RESUMEN
We report superconducting nanostrip single-photon detectors (SNSPDs) with dielectric multilayer cavities (DMCs) for a 2-µm wavelength. We designed a DMC composed of periodic SiO2/Si bilayers. Simulation results of finite element analysis showed that the optical absorptance of the NbTiN nanostrips on the DMC exceeded 95% at 2 µm. We fabricated SNSPDs with an active area of 30 µm × 30 µm, which was sufficiently large to couple with a single-mode fiber of 2 µm. The fabricated SNSPDs were evaluated using a sorption-based cryocooler at a controlled temperature. We carefully verified the sensitivity of the power meter and calibrated the optical attenuators to accurately measure the system detection efficiency (SDE) at 2 µm. When the SNSPD was connected to an optical system via a spliced optical fiber, a high SDE of 84.1% was observed at 0.76â K. We also estimated the measurement uncertainty of the SDE as ±5.08% by considering all possible uncertainties in the SDE measurements.
RESUMEN
Here, we examined the removal of soluble divalent manganese (Mn(II)) by combination treatment with superfine powdered activated carbon (SPAC) and free chlorine in a membrane filtration pilot plant and batch experiments. Removal rates >95% were obtained with 3 mg/L SPAC, 1 mg/L chlorine, and a contact time of 4 min, meeting practical performance standards. Mn(II) was found to be oxidized and precipitated on the surface of the activated carbon particles by chlorine. The Mn(II) removal rate was fitted to pseudo-first-order reaction kinetics, and the rate coefficient changed in inverse proportion to as-is particle size, but not to true particle size. The rate coefficient was independent of both Mn(II) concentration, except at high Mn(II) concentration, and the chlorine concentrations tested. The rate-determining step of Mn(II) removal was confirmed to be external-film mass transfer, not chemical oxidation. Activated carbon was found to have a catalytic effect on the oxidation of Mn(II), but the effect was minimal for conventionally sized activated carbon. However, Mn(II) removal at feasible rates for practical application can be expected when the activated carbon particle diameter is reduced to several micrometers. Activated carbon with a particle size of around 1-2 µm may be the most appropriate for Mn(II) removal because particles below this size were aggregated, resulting in reduced removal efficiency.
Asunto(s)
Carbón Orgánico , Purificación del Agua , Adsorción , Cloro , Manganeso , Estrés Oxidativo , PolvosRESUMEN
As a pretreatment for membrane microfiltration (MF), the use of powdered activated carbon (PAC) with a particle size much smaller than that of conventional PAC (super-powdered PAC, or S-PAC) has been proposed to enhance the removal of dissolved substances. In this paper, another advantage of S-PAC as a pretreatment for MF is described: the use of S-PAC attenuates trans-membrane pressure increases during the filtration operation. The floc particles that formed during coagulation preceded by S-PAC pretreatment were larger and more porous than the floc particles formed during coagulation preceded by PAC pretreatment and those formed during coagulation without pretreatment. This result was due to increased particle-particle collision frequency and better removal of natural organic matter, which inhibits coagulation by consuming coagulant, before the coagulation reaction. The caked fouling layer that built up on the membrane surface was thus more permeable with S-PAC than with normal PAC. Both physically reversible and irreversible membrane foulings were reduced, and more stable filtration was accomplished with S-PAC pretreatment.