RESUMEN
To increase the energy density of today's lithium batteries, it is necessary to develop an anode with higher energy density than graphite or carbon/silicon composites. Hence, research on metallic lithium has gained a steadily increasing momentum. However, the severe safety issues and poor Coulombic efficiency of this highly reactive metal hinder its practical application in lithium-metal batteries (LMBs). Herein, the development of an artificial interphase is reported to enhance the reversibility of the lithium stripping/plating process and suppress the parasitic reactions with the liquid organic carbonate-based electrolyte. This artificial interphase is spontaneously formed by an alloying reaction-based coating, forming a stable inorganic/organic hybrid interphase. The accordingly modified lithium-metal electrodes provide substantially improved cycle life to symmetric Li||Li cells and high-energy Li||LiNi0.8Co0.1Mn0.1O2 cells. For these LMBs, 7 µm thick lithium-metal electrodes have been employed while applying a current density of 1.0 mA cm-2, thus highlighting the great potential of this tailored interphase.
RESUMEN
Sodium-ion batteries (SIBs) are postulated as sustainable energy storage devices for light electromobility and stationary applications. The anode of choice in SIBs is hard carbon (HC) due to its electrochemical performance. Among different HC precursors, bio-waste resources have attracted significant attention due to their low-cost, abundance, and sustainability. Many bio-waste materials have been used as HC precursors, but they often require strong acids/bases for pre-/post-treatment for HC development. Here, the morphology, microstructure, and electrochemical performance of HCs synthesized from hazelnut shells subjected to different pre-treatments (i. e., no pre-treatment, acid treatment, and water washing) were compared. The impact on the electrochemical performance of sodium-ion cells and the cost-effectiveness were also investigated. The results revealed that hazelnut shell-derived HCs produced via simple water washing outperformed those obtained via other processing methods in terms of electrochemical performance and cost-ecological effectiveness of a sodium-ion battery pack.