RESUMEN
This study utilized a statistical nanoindentation analysis technique (SNT) to measure the amount of organic and inorganic constituents of twenty different brands of dental resin-based composites (RBCs) and tested whether their macro-property such as flexural modulus could be approximated by the proportions of constituents' micromechanical signatures using various rules of mixtures. The probability density function (PDF) of constitutive moduli per RBC brand were measured for three groups, comprised of different indent arrays and inter-indent spacings. SNT was then applied to deconvolute each PDF, from which the effective filler (µF) and matrix (µM) moduli and filler (VF) and matrix (VM) volume fractions per RBC brand were computed. VF and VM values obtained via SNT were strongly correlated with VF and VM obtained via Thermogravimetric Analysis and Archimedes method. The "observed" flexural modulus (EcFS) measured under macro-experiment were well associated with "predicted" effective modulus (EcEff) measured under nano-experiment, thereby establishing that global modulus was strongly affected by the constituents' micromechanics. However, the "predicted" EcEff were proportionally higher than the "observed" EcFS. VF was a confounder to EcFS and EcEff, whereby the influence of VF on both modular ratios (EcFS/µM and EcEff/µM) was best modeled by an exponential regression.
Asunto(s)
Resinas Compuestas , Materiales Dentales , Módulo de Elasticidad , Ensayo de Materiales , Docilidad , Propiedades de SuperficieRESUMEN
OBJECTIVES: The purpose of this study was to investigate the effect of high-irradiance light-curing-units (LCUs) on the depth-of-cure (DoC) and degree-of-polymerization (DoP) of bulk-fill composites (BFCs). METHODS: The DoC of composites (Beautifil-Bulk, SHOFU; Filtek-Bulk-Fill, 3M ESPE; Tetric-EvoCeram-Bulk-Fill, Ivoclar; Sonic-Fill-2, Kerr; Venus-Bulk-Fill, Heraeus; Z250, 3M-ESPE) were measured according to ISO-4049 using high-irradiance LCUs (FlashMax-P3, CMS-Dental; SPEC3, Coltene) and conventional LCU (Paradigm, 3M-ESPE) for exposure times: 3/9-s, 3/20-s, and 10/20-s respectively. Using FTIR, the DoP per composite was measured at the bottom surface as a function of post-curing times for the LCUs at the same exposure times. Data was analyzed with nonlinear regression and ANOVA/Tukey. RESULTS: Significant differences in DoC were found amongst the LCUs for the various exposure times. All BFCs failed to meet the DoC claimed by manufacturers and failed to satisfy ISO-4049 with the high-irradiance LCUs with 3-s exposures. Standard irradiance and 20-s exposures outperformed all other irradiance-exposure combinations for maximizing the DoC and DoP of BFCs. A minimum of 15.3J/cm2 radiant exposure was required to achieve an adequate maximum polymerization rate. Venus Bulk exhibited the highest DoC and DoP for any LCU-exposure-time combination. SIGNIFICANCE: Among the different combinations of BFCs and LCUs, DoC and DoP were always increased with longer exposure time, but there exists a theoretical radiant-exposure limit beyond which DoP or DoC remains unchanged. However, high DoC or DoP are not always associated with one another. Thus, the exposure-reciprocity law must be approached thoughtfully since irradiance and exposure can independently affect DoP and DoC.