: mdl-18335475

RESUMEN

The quantitative relationship between the TLC retention parameters of 28 short peptides and their physicochemical characteristics was calculated using linear regression analysis. It was established that surface parameters exert a significant impact on the retention of peptides and the ratio of non-polar surface area/polar surface area exerts the highest influence on the retention. This result may be due to the fact that peptides turn towards the apolar surface of the stationary phase with their non-polar substructures while the polar molecular parts point into the hydrophilic mobile phase.


Asunto(s)
Péptidos/química , Secuencia de Aminoácidos , Fenómenos Químicos , Química Física
3.
Environ Int ; 30(7): 953-71, 2004 Sep.
Artículo en Inglés | MEDLINE | ID: mdl-15196844

RESUMEN

The more recent methods for the removal of synthetic dyes from waters and wastewater are complied. The various methods of removal such as adsorption on various sorbents, chemical decomposition by oxidation, photodegradation, and microbiological decoloration, employing activated sludge, pure cultures and microbe consortiums are described. The advantages and disadvantages of the various methods are discussed and their efficacies are compared.


Asunto(s)
Bacterias/metabolismo , Color , Colorantes/química , Hongos/metabolismo , Eliminación de Residuos Líquidos/métodos , Purificación del Agua/métodos , Adsorción , Catálisis , Colorantes/metabolismo , Peróxido de Hidrógeno , Organismos Modificados Genéticamente , Oxidación-Reducción , Ozono , Fotólisis , Titanio
4.
Chemosphere ; 52(1): 185-93, 2003 Jul.
Artículo en Inglés | MEDLINE | ID: mdl-12729701

RESUMEN

The growth inhibitory effect of 30 synthetic dyes on 22 bacteria (test organisms) belonging to various taxonomic groups was determined. The strength (potency) and selectivity of the biological effect were separated by the spectral mapping technique, reducing the dimensionality of the selectivity maps to two by the nonlinear mapping technique. The relationship between biological effect and physicochemical parameters of dyes was elucidated by stepwise regression analysis. It has been established that the strength of the effect of anthracene and trityl derivatives was higher than that of azobenzene dyes and significantly depended on the hydrophobicity of the compound. The selectivity of the effect also depended on hydrophobicity and on the nonpolar unsaturated surface area of the dyes. Gram negative and Gram positive bacteria differed in the strength and selectivity of their response to dyes indicating the marked impact of the taxonomical position on the response. Contrary to other multivariate mathematical statistical methods biological activity may be divided by SPM into potency and selectivity values, therefore, application of the technique in future QSAR studies is highly recommended.


Asunto(s)
Colorantes/efectos adversos , Bacterias Gramnegativas , Bacterias Grampositivas , Modelos Teóricos , Contaminantes del Agua/efectos adversos , Bioensayo , Predicción , Análisis Espectral
5.
Environ Int ; 28(5): 337-48, 2002 Nov.
Artículo en Inglés | MEDLINE | ID: mdl-12437283

RESUMEN

The newest results concerning the biological activity and environmental fate of anionic surfactants are collected and critically evaluated. The chemical and physicochemical parameters related to the biological activity and the field of application are briefly discussed. Examples on the effect of anionic surfactants on the cell membranes, on the activity of enzymes, on the binding to various proteins and to other cell components and on their human toxicity are presented and the possible mode of action is elucidated. The sources of environmental pollution caused by anionic surfactants are listed and the methods developed for their removal from liquid, semiliquid and solid matrices are collected. Both the beneficial and adversary effects of anionic surfactants on the environment are reported and critically discussed. It was concluded that the role of anionic surfactants in the environment is ambiguous: they can cause serous environmental pollution with toxic effect on living organisms; otherwise, they can promote the decomposition and/or removal of other inorganic and organic pollutants from the environment. The relationship between their chemical structure, physicochemical parameters, biological activity and environmental impact is notwell understood. A considerable number of data are needed for the development of new anionic surfactants and for the successful application of the existing ones to reduce the adversary and to promote beneficial effects.


Asunto(s)
Contaminantes Ambientales/efectos adversos , Tensoactivos/efectos adversos , Animales , Fenómenos Químicos , Química Física , Contaminantes Ambientales/análisis , Humanos , Residuos Industriales , Medición de Riesgo , Tensoactivos/análisis , Tensoactivos/química
6.
Environ Toxicol Chem ; 21(6): 1206-12, 2002 Jun.
Artículo en Inglés | MEDLINE | ID: mdl-12069304

RESUMEN

The fungicidal activity of 10 trityl dyes and six reference compounds was determined on 36 fungal strains, and the data matrix was evaluated separately by principal component analysis (PCA) and by spectral mapping technique (SPM). The dimensionality of the maps of the principle component loadings and variables and the selectivity maps were reduced to two by varimax rotation and by nonlinear mapping. Calculations proved that both the strength and selectivity of the fungicidal activity of trityl dyes considerably depended on the chemical structure of the dye and on the type of fungi. Both PCA and SPM were suitable for evaluation of the antifungal activity of dyes; however, the strength and selectivity of the fungicidal effect can be separated only by SPM. Due to its advantageous application parameters, use of SPM in future quantitative structure-activity relationship studies is highly recommended.


Asunto(s)
Colorantes/farmacología , Modelos Teóricos , Compuestos de Tritilo/farmacología , Hongos/efectos de los fármacos , Fungicidas Industriales/farmacología , Pruebas de Sensibilidad Microbiana
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