RESUMEN
This study investigates the effect of a natural dye extracted from common poppy (Papaver rhoeas) waste flowers on the optical properties of chitosan (CS) films. The extraction of natural dyes from waste flowers can be considered a new field for research in green chemistry. CS films are flexible and biodegradable but have low optical activity and band gap, limiting their applications in optical devices. The doped CS polymer with different concentrations of Papaver rhoeas dye exhibited enhanced optical properties. Also, 30 % glycerol was added as a plasticizer to omit film brittleness. The FTIR examinations is helpful to propose a mechanism that explains the interaction of the dye with the host polymer. The UV-vis spectroscopic examination establish that the optical characteristics of the films can be modified by adjusting the dye concentration. Furthermore, optical absorption properties are described using the Tauc non-direct transition model, revealing an approximate optical band gap of 1.64 eV. This band gap defines the energy required for electron transitions, elucidating the material's electronic characteristics. The extinction coefficient (k) and refractive index (n) of the CS-doped films' shows a dispersion behavior at visible regions of EM radiation. The Wemple-DiDomenico single oscillator model was used to investigate the n dispersion and determine the oscillator energy equivalent to the optical band gap. Additionally, calculations have been performed on optical dielectric properties and optical conductivity. The Urbach energy was measured and used to detect the structure of the films. The findings underscore the potential applications of these natural dye-doped CS films in eco-friendly materials and optical devices.
RESUMEN
The current study employed a novel approach to design polymer composites with modified structural and declined optical band gaps. The results obtained in the present work for polymer composites can be considered an original method to make a new field for research based on green chemistry. Natural dyes extracted from green tea were mixed with hydrated zinc acetate (Zn(CH3COO)2·2H2O) to produce a metal complex. FTIR results comprehensively established the formation of the Zn-metal complex. The interaction among various components of PVA : Zn-metal complex composite was investigated using FTIR spectroscopy. The non-existence of anion bands of acetate in the Zn-metal complex spectrum confirms the formation of the Zn-metal complex. XRD analysis reveals that the Zn-metal complex improves the amorphous phase of the PVA-based composites. The absorption edge of the doped films shifted towards the lower photon energies. Optical dielectric properties were used to determine N/m*, ε ∞, τ, µ opt, ω p, and ρ opt; the W-D model was used to calculate E d, E o and n o parameters. The optical dielectric loss parameter was used to determine the optical band gap while the Tauc model was employed to identify various types of electron transitions. The optical energy band gap was 6.05 eV for clean PVA while it decreased to 1 eV for PVA inserted with the Zn-metal complex. The increase in Urbach energy from 0.26 eV to 0.45 eV is an evidence of the boost of amorphous phases in PVA : Zn-metal complex composites. The nonlinear refractive index and the first-order and second-order nonlinear optical susceptibilities were determined. The value of E o obtained from the W-D model closely matches the optical energy band gap obtained from the Tauc model, which indicates the precision of the analysis in the present study. The increase in SELF and VELF in the composite films establishes that new energy states assigned to the added Zn-metal complex amplify the probability of light-matter interaction.
RESUMEN
In the current study, the film fabrication of polystyrene (PS) based polymer nanocomposites (NCs) with tuned refractive index and absorption edge was carried out using the solution cast method. X-ray diffraction (XRD) and ultraviolet-visible (UV-Vis) light characterization techniques were performed. The structural and optical properties of the prepared films were specified. The hump of PS decreased significantly when SnTiO3 nanoparticles (NPs) were introduced. Sharp and high intense peaks of SnTiO3 NPs at a high filler ratio were observed. The crystalline size was determined for SnTiO3 NPs from the sharp crystalline peaks using Debye-Scherrer's equation and was found to be 25.179 nm, which is close enough to that described by the supplier. Several optical parameters, such as absorption coefficient (α), refractive index (n), and optical dielectric properties, were investigated. The absorption spectra were tuned with increasing SnTiO3NPs. Upon the addition of the NPs to the PS host polymer, the absorption edge undergoes shifting to lesser photon energy sides. The optical dielectric constant (ε') was correlated to the refractive index. The study of the optical band gap was conducted in detail using both Tauc's model and the optical dielectric loss (εâ³) parameter. The results showed that the εⳠparameter is noteworthy to be measured in the optical band gap study of materials.