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Artículo en Inglés | MEDLINE | ID: mdl-28763240

RESUMEN

This investigation was undertaken to describe a natural process for the removal of silver and the simultaneous recovery of Ag/Ag2O nanoparticles by dead biomass of the yeast Rhodotorula mucilaginosa. The removal of silver ions from aqueous solution and the synthesis of Ag/Ag2O nanoparticles were analyzed based on physicochemical factors and equilibrium concentration, combined with transmission electron microscopy (TEM), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), X-ray photoelectron spectroscopy (XPS), and infrared spectroscopy (FTIR). A successful process for the synthesis of Ag/Ag2O nanoparticles was obtained, following the Langmuir isotherm model, showing a high biosorption capacity of silver (49.0 mg g-1). The nanoparticles were spherical, had an average size of 11.0 nm, were synthesized intracellularly and capped by yeast proteins. This sustainable protocol is an attractive platform for the industrial-scale production of silver nanoparticles and of a silver nanobiosorbent.


Asunto(s)
Biomasa , Nanopartículas del Metal/química , Óxidos/química , Rhodotorula/química , Compuestos de Plata/química , Plata/química , Adsorción , Biodegradación Ambiental , Modelos Teóricos , Nanotecnología , Rhodotorula/crecimiento & desarrollo , Rhodotorula/ultraestructura , Propiedades de Superficie
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