RESUMEN

Sulfate minerals are rare in the Archean rock record and largely restricted to the occurrence of barite (BaSO4 ). The origin of this barite remains controversially debated. The mass-independent fractionation of sulfur isotopes in these and other Archean sedimentary rocks suggests that photolysis of volcanic aerosols in an oxygen-poor atmosphere played an important role in their formation. Here, we report on the multiple sulfur isotopic composition of sedimentary anhydrite in the ca. 3.22 Ga Moodies Group of the Barberton Greenstone Belt, southern Africa. Anhydrite occurs, together with barite and pyrite, in regionally traceable beds that formed in fluvial settings. Variable abundances of barite versus anhydrite reflect changes in sulfate enrichment by evaporitic concentration across orders of magnitude in an arid, nearshore terrestrial environment, periodically replenished by influxes of seawater. The multiple S-isotope compositions of anhydrite and pyrite are consistent with microbial sulfate reduction. S-isotope signatures in barite suggest an additional oxidative sulfate source probably derived from continental weathering of sulfide possibly enhanced by microbial sulfur oxidation. Although depositional environments of Moodies sulfate minerals differ strongly from marine barite deposits, their sulfur isotopic composition is similar and most likely reflects a primary isotopic signature. The data indicate that a constant input of small portions of oxidized sulfur from the continents into the ocean may have contributed to the observed long-term increase in Δ33 Ssulfate values through the Paleoarchean.

Asunto(s)

Isótopos de Azufre/química , Oxidación-Reducción , Sudáfrica , Sulfuros

RESUMEN

Astronomical forcing associated with Earth's orbital and inclination parameters ("Milankovitch" forcing) exerts a major control on climate as recorded in the sedimentary rock record, but its influence in deep time is largely unknown. Banded iron formations, iron-rich marine sediments older than 1.8 billion years, offer unique insight into the early Earth's environment. Their origin and distinctive layering have been explained by various mechanisms, including hydrothermal plume activity, the redox evolution of the oceans, microbial and diagenetic processes, sea level fluctuations, and seasonal or tidal forcing. However, their potential link to past climate oscillations remains unexplored. Here we use cyclostratigraphic analysis combined with high-precision uranium-lead dating to investigate the potential influence of Milankovitch forcing on their deposition. Field exposures of the 2.48-billion-year-old Kuruman Banded Iron Formation reveal a well-defined hierarchical cycle pattern in weathering profile that is laterally continuous over at least 250 kilometres. The isotopic ages constrain the sedimentation rate at 10 m/Myr and link the observed cycles to known eccentricity oscillations with periods of 405 thousand and about 1.4 to 1.6 million years. We conclude that long-period, Milankovitch-forced climate cycles exerted a primary control on large-scale compositional variations in banded iron formations.

RESUMEN

Selenium poisoning is a significant health problem in parts of Punjab, India, which is an area of intense agricultural productivity. To determine the complex soil dynamics that control distribution of Se in this area, we measured concentrations and δ(82/76)Se of bulk Se and individual Se pools in four soil profiles. This was compared against δ(82/76)Se of crops and groundwater used for irrigation. The isotopic composition of bulk Se and component Se pools reveal spatial heterogeneity. The bulk δ(82/76)Se show progressively lower values with increasing soil depth indicating the preferential migration of isotopically lighter Se downward through the soil profile. The δ(82/76)Se of water-soluble Se is isotopically heavier than δ(82/76)Se of adsorbed Se, suggesting Se isotope fractionation by reduction prior to scavenging by reactive minerals in the soil. The organically bound Se is isotopically lighter than water-soluble Se and correlates with the C/N ratio at different soil depths. Thus, Se immobilization by redox cycling controls the biogeochemical Se cycle in the soil. Se isotope ratios help to trace biochemical processes of Se in agricultural seleniferous soils and provide an important assessment for better soil management mitigating Se concentrations of ecotoxicological levels.

Asunto(s)

Isótopos/análisis , Selenio/análisis , Suelo/química , Productos Agrícolas/química , Monitoreo del Ambiente/métodos , India , Isótopos/metabolismo , Selenio/metabolismo , Compuestos de Selenio/metabolismo , Solubilidad , Agua/química

RESUMEN

The buoyancy and strength of sub-continental lithospheric mantle is thought to protect the oldest continental crust (cratons) from destruction by plate tectonic processes. The exact origin of the lithosphere below cratons is controversial, but seems clearly to be a residue remaining after the extraction of large amounts of melt. Models to explain highly melt-depleted but garnet-bearing rock compositions require multi-stage processes with garnet and clinopyroxene possibly of secondary origin. Here we report on orogenic peridotites (fragments of cratonic mantle incorporated into the crust during continent-continent plate collision) from Otrøy, western Norway. We show that the peridotites underwent extensive melting during upwelling from depths of 350 kilometres or more, forming a garnet-bearing cratonic root in a single melting event. These peridotites appear to be the residue after Archaean aluminium depleted komatiite magmatism.