RESUMEN
The poor access to water quality for Nigerians has pushed for the designing of new trend silver nitrate impregnated locally made Point-Of-Use (POU) ceramic filters to enhance water purification efficiency for household use. This study utilized silver nitrate-molded ceramic filters prepared with Kaolin from Owode, silt soil, sodium silicate, sawdust, and distilled water in three varying proportions to ascertain pollution removal efficiencies. Heating was carried out by firing the filters at 900 °C and further preheating at 400 °C after dipping in silver nitrate solution. Silver nanoparticle and dissociated particle discharge from filter pot painted with 0.03 mg/g casein-covered nAg or AgNO3 were estimated as an element of pH (5-9), ionic strength (1-50mM), and cation species (Na+, Ca2+, Mg2+). Silver delivery was constrained by disintegration as Ag+ and resulting cation exchange measures, paying little heed to silver structure applied. Water analysis for both heavy metals (Pb and Cd) and microbial load (E. coli) evaluated, corroborate the maximum removal efficiency. It was observed that kaolin-sawdust with the Silver nitrate filters showed a constant and effective removal of both heavy metals and disinfection of microbial loads. The minimum flow rates observed were 4.97 mL/min for batch filter used for Iju River water sample one (AF1) and 4.98 mL/min for batch filter used for Iju River water sample two (AF2) having porosity 49.05% and 50.00%, whereas the 5 mL/min higher flow rate was used for batch filter from borehole water sample one (BF1) and batch filter used for well water sample two (CF2) with porosity of 50.00%. Significantly, the results obtained show that the filters are suitable for point-of-use application in both the urban and rural areas of developing countries such as Nigeria.
RESUMEN
This study assessed the radioactivity level of Iju River sediments and its associated radiological risks exposure to human. Gamma absorbed dose rates were measured using a portable gamma spectrometer at an interval of 50 m between each point (Model No:RS-125 manufactured by Canadian Geophysical Institute). The measured absorbed gamma dose rates range from 22 to 59 nGy/h with the highest value noted in site 13. The mean activity concentrations of U-238, Th-232 and K-40 from Iju river sediments were 24.1 ± 0.4 Bq/kg, 35.2 ± 1.1 Bq/kg and 501.0 ± 11.1 Bq/kg, which were lower than the world average values of 32 and 45 for U-238 and Th-232 by 25% and 21% and higher than 412 Bq/kg for K-40 by a factor of 0.22 (22%).â¢This highest value of K-40 found in site 6 may be due to the presence of feldspartic minerals buried in the sediments.â¢Consequently, the radiological hazard indices were below the permissible limits except the mean value of 28 × 10-2 for excess lifetime cancer risk (ELCR) for the samples collected in site 6, which is higher than the average world value of 0.29 × 10-3 by a factor of 0.03.â¢The regression model indicates that Th-232 attributes more radioactivity impacts on the soil sediments than the contributions of U-232 and K-40, as such, presumed to be the radionuclide parameter controlling the depositional process in the region.