RESUMEN
Iron Oxide-commercial activated carbon nanocomposite (CAC-IO) was prepared from commercial activated carbon (CAC) by the co-precipitation method, and the resulting nanocomposite was used as an adsorbent to remove hexavalent chromium (Cr6+) ions and Mordant Violet 40 (MV40) dye from wastewater. The produced materials (CAC, CAC after oxidation, and CAC-IO) were comparatively characterized using FTIR, BET, SEM, EDX TEM, VSM, and XRD techniques. The adsorption mechanism of Cr6+ ions and MV40 dye on CAC-IO was examined using Langmuir and Freundlich isotherm models.. Different models were applied to know the adsorption mechanism and it was obtained that Pseudo-second order fits the experimental data better. This means that the adsorption of the adsorbate on the nanocomposite was chemisorption. The maximum removal percent of Cr6+ ions by CAC-IO nanocomposite was 98.6% determined as 2 g L-1 adsorbent concentration, 100 mg L-1 initial pollutant concentration, solution pH = 1.6, the contact time was 3 h and the temperature was room temperature. The maximum removal percentage of Mordant Violet 40 dye (C.I. 14,745) from its solutions by CAC-IO nanocomposite was 99.92% in 100 mg L-1 of initial dye concentrations, 1.0 g L-1 of adsorbent concentration, solution pH = 2.07, the contact time was 3 h. The MV40 dye adsorption on CAC-IO was the most fitted to the Freundlich isotherm model. The maximum adsorption capacity was calculated according to the Langmuir model as 833.3 mg g-1 at 2 g L-1 of adsorbent concentration and 400 mg L-1 of initial MV40 dye concentration. The Cr6+ ions adsorption on CAC-IO was more fitted to the Freundlich model with Qmax, equal to 312.50 mg g-1 at 1 g L-1 adsorbent concentration and 400 mg L-1 of Cr6+ ions initial concentrations.
RESUMEN
In recent years, water pollution has become one of the most dangerous problems facing the world. Pollution of water with heavy metals and different dyes has caused many harmful effects on human health, living organisms and our environment. In this study, iron oxide nanomagnetic composite from Pterocladia Capillacea red algae-derived activated carbon (PCAC-IO) was synthesized by co-precipitation method using different iron salts and different base solutions. The synthesized nanocomposite was investigated with various characterization techniques such as FTIR, BET, SEM-EDX, TEM, XRD, and VSM. The obtained PCAC-IO adsorbent was used for Cr6+ ions and Mordant Violet 40 (MV40) dye removal. The adsorption mechanism of Cr6+ ions and MV40 dye on PCAC-IO was examined using several adsorption and kinetic isotherm models. Langmuir and Freundlich models were investigated using experimental data. Pseudo-first-order (PFO), Pseudo-second-order (PSO) and intraparticle diffusion models (IPDM) were applied to identify the adsorption mechanism. It has shown that the PSO kinetic model fits better with the experimental data obtained from PCAC-IO. This result can be interpreted as the adsorption of the adsorbate on the nanocomposite as chemical adsorption. The optimum conditions for maximum Cr6+ ions removal (96.88%) with PCAC-IO adsorbent occur at room temperature, 5 g L-1 adsorbent concentration, 100 mg L-1 initial pollutant concentration, pH 1 and at the end of 180 min, while maximum MV40 dye removal (99.76%), other conditions being the same, unlikely it occurred at pH 2.06 and after 45 min. The most suitable model for Cr6+ ions removal under the conditions of 1 L-1 g adsorbent concentration and 400 mg L-1 adsorbate concentration was Langmuir (Qmax = 151.52 mg g-1), while for MV40 removal it was Freundlich (Qmax = 303.03 mg g-1). We propose the use of activated carbon-supported iron oxide prepared from bio-waste material, especially from Pterocladia Capillacea red algae, as a promising adsorbent with high efficiency in the removal of Cr6+ ions and MV40 dye from aqueous media.