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1.
Chem Commun (Camb) ; 52(82): 12151-12154, 2016 Oct 06.
Artículo en Inglés | MEDLINE | ID: mdl-27549372

RESUMEN

A novel indirect charging system that uses a redox mediator was demonstrated for Li-O2 batteries. 4-Methoxy-2,2,6,6-tetramethylpiperidinyl-1-oxyl (MeO-TEMPO) was applied as a mediator to enable the oxidation of Li2O2, even though Li2O2 is electrochemically isolated. This system promotes the oxidation of Li2O2 without parasitic reactions attributed to electrochemical charging and reduces the charging time.

2.
Chem Commun (Camb) ; 49(75): 8389-91, 2013 Sep 28.
Artículo en Inglés | MEDLINE | ID: mdl-23939341

RESUMEN

Precise knowledge of the discharge and charge reactions within Li-O2 batteries is an important aspect of developing highly efficient, rechargeable Li-O2 cells. We describe an analytical method capable of determining the quantity of Li2O2 in the cathode on the basis of the reaction of Li2O2 with an oxoammonium salt.

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