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Spectrochim Acta A Mol Biomol Spectrosc ; 192: 487-498, 2018 Mar 05.
Artículo en Inglés | MEDLINE | ID: mdl-29133132

RESUMEN

The natural dyes anthocyanin and chlorophyll were extracted from Musa acuminata bracts and Alternanthera dentata leaves, respectively. The dyes were then applied as sensitizers in TiO2-based dye-sensitized solar cells (DSSCs). The ethanol extracts of the dyes had maximum absorbance. High dye yields were obtained under extraction temperatures of 70 to 80°C, and the optimal extraction temperature was approximately 80°C. Moreover, dye concentration sharply decreased under extraction temperatures that exceeded 80°C. High dye concentrations were obtained using acidic extraction solutions, particularly those with a pH value of 4. The DSSC fabricated with anthocyanin from M. acuminata bracts had a conversion efficiency of 0.31%, short-circuit current (Isc) of 0.9mA/cm2, open-circuit voltage (Voc) of 0.58V, and fill factor (FF) of 62.22%. The DSSC sensitized with chlorophyll from A. dentata leaves had a conversion efficiency of 0.13%, Isc of 0.4mA/cm-2,Voc of 0.54V, and FF of 67.5%. The DSSC sensitized with anthocyanin from M. acuminata bracts had a maximum incident photon-to-current conversion efficiency of 42%, which was higher than that of the DSSC sensitized with chlorophyll from A. dentata leaves (23%). Anthocyanin from M. acuminata bracts exhibited the best photosensitization effects.


Asunto(s)
Amaranthaceae/química , Colorantes/aislamiento & purificación , Musa/química , Hojas de la Planta/química , Energía Solar , Antocianinas/química , Calibración , Clorofila/química , Electroquímica , Concentración de Iones de Hidrógeno , Fotones , Extractos Vegetales/química , Solventes/química , Espectrometría por Rayos X , Espectroscopía Infrarroja por Transformada de Fourier , Propiedades de Superficie , Temperatura , Titanio/química , Difracción de Rayos X
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