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This study investigated the removal of tetracycline from the aqueous solutions by lanthanum oxide nanoparticles covered with polyethylene terephthalate (PET) using a low-cost and facile co-precipitation method, via catalytic wet air oxidation process (CWAO) by response surface methodology (RSM). XRD, FTIR, SEM, and EDX-map techniques have been employed to investigate the crystal structure, functional groups on the surface, morphologic characteristics, and elemental composition, respectively. Under optimum conditions (pH= 9, initial TC concentration= 20 mg L-1, nanocomposite dosage= 1.5 g L-1, pressure= 4 bar, temperature= 70 °C, and time= 90 min), TC removal efficiency by La2O3-PET was achieved at about 99.9%. The environmental parameters were assessed to determine tetracycline catalytic wet air oxidation degradation rate, which included cleaning gases, hydrogen peroxide, type of organic compounds, anions, radical scavenger and reusability. The ANOVA results indicated that the polynomial model proves that the model is entirely meaningful (F-value> 0.001 and P-value< 0.0001) and has high coefficient values of adjusted R2 (0.7404) and predicted R2 (0.5940). The findings indicated that the variables of time, pH, temperature, dosage, and TC concentration have the greatest role in removing tetracycline, respectively. However, pressure as a factor does not have a considerable influence on the performance of the system. In general, due to the presence of the role of additional anionics, the effectiveness of this method for removing tetracycline from drinking water was 82.76%. The catalyst indicated pleasing stability and recycling power during eight testing cycles. Further, the estimated electrical energy per order consumption (EEO) for the CWAO/La2O3-PET system was calculated as 5.31 kWh m-3 with an operational cost (OC) utilization of 1.78 USD kg-1 and it has been shown that this process is feasible and economically comparable to other CWAO processes. The breakdown intermediate products of tetracycline in the CWAO were examined using gas chromatography/mass spectrometry (GC-MS) analysis. The toxicity analyses for the removal of TC were carried out using Daphnia magna and the CWAO process achieved a remarkable decrease in the presence of La2O3-PET nanocomposite (LC50 and toxicity unit (TU) 48 h equal to 0.634 and 157.72 vol percent).

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In this study, Cr(VI) was removed sonocatalytically by the zinc oxide nanoparticle coated with polyethylene terephthalate (PET) fabricated through a facile co-precipitation method. The crystal structure, functional groups on the surface, morphology, surface composition and oxidation states of the nanomaterials were investigated by XRD, FTIR, SEM, EDX and XPS techniques. Environmental parameters including solution pH, catalyst dose, hexavalent chromium concentration, H2O2 content, purging gases, organic compounds and type and anions strength on the sonotocatalytic removal of Cr(VI) were also investigated. Additionally, the contribution of each process, reusability, Cr(VI) reduction from actual water and electroplating wastewater were evaluated. Under the optimal conditions, [Cr(VI)]0=20 mg/L, nanocomposite loading=1.6 g/L and pH=5, 99.92% of Cr(VI) was removed within 60 min. By increaing, Cr(VI) concentration (5-50 mg/L), kobs decreased to values between 0.1498 and 0.0063 min-1 and the calculated electrical energy per order (EEo) increased from 148.68 to 3535.24 kWh.m-3, respectively. The presence of purging gases, organic compounds and ionic strength negatively affected Cr(VI) reduction. Examination of radical scavengers showed that the most active radicals in Cr(VI) removal were O2•- and h+. The removal of the Cr(VI) using the US/ZnO-PET method (99.92%) was higher than that of the US/ZnO method (70.78%). The catalyst activity was well maintained up to eight consecutive cycles. In addition, the removal efficiency was approximately 72.23 and 68.55% for drinking water and real electroplating wastewater samples, respectively. The results of toxicity in the sonotocatalytic removal of Cr(VI) by Daphnia magna showed LC50 and toxicity unit (TU) 48 h, which was equal to 81.46 and 1.227 vol percent.

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Overexposure to solar ultraviolet radiation (SUVR) can cause skin and eye adverse effects for outdoor workers. In this study, the burden of disease induced by occupational exposure to SUVR and its spatiotemporal trend at national and sub-national levels in Iran, 2005-2019 were assessed. The attributable burden of disease was assessed using the following five datasets: (1) distribution of occupational exposure to SUVR, (2) total incidences and deaths of health outcomes of SUVR exposure, (3) population attributable fractions of the health outcomes of SUVR exposure, (4) age-gender distribution of outdoor workers, and (5) disability-adjusted life year (DALY) calculation constants. During 2005-2019, the attributable DALYs increased from 2442 to 2907 and the attributable DALY rate (per 100,000 workers) slightly decreased from 11.94 to 11.91. The share of YLL in the attributable burden of disease was in the range of 43%-46%. Out of nine causes, about 90% of the attributable burden of disease in 2019 was related to cataracts (29.9%), malignant skin melanoma (27.4%), squamous-cell carcinoma (18.6%), and sunburn (17.2%). During the study period, the attributable DALY rate in women increased by 60.95% (from 5.04 to 8.11) and in men decreased by 2.06% (from 13.03 to 12.76). The total attributable DALYs and DALY rate rose by age during 2005-2019. The contributions of population growth, risk-deleted DALY rates, exposure risk, and population age structure in temporal changes of the attributable burden of disease were 19.27%, 9.13%, -1.35%, and -14.8%, respectively. The three highest attributable DALY rates in 2019 were observed in South Khorasan (21.28), Chahar Mahal and Bakhtiari (17.42), and Kordestan (17.26), respectively. The preventive interventions against SUVR overexposure, regular screenings, and early treatments with an emphasis on occupations with continuous sun exposure and provinces with increasing attributable DALY rates should be considered in the occupational health action plan in the country.

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In this study, removal of Cr(VI) by Scallop shell-Fe3O4 nanoparticles was investigated with variation of pH, adsorbent dosage, initial Cr(VI) concentration, ionic strength and temperature. Coating of Fe3O4 nanoparticles onto Scallop shell was identified by Fourier transform infrared spectroscopy, X-ray diffraction, scanning electron microscopy and energy dispersive X-ray analysis. The maximum adsorption was observed at pH 3. Removal efficiency of Cr(VI) was increased with increasing adsorbent dosage, but was decreased with increasing initial Cr(VI) concentration and temperature. Removal efficiency of Cr(VI) was decreased in the presence of sulfate and carbonate ions. Adsorption kinetic study revealed that a pseudo-second order model better described the removal data than a pseudo-first order model and an intra-particle diffusion model. Maximum adsorption capacity was estimated to be 34.48 mg/g. Thermodynamic studies indicated that adsorption of Cr(VI) onto Scallop shell-Fe3O4 nanoparticles occurred via an exothermic (ΔH = -320.88 KJ mol-1) process. Adsorption efficiency of Cr(VI) by Scallop shell-Fe3O4 nanoparticles was maintained even after eight successive cycles.

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BACKGROUND: Estrogenic steroids such as estrone (E1), 17ß-estradiol (E2), estriol (E3), and 17α-ethinylestradiol (EE2) are among the most potent endocrine disrupting compounds (EDCs). Compared with North America, Europe and Japan there is no reliable information on the concentration of steroid hormones in wastewater treatment plants (WWTPs) influents and effluents in Iran. The aim of the present study was to determine the amounts of E1, E2, E3, and EE2 influents and effluents of 7 municipal WWTPs across Tehran, the capital city of Iran, in two seasons, summer and autumn, through solid-phase extraction (SPE) gas chromatography-mass spectrometry (GC-MS). RESULTS: The results showed that the concentrations of E1, E2, and EE2 in influents ranged from 6.54-18.76 ng/L, 1.02-8 ng/L and 4.18-11.76 ng/L, respectively. Also, the concentrations of E1, E2, and EE2 in effluents ranged from 1.04-4.99 ng/L, 0.5-2.20 ng/L and 0.5-2.58 ng/L, respectively. The levels of E3 were below the detection limit (0.5 ng/L). The percentage removal rate of E1, E2 and EE2 ranged between 61.76-87.25%, 50.98-82.63%, and 66.3-90.25%, respectively. Results indicated no significant correlation between hormone concentrations and seasons. CONCLUSIONS: The study showed that WWTP number 7 had significant differences in influent hormone concentrations compared with others. Results only showed a significant relationship between hormones and TSS removal rate, but there was no significant relationship between hormones and COD removal rate. The removal rate of hormone in WWTP number 4 and 7 were significantly different from the others. There was no significant correlation between hormone concentrations and seasons.

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Tea is one of the most common drinks in all over the world. Rapid urbanization and industrialization in recent decades has increased heavy metals in tea and other foods. In this research, heavy metal contents such as lead (Pb), cadmium (Cd) and arsenic (As) were determined in 105 black tea samples cultivated in Guilan and Mazandaran Provinces in north of Iran and their tea infusions. The amount of heavy metals in black tea infusions were analyzed using Inductively Coupled Plasma Atomic Emission Spectroscopy (ICP - AES).The mean ± SD level of Pb in 5, 15 and 60 min in infusion tea samples were 0.802 ± 0.633, 0.993 ± 0.667 and 1.367 ± 1.06 mg/kg of tea dry weight, respectively. The mean level of Cd in 5, 15 and 60 min in infusion tea samples were 0.135 ± 0.274, 0.244 ± 0.46 and 0.343 ± 0.473 mg/kg of tea dry weight, respectively. The mean level of As in 5, 15 and 60 min in infusion tea samples were 0.277 ± 0.272, 0.426 ± 0.402 and 0.563 ± 0.454 mg/kg of tea dry weight, respectively. Also, the results showed that the locations and the infusion times influenced upon the amount of these metals (P < 0.05).