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When slowly sheared, jammed packings respond elastically before yielding. This linear elastic regime becomes progressively narrower as the jamming transition point is approached, and rich nonlinear rheologies such as shear softening and hardening or melting emerge. However, the physical mechanism of these nonlinear rheologies remains elusive. To clarify this, we numerically study jammed packings of athermal frictionless soft particles under quasistatic shear γ. We find the universal scaling behavior for the ratio of the shear stress σ and the pressure P, independent of the preparation protocol of the initial configurations. In particular, we reveal shear softening σ/Pâ¼Î³^{1/2} over an unprecedentedly wide range of strain up to the yielding point, which a simple scaling argument can rationalize.
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Building on the recently derived inhomogeneous mode-coupling theory, we extend the generalized mode-coupling theory of supercooled liquids to inhomogeneous environments. This provides a first-principles-based, systematic, and rigorous way of deriving high-point dynamical susceptibilities from variations of the many-body dynamic structure factors with respect to their conjugate field. This framework allows for a fully microscopic possibility to probe for collective relaxation mechanisms in supercooled liquids near the mode-coupling glass transition. The behavior of these dynamical susceptibilities is then studied in the context of simplified self-consistent relaxation models.
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There is a growing interest in the stochastic processes of nonequilibrium systems subject to nonconserved forces, such as the magnetic forces acting on charged particles and the chiral self-propelled force acting on active particles. In this paper, we consider the stationary transport of noninteracting Brownian particles under a constant magnetic field in a position-dependent temperature background. We demonstrate the existence of the Nernst-like stationary density current perpendicular to both the temperature gradient and magnetic field, induced by the intricate coupling between the nonconserved force and the multiplicative noises due to the position-dependent temperature.
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Geometrical properties of two-dimensional mixtures near the jamming transition point are numerically investigated using harmonic particles under mechanical training. The configurations generated by the quasi-static compression and oscillatory shear deformations exhibit anomalous suppression of the density fluctuations, known as hyperuniformity, below and above the jamming transition. For the jammed system trained by compression above the transition point, the hyperuniformity exponent increases. For the system below the transition point under oscillatory shear, the hyperuniformity exponent also increases until the shear amplitude reaches the threshold value. The threshold value matches with the transition point from the point-reversible phase where the particles experience no collision to the loop-reversible phase where the particles' displacements are non-affine during a shear cycle before coming back to an original position. The results demonstrated in this paper are explained in terms of neither of universal criticality of the jamming transition nor the nonequilibrium phase transitions.
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Frequency-dependence of specific heat in supercooled hard sphere liquid is computed using quantum mode-coupling theory (QMCT). Mode-coupling equations are solved using a recently proposed perturbative method that allows us to study relaxation in the moderate quantum regime where quantum effects assist liquid to glass transition. Zwanzig's formulation is used to compute the frequency-dependent specific heat in the supercooled state using dynamical information from QMCT. Specific heat shows strong variation as the quantumness of the liquid is changed, which becomes more significant as density is increased. It is found that, near the transition point, different dynamical modes contribute to specific heat in classical and quantum liquids.
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We extend the replica liquid theory in order to describe the multiple glass transitions of binary mixtures with large size disparities, by taking into account the two-step replica symmetry breaking (2RSB). We determine the glass phase diagram of the mixture of large and small particles in the large-dimension limit where the mean-field theory becomes exact. When the size ratio of particles is beyond a critical value, the theory predicts three distinct glass phases; (i) the one-step replica symmetery breaking (1RSB) double glass where both components vitrify simultaneously, (ii) the 1RSB single glass where only large particles are frozen while small particles remain mobile, and (iii) a glass phase called the 2RSB double glass where both components vitrify simultaneously but with an energy landscape topography distinct from the 1RSB double glass.
