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The increase in the world population and the intensification of agricultural practices have resulted in the release of several contaminants into the environment, especially pesticides and heavy metals. This article reviews recent advances in using adsorbent and catalytic materials for environmental decontamination. Different materials, including clays, carbonaceous, metallic, polymeric, and hybrid materials, are evaluated for their effectiveness in pollutant removal. Adsorption is an effective technique due to its low cost, operational simplicity, and possibility of adsorbent regeneration. Catalytic processes, especially those using metallic nanoparticles, offer high efficiency in degrading complex pesticides. Combining these technologies can enhance the efficiency of remediation processes, promoting a more sustainable and practical approach to mitigate the impacts of pesticides and other agricultural pollutants on the environment. Therefore, this review article aims to present several types of materials used as adsorbents and catalysts for decontaminating ecosystems affected by agricultural pollutants. It discusses recent works in literature and future perspectives on using these materials in environmental remediation. Additionally, it explores the possibilities of using green chemistry principles in producing sustainable materials and using agro-industrial waste as precursors of new materials to remove contaminants from the environment.
RESUMEN
In this study, the effectiveness of microcrystalline cellulose (MCC) as an adsorbent for the removal of hexavalent chromium, Cr(vi), from synthetic wastewater was enhanced through functionalization with polyaniline (PANI). Scanning electron microscopy (SEM) showed that MCC was an effective scaffold for in situ chemical oxidative polymerization of aniline. Fourier transform infrared spectroscopy (FTIR) spectroscopy and X-ray diffraction confirmed successful PANI synthesis. The MCC/PANI nanocomposites exhibited relatively high specific surface areas, compared to that of the MCC (2.05 m2 g-1). Batch adsorption studies showed that the optimal conditions for the removal of Cr(vi) from wastewater using the MCC/PANI-69 wt% nanocomposite were an initial Cr(vi) concentration of 100 mg L-1, an adsorbent dosage of 4 g L-1 and a Cr(vi) solution pH of 7. The MCC/PANI-69 wt% required only 30 min to reach equilibrium and the equilibrium removal efficiency was 95%. FTIR spectroscopy and energy dispersive X-ray spectrometry results suggest that the Cr(vi) removal mechanism by the MCC/PANI-69 wt% nanocomposite at pH 7 was through electrostatic attraction of Cr(vi) species by PANI, reduction of Cr(vi) into Cr(iii) and precipitation of Cr(iii) on the nanocomposite surface. The kinetics for the removal of the Cr(vi) by the MCC/PANI-69 wt% nanocomposite were adequately described by the pseudo second order (PSO) kinetics model, whereas the Langmuir isotherm adequately described the equilibrium data. The MCC/PANI-69 wt% nanocomposite had a significantly improved maximum adsorption capacity of 35.97 mg g-1, at pH 7, in comparison to that of the MCC (3.92 mg g-1 at pH 1). The study demonstrated that, whereas most of the reported adsorbents for Cr(vi) are only effective at low pH values, the MCC/PANI nanocomposite synthesized in this study was effective at pH 7.
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The extensive use of non-biodegradable plastic products has resulted in significant environmental problems caused by their accumulation in landfills and their proliferation into water bodies. Biodegradable polymers offer a potential solution to mitigate these issues through the utilization of renewable resources which are abundantly available and biodegradable, making them environmentally friendly. However, biodegradable polymers face challenges such as relatively low mechanical strength and thermal resistance, relatively inferior gas barrier properties, low processability, and economic viability. To overcome these limitations, researchers are investigating the incorporation of nanofillers, specifically bentonite clay, into biodegradable polymeric matrices. Bentonite clay is an aluminum phyllosilicate with interesting properties such as a high cation exchange capacity, a large surface area, and environmental compatibility. However, achieving complete dispersion of nanoclays in polymeric matrices remains a challenge due to these materials' hydrophilic and hydrophobic nature. Several methods are employed to prepare polymer-clay nanocomposites, including solution casting, melt extrusion, spraying, inkjet printing, and electrospinning. Biodegradable polymeric nanocomposites are versatile and promising in various industrial applications such as electromagnetic shielding, energy storage, electronics, and flexible electronics. Additionally, combining bentonite clay with other fillers such as graphene can significantly reduce production costs compared to the exclusive use of carbon nanotubes or metallic fillers in the matrix. This work reviews the development of bentonite clay-based composites with biodegradable polymers for multifunctional applications. The composition, structure, preparation methods, and characterization techniques of these nanocomposites are discussed, along with the challenges and future directions in this field.
RESUMEN
Enhancing the melt processability of cellulose is key to broadening its applications. This is done via derivatization of cellulose, and subsequent plasticization and/or blending with other biopolymers, such as polylactic acid (PLA) and polybutylene adipate terephthalate (PBAT). However, derivatization of cellulose tends to reduce its biodegradability. Moreover, traditional plasticizers are non-biodegradable. In this study, we report the influence of polyethylene glycol (PEG) plasticizer on the melt processibility and biodegradability of cellulose diacetate (CD) and its blends with PLA and PBAT. CD was first plasticized with PEG (PEG-200) at 35 wt%, and then blended with PLA and PBAT using a twin-screw extruder. Blends of the PEG plasticized CD with PLA at 40 wt% and with PBAT at 60 wt% were studied in detail. Dynamic mechanical analysis (DMA) showed that PEG reduced the glass transition of the CD from ca. 220 °C to less than 100 °C, indicating effective plasticization. Scanning electron microscopy revealed that the CD/PEG-PBAT blend had a smoother morphology implying some miscibility. The CD/PEG-PBAT blend at 60 wt% PBAT had an elongation-to-break of 734%, whereas the CD/PEG-PLA blend had a tensile strength of 20.6 MPa, comparable to that of the PEG plasticized CD. After a 108-day incubation period under simulated aerobic composting, the CD/PEG-PBAT blend at 60 wt% PBAT exhibited a biodegradation of 41%, whereas that of the CD/PEG-PLA at 40 wt% PLA was 107%. This study showed that melt processible, biodegradable CD blends can be synthesized through plasticization with PEG and blending with PBAT or PLA.