RESUMEN
The treatment of flue gases has become a crucial area of interest with the increasing air emissions into the atmosphere from industries involved in combustion of fossil fuels in their operations. In essence, there is a critical need for effective methods of treatment more than ever. Treatment and separation are now a demand for the overall industrial operations to control the rate of flue gas emissions. The major culprit in this wise is power generating industry. The major associated air pollutants are carbon dioxide, sulfur oxides, trace metals, volatile organic compounds, particulate matters, and nitrogen oxides. However, the choice of technologies to be utilized requires more than just knowledge of the separation process, but also a good understanding of the properties of the pollutants. This review explored and evaluated the various separation processes and technologies for the treatment of industrial flue gases for the control of the associated air pollutants. It also analyzed the performance with references to cost and efficiency, the advantages and disadvantages, principles for selection, research direction, and/or potential opportunities in existing separation processes and technologies.
RESUMEN
Mosquito coils of various brands are frequently burnt in indoor environments to drive away mosquitoes-the vector for malaria parasite in regions where the disease is endemic. Emissions from the coils could be a source of indoor air pollution. In this study, various brands of mosquito coils obtained from retail shops in Lagos, Nigeria were burnt in an environmental test box with a view to characterizing carbon monoxide (CO), nitric oxide (NO), and nitrogen dioxide (NO2) in the gaseous emissions as well as elemental concentrations of the ash. Emission characterization achieved with the RAS1700 bio-gas analyzer while AAS was adopted for elemental analysis of the mosquito coil ashes. The emission factor of CO, NO and NO2 from the coil samples ranged between 0.00138 to 0.26277 µg/m3, 0.0002 to 0.00454 µg/m3, and 0.000074 to 0.00714 µg/m3, respectively. These values were found to be lower than permissible indoor levels recommended by NIOSH. The range of concentrations of Pb, Zn, Cd, Cr, Cu, As, Hg, Fe in the coil ashes from all the brands were 0.02 to 0.04 mg/g, 0.011 to 0.02 mg/g, 0.001 to 0.003 mg/g, 0.004 to 0.008 mg/g, 0.004 to 0.006 mg/g, 0.0001 to 0.0004 mg/g, 0.001 to 0.003 mg/g, and 0.124 to 0.14 mg/g, respectively. Although, the concentrations of the pollutants obtained in this study are within the recommended limits, prolong exposure could trigger chronic disease conditions. Adequate ventilation of indoor environments or utilization of mosquito nets in place of coils could be considered.
RESUMEN
As a way of wastes-to-voltage conversion, experimental benchtest trial of electricity generation from a blend of cocoa and kolanut harvest by-products is presented in this study. Bioethanol obtained from the blend, through a process of alcoholic fermentation, was mixed with gasoline at specific proportion and employed to fire a spark ignition engine that served as a prime-mover in driving a four-pole three-phase salient-pole synchronous machine. Performance of the driving machine, as the fuel-mix proportion and its speed of rotation varied, was studied. Likewise, the electric power output characteristic of the driven machine, when operated at its rated synchronous speed, was examined. It was found that the driving machine performed better on mixed fuel than pure gasoline. There were gradual increases in the torque and the power developed by the machine as the proportion of ethanol in the fuel-mix and the rotational speed increased. While the highest values of torque and power developed on using pure gasoline were 12.4 Nm and 2574 W respectively at 1900 rpm, 13.1 Nm torque and 2953 W power were obtained from the machine when ignited with 10%-bioethanol fuel-mix at the same speed. Also, with 90 Vdc excitation voltage and rotation at 1500 rpm synchronous speed, the driven machine continuously generated electricity at 207.6 Vrms (line-to-line), 1.169 A, 0.698 power factor, 48.17 Hz, 0.294 kW output. This study demonstrated the possibility of continuous generation of electric power from cocoa and kolanut wastes. Result obtained from the laboratory-based trial indicates that at such agricultural regions that are advantaged in the production of the two crops, harvest residues of the crops can be explored as a steady source of biofuel for off-grid microgrid electrification.
RESUMEN
Huge quantities of harvest wastes that are generated from agricultural practices at every farming season in Nigeria are not put into significant use. As an attempt towards adopting these abundant by-products as bioenergy resources for electricity generation, yearly quantities of both cocoa and kolanut harvest residues were estimated in this study. Hygroscopic natures and moisture contents of the two, and their blends, were also analyzed and compared. It was estimated that approximately 681,000 tons and 90,000 tons of cocoa and kolanut husks respectively, are produced in the country annually. While the proximate analyses showed that the sample made of 100% cocoa waste had the least volatile matter and moisture contents in addition to having highest fixed ash and fixed carbon contents, the reverse was the case with the sample made of 100% kolanut waste composition. From the ultimate analyses, however, the latter appears to possess the best characteristic (highest hydrogen and least oxygen contents), but its highest nitrogen content is a pointer to its exhibition of poor thermal property. The gross calorific contents of the samples were, therefore employed for definitive determination of their thermoelectric potentials and these gave higher heating values of 15.19 MJ/kg and 13.87 MJ/kg respectively, with the blends having their values within this range in proportionality to the mass percentage of kolanut husk in the blends. In addition to the two wastes exhibiting good energy characteristics, the study concludes that their blending offers benefit of reduction in ash content. At the optimal blend of equal composition of the two materials (50%CPH/50%KPH), it was estimated that 29,000 MW of electricity is accruable from the wastes.