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We study supercooled dynamics in a quantum hard-sphere liquid using quantum mode-coupling formulation. In the moderate quantum regime, classical cage effects lead to slower dynamics compared to the strongly quantum regime, where tunneling overcomes classical caging, leading to faster relaxation. As a result, the glass transition critical density can become significantly higher than for the classical liquids. A perturbative approach is used to solve time dependent quantum mode-coupling equations to study in detail the dynamics of the supercooled liquid in the moderate quantum regime. Similar to the classical case, the relaxation time shows the power-law increase with the increase in the density in the supercooled regime. However, the power-law exponent is found to be dependent on the quantumness; it increases linearly as the quantumness is increased in the moderate quantum regime.
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We perform molecular dynamics simulations to investigate the effect of a glass preparation on its yielding transition under oscillatory shear. We use swap Monte Carlo to investigate a broad range of glass stabilities from poorly annealed to highly stable systems. We observe a qualitative change in the nature of yielding, which evolves from ductile to brittle as glass stability increases. Our results disentangle the relative role of mechanical and thermal annealing on the mechanical properties of amorphous solids, which is relevant for various experimental situations from the rheology of soft materials to fatigue failure in metallic glasses.
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The reversible-irreversible (RI) transition of particle trajectories in athermal colloidal suspensions under cyclic shear deformation is an archetypal nonequilibrium phase transition which has attracted much attention recently. Most studies of the RI transitions have focused on either dilute limit or very high densities well above the jamming transition point. The transition between the two limiting cases is largely unexplored. In this paper, we study the RI transition of athermal frictionless colloidal particles over a wide range of densities, with emphasis on the region below φJ, by using oscillatory sheared molecular dynamics simulation. We reveal that the nature of the RI transitions in the intermediate densities is very rich. As demonstrated by the previous work by Schreck et al. [Phys. Rev. E: Stat., Nonlinear, Soft Matter Phys., 2013, 88, 052205], there exist the point-reversible and the loop-reversible phases depending on the density and the shear strain amplitude. We find that, between the two reversible phases, a quasi-irreversible phase where the particles' trajectories are highly non-affine and diffusive. The averaged number of contacts of particles is found to characterize the phase boundaries. We also find that the system undergoes the yielding transition below but in the vicinity of φJ when the strain with a small but finite strain rate is applied. This yielding transition line matches with the RI transition line separating the loop-reversible from the irreversible phases. Surprisingly, the nonlinear rheological response called "softening" has been observed even below φJ. These findings imply that geometrical properties encoded in the sheared configurations control the dynamical transitions.
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We numerically investigate the slow dynamics of a binary mixture of ultrasoft particles interacting with the generalized Hertzian potential. If the softness parameter, α, is small, the particles at high densities start penetrating each other, form clusters, and eventually undergo the glass transition. We find multiple cluster-glass phases characterized by a different number of particles per cluster, whose boundary lines are sharply separated by the cluster size. Anomalous logarithmic slow relaxation of the density correlation functions is observed in the vicinity of these glass-glass phase boundaries, which hints the existence of the higher-order dynamical singularities predicted by the mode-coupling theory. Deeply in the cluster glass phases, it is found that the dynamics of a single particle is decoupled from that of the collective fluctuations.
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We use computer simulations to probe the thermodynamic and dynamic properties of a glass former that undergoes an ideal glass transition because of the presence of randomly pinned particles. We find that even deep in the equilibrium glass state, the system relaxes to some extent because of the presence of localized excitations that allow the system to access different inherent structures, thus giving rise to a nontrivial contribution to the entropy. By calculating with high accuracy the vibrational part of the entropy, we show that also in the equilibrium glass state thermodynamics and dynamics give a coherent picture, and that glasses should not be seen as a disordered solid in which the particles undergo just vibrational motion but instead as a system with a highly nonlinear internal dynamics.
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The irreversible currents and entropy production rate of a dilute colloidal suspension are calculated using linear irreversible thermodynamics and the linear response theory. The "anomalous" or "hidden" entropy that has been the subject of recent discussion in the context of stochastic thermodynamics is fully accounted for in these classical frameworks. We show that the two distinct formulations lead to identical results as long as the local equilibrium assumption, or equivalently, the linear response theory, is valid.
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This corrects the article DOI: 10.1103/PhysRevLett.117.165701.
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Using molecular dynamics simulation, we investigate the slow dynamics of a supercooled binary mixture of soft particles interacting with a generalized Hertzian potential. At low density, it displays typical slow dynamics near its glass transition temperature. At higher densities, particles bond together, forming clusters, and the clusters undergo the glass transition. The number of particles in a cluster increases one by one as the density increases. We demonstrate that there exist multiple cluster-glass phases characterized by a different number of particles per cluster, each of which is separated by distinct minima. Surprisingly, a so-called higher order singularity of the mode-coupling theory signaled by a logarithmic relaxation is observed in the vicinity of the boundaries between monomer and cluster glass phases. The system also exhibits rich and anomalous dynamics in the cluster glass phases, such as the decoupling of the self- and collective dynamics.
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We use molecular dynamics simulations to investigate dynamic heterogeneities and the potential energy landscape of the Gaussian core model (GCM). Despite the nearly Gaussian statistics of particles' displacements, the GCM exhibits giant dynamic heterogeneities close to the dynamic transition temperature. The divergence of the four-point susceptibility is quantitatively well described by the inhomogeneous version of the mode-coupling theory. Furthermore, the potential energy landscape of the GCM is characterized by large energy barriers, as expected from the lack of activated, hopping dynamics, and display features compatible with a geometric transition. These observations demonstrate that all major features of mean-field dynamic criticality can be observed in a physically sound, three-dimensional model.
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We use computer simulations to study the thermodynamic properties of a glass-former in which a fraction c of the particles has been permanently frozen. By thermodynamic integration, we determine the Kauzmann, or ideal glass transition, temperature [Formula: see text] at which the configurational entropy vanishes. This is done without resorting to any kind of extrapolation, i.e., [Formula: see text] is indeed an equilibrium property of the system. We also measure the distribution function of the overlap, i.e., the order parameter that signals the glass state. We find that the transition line obtained from the overlap coincides with that obtained from the thermodynamic integration, thus showing that the two approaches give the same transition line. Finally, we determine the geometrical properties of the potential energy landscape, notably the T- and c dependence of the saddle index, and use these properties to obtain the dynamic transition temperature [Formula: see text]. The two temperatures [Formula: see text] and [Formula: see text] cross at a finite value of c and indicate the point at which the glass transition line ends. These findings are qualitatively consistent with the scenario proposed by the random first-order transition theory.
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We analyze, using inhomogeneous mode-coupling theory, the critical scaling behavior of the dynamical susceptibility at a distance ε from continuous second-order glass transitions. We find that the dynamical correlation length ξ behaves generically as ε(-1/3) and that the upper critical dimension is equal to six. More surprisingly, we find that ξ grows with time as ln²t exactly at criticality. All of these results suggest a deep analogy between the glassy behavior of attractive colloids or randomly pinned supercooled liquids and that of the random field Ising model.
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In this work, we numerically investigate a new method for the characterization of growing length scales associated with spatially heterogeneous dynamics of glass-forming liquids. This approach, motivated by the formulation of the inhomogeneous mode-coupling theory (IMCT) [Biroli, G.; et al. Phys. Rev. Lett. 2006 97, 195701], utilizes inhomogeneous molecular dynamics simulations in which the system is perturbed by a spatially modulated external potential. We show that the response of the two-point correlation function to the external field allows one to probe dynamic correlations. We examine the critical properties shown by this function, in particular, the associated dynamic correlation length, that is found to be comparable to the one extracted from standardly employed four-point correlation functions. Our numerical results are in qualitative agreement with IMCT predictions but suggest that one has to take into account fluctuations not included in this mean-field approach to reach quantitative agreement. Advantages of our approach over the more conventional one based on four-point correlation functions are discussed.