RESUMEN
The (0.90)Y2O3:(0.10-x)Eu3+:(x)Bi3+ nanophosphors (0.00 ≤ x ≤ 0.06) are synthesised using chemical combustion citrate route and characterized via X-ray diffraction, Raman spectroscopy, Fourier transform infrared spectroscopy, UV- visible and photoluminescence spectroscopy. The scanning electron micrographs indicate that the grain size of the phosphors ranges between 40 to 50 nm. The photoluminescence (PL) spectra, acquired under the excitation wavelength of 365 nm of ultraviolet light, show emission peaks at wavelengths 580 nm, 586-598 nm, 610 nm, 629-661 nm and 686-695 nm corresponding to the 5D0 â 7FJ electronic transitions of the Eu3+ ion with J = 0, 1, 2, 3 and 4, respectively. The most intense PL spectra at 611 nm (5D0 â 7F2), showcasing reddish-orange emission, indicate a higher concentration of Eu3+ ions in asymmetric sites within the Y2O3 host matrix. The presence of the distinct electronic transitions of Eu3+ in PL spectra acclaims that Bi3+ ions transfer their energy efficiently to Eu3+ ions in the matrix. Physical and chemical tests are being conducted on nanophosphors with Bi3+ substitutional doping of x = 0.02 and x = 0.04, both demonstrating intense PL emission. Magnetisation measurements suggest the soft magnetic nature of the nanophosphors, attributing it to the presence of Eu3+ ions in the 7F2 state. The highest PL intensity is seen in the nanophosphor (x = 0.04) with substitutional doping of 6% of Eu3+ and 4% of Bi3+ in Y2O3. This nanophosphor also demonstrates excellent optical stability in the investigated conditions and exhibits soft magnetic behaviour, positioning it as a promising material for incorporation as a fluorescent magnetic pigment in security ink applications. These features serve to prevent counterfeiting of secured documents both optically and magnetically.
RESUMEN
Ferroelectric materials with crystal symmetry transition from single phase to multiphase coexistence exhibit anomalous photosensitive properties. The optical properties (optical band gap and photosensitive) found on non-centrosymmetric and centrosymmetric systems achieved research interest because of their interesting behavior. In this regard, the lead-free polycrystalline Ba1-xSrxTiO3(BSTO, 0⩽x⩽0.3) has been synthesized to explore its crystal structure, dielectric, light absorption, and photocurrent sensing properties for various applications. Both experimental and theoretical studies on BSTO (0⩽x⩽0.3) ceramics confirm the crystal symmetry transition with the reduction of band gap as compared to pristine BaTiO3. This crystal symmetry transition plays an important role in varying the various physical properties as it involves the transition from the polar phase to the non-polar phase. The optical band gap has been estimated experimentally by the Tauc plot method and found that there is a small variation of energy band gap from 3.615 eV to 3.212 eV with Sr substitution. The highest dielectric constant was found to be 5327 at lower frequency on Ba0.76Sr0.24TiO3after that for further increase in Sr concentration the dielectric constant decreases because of the introduction of the non-polar phase. A strong correlation between crystal structure and physical properties (dielectric, optical, etc.) has been observed. The photocurrent of the samples is significant which reveals that the sample is influenced by the photons. In a nutshell, the present study deepens the understanding of the correlation between crystal structure and various physical properties of BSTO and, hence provides an idea of required design parameters to construct a ferroelectric system for better photosensitive nature suitable for device applications.