RESUMEN
Leather post-tanning is responsible for producing effluents that are difficult to treat due to several recalcitrant pollutants. Dyes, tannins, and fatliquoring agents are mainly related to this characteristic. This study, as the state-of-the-art, attempts to systematically review treatment technologies applied in recent years to the post-tanning effluents. The Scopus database was used to identify articles related to post-tanning pollutants removal. Through the review, Advanced Oxidation Processes (AOPs) and adsorption proved to be good alternatives to increase the effluent biodegradability when applied before biological treatment. AOPs and adsorption were also efficient for the final polishing of the effluents, to reach the regulation standards for disposal, as well as enzymatic treatment. Furthermore, Membrane Separation Processes demonstrated good applicability when the reuse of the treated effluent is aimed.
Asunto(s)
Aguas Residuales , Contaminantes Químicos del Agua , Colorantes , Oxidación-Reducción , Curtiembre , Eliminación de Residuos Líquidos , Aguas Residuales/análisisRESUMEN
The leather industry uses a large amount of chemicals to transform a raw hide into finished leather. Chemicals are not fully taken up by leather and thus end up in tannery wastewater. Physicochemical and toxicological characterization of tannery effluents has been widely assessed. However, the characterization of processing chemicals and their relation to the pollution load of effluents remains unknown. Thus, this study aimed to assess a physicochemical and cytotoxic characterization of chemicals used in the leather post-tanning process and to evaluate the contribution of each chemical to the pollution load of raw wastewater. This study was performed using a leather post-tanning formulation applied by a large tannery located in Brazil. Deacidulation agents caused high conductivity and dissolved solids in wastewater. Retanning agents (natural and synthetic tannins) were responsible for the largest inorganic pollution load, and synthetic tannins were more toxic than natural ones. Fatliquoring agents released the highest chemical oxygen demand load in wastewater and they were the chemical group that presented the highest toxicity. Fixing agent and black dye provided inorganic pollution load to wastewater, and nitrogen pollution of wastewater was mainly related to the neutralizing retanner and the black dye.