RESUMEN
In the title compound, [PdBr(C17H17N2O5)], the Pd(II) atom is coordinated by an N,C(1),N'-tridentate pincer ligand and a Br atom in a distorted square-planar geometry. In the crystal, mol-ecules are connected by C-Hâ¯Br and C-Hâ¯O hydrogen bonds, and π-π inter-actions between the oxazole and benzene rings [centroid-centroid distance = 3.7344â (19)â Å], resulting in a three-dimensional supra-molecular structure.
RESUMEN
Bis(thiazole) pincer palladium complexes showed efficient catalytic activity for the Suzuki-Miyaura coupling of aryl halides, allowing the synthesis of biaryls with very high turnover numbers and turnover frequencies. The complexes were successfully applied in the scalable and green synthesis of the key intermediates of bioactive LUF5771 and its analogues